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Wanhainen, ChristinaORCID iD iconorcid.org/0000-0003-4711-7671
Publikasjoner (10 av 92) Visa alla publikasjoner
Mendes, L., Martinsson, O., Jamal, D., Azim Zadeh, A. & Wanhainen, C. (2025). Lithogeochemistry and origin of the komatiites from Mundonguara mine in the Manica greenstone belt, Mozambique. Journal of African Earth Sciences, 223, Article ID 105494.
Åpne denne publikasjonen i ny fane eller vindu >>Lithogeochemistry and origin of the komatiites from Mundonguara mine in the Manica greenstone belt, Mozambique
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2025 (engelsk)Inngår i: Journal of African Earth Sciences, ISSN 1464-343X, E-ISSN 1879-1956, Vol. 223, artikkel-id 105494Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The Manica greenstones belt in western Mozambique constitutes the eastern extension of the Odzi-Mutare greenstone belt in Zimbabwe that is one of several Archean greenstone belts within the Zimbabwe Craton. These greenstones are in Mozambique constituting the Manica Group and are subdivided in two main lithostratigraphic units: The Macequece Formation and the Vengo Formation. The former is hosting the Mundonguara Cu-Au mine and is dominated by volcanic rocks, while the younger Vengo Formation is consisting of epiclastic sedimentary rocks. This paper considers the character and origin of the ultramafic, mafic, and felsic rocks within the Macequece Formation. They include peridotitic komatiite, pyroxenitic komatiite, komatiitic cumulate rocks, gabbroic dykes, rhyolitic units, and a granitic rock intruding the komatiites. Samples of these rocks have been collected from outcrops and drill cores and are investigated through petrographic studies of thin sections and whole rock geochemistry including major and trace elements to interpret the geological environment and tectonic setting.The supracrustal rocks are metamorphosed to greenschist facies and the komatiites consists of varying proportions of serpentine, talc, chlorite, and amphibole. Primary features are partly preserved, with spinifex, vesicular, and cumulate textures. The komatiites are variously affected by carbonate alteration and deformation and the rhyolitic rocks are mostly strongly silicified. The komatiites are of the Al-undepleted type, with a MgO content of 25–45 wt %, while the mafic intrusions are tholeiitic in character, varying from gabbronorite to diorite in composition. Trace element diagrams used for interpretation of tectonic setting gives ambiguous results that could be an effect of crustal contamination of the ultramafic and mafic magmas. Using diagrams less sensitive to crustal contamination suggests the mafic and ultramafic magma to have a mantle source Minor rhyolitic rocks are chemically similar to granitic rocks intruding the komatiites and might have a mainly crustal magma source. This suggested that the Manica greenstones belt formed from magmas generated by mantle plume activity in a continental rift setting and were deposited on older Archean continental crust. These rocks are tentatively correlated with the Bends or Brookland formations belonging to the 2.9–2.8 Ga Mtshingwe Group in the Belingwe greenstone belts in Zimbabwe.

sted, utgiver, år, opplag, sider
Elsevier, 2025
Emneord
Peridotitic komatiite, Pyroxenitic komatiite, Cumulate rocks, Archean greenstone belts, Manica greenstone belt, Zimbabwe craton
HSV kategori
Forskningsprogram
Malmgeologi
Identifikatorer
urn:nbn:se:ltu:diva-110996 (URN)10.1016/j.jafrearsci.2024.105494 (DOI)2-s2.0-85210694642 (Scopus ID)
Forskningsfinansiär
Sida - Swedish International Development Cooperation Agency, 51140073
Merknad

Validerad;2025;Nivå 2;2025-03-20 (u4);

Fulltext license: CC BY

Tilgjengelig fra: 2024-12-10 Laget: 2024-12-10 Sist oppdatert: 2025-03-20bibliografisk kontrollert
Tiu, G., Wanhainen, C., Jansson, N., Liwicki, F. & Sand, A. (2024). Data fusion using machine learning: Towards real-time implementation of geometallurgical modelsfor ore tracking. In: : . Paper presented at 7th International Symposium on Process Mineralogy, Process Mineralogy '24, Cape Town, South Africa, November 11–13, 2024.
Åpne denne publikasjonen i ny fane eller vindu >>Data fusion using machine learning: Towards real-time implementation of geometallurgical modelsfor ore tracking
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2024 (engelsk)Konferansepaper, Oral presentation with published abstract (Fagfellevurdert)
Abstract [en]

This study explores the integration of data fusion using machine learning methods for ore tracking frommine to mill, with the goal of developing predictive geometallurgical models. Conducted at BolidenMineral AB's Garpenberg Zn-Pb-Ag-(Cu-Au) mine in Sweden, the research utilizes extensive geological,operational, and legacy data to create a foundation for a digital twin geometallurgical model for theprocessing plant. By combining 3D geological data with mining and plant operational data, the projectaims to enhance the understanding of ore variability and its impact on processing performance. Thisapproach not only seeks to improve efficiency and reduce variability in production but also providesvaluable insights for more accurate prediction and simulation models in geometallurgy. The outcomesof this research could contribute significantly to the future of data-driven mine planning for optimizedperformance.

HSV kategori
Forskningsprogram
Malmgeologi; Maskininlärning
Identifikatorer
urn:nbn:se:ltu:diva-111062 (URN)
Konferanse
7th International Symposium on Process Mineralogy, Process Mineralogy '24, Cape Town, South Africa, November 11–13, 2024
Tilgjengelig fra: 2024-12-13 Laget: 2024-12-13 Sist oppdatert: 2025-02-07bibliografisk kontrollert
Barbosa, L., Tiu, G., Jansson, N., Wanhainen, C., Lilja, L. & Ghorbani, Y. (2024). Gold occurrence in the footwall of the Lappberget Deposit, Garpenberg Mine, Sweden: Implications for recovery efficiency. Ore Geology Reviews, 171, Article ID 106174.
Åpne denne publikasjonen i ny fane eller vindu >>Gold occurrence in the footwall of the Lappberget Deposit, Garpenberg Mine, Sweden: Implications for recovery efficiency
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2024 (engelsk)Inngår i: Ore Geology Reviews, ISSN 0169-1368, E-ISSN 1872-7360, Vol. 171, artikkel-id 106174Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

By-product metals have a significant potential to bring additional economic benefits to mines. However, a detailed characterization of their distribution is generally required to fulfill this potential and should preferably be integrated into a geometallurgical assessment. This contribution presents a detailed mineralogical and textural investigation of gold-bearing phases at the footwall of the Zn–Pb–Ag–(Cu–Au) Lappberget Deposit, Garpenberg Mine, Sweden, using optical microscopy, scanning electron microscope with energy dispersive spectroscopy (SEM-EDS), electron probe microanalysis (EPMA), laser ablation-inductively coupled plasma mass spectrometer (LA-ICPMS), and bulk chemical analysis applied to drill core and Knelson concentrator samples. Gold is a by-product at the Garpenberg mine, but it is unclear how the mineralogy, occurrence, and distribution of gold-bearing phases impact on gold recoveries during mineral processing. Our results show that Au-dominant electrum is the most abundant gold-bearing phase in the footwall of the Lappberget deposit, occurring strongly associated to sulfides in a variety of textures and grain sizes. Electrum grains commonly occur within sulfide borders, as inclusions, intergrowth and overgrowths of chalcopyrite, pyrite, galena, sphalerite, and pyrrhotite. Gangue minerals may also contain disseminated electrum and inclusions. Electrum grain sizes range from ∼5 µm to 300 µm, predominantly below 100 µm. The potential of sulfide lattice-bound invisible gold in the form of solid-solution gold and colloidal gold was also investigated, showing Au depletion within the analyzed sulfide carriers. The analysis of the concentrate samples from the Knelson gravity concentrator showed 584 and 431 ppm of gold content. High degree of liberation is observed among the gold-bearing phases in the concentrate, and gold recovery is highest among fractions coarser than 106 µm mesh. Pyrite and galena are the most abundant minerals in the concentrate samples. The gold-bearing phases were categorized based on its mineralogy, texture, grain size, and association and their influence on gold processing, especially textures and grain size, which implicates its liberation in milling and recovery by the gravity separator.

sted, utgiver, år, opplag, sider
Elsevier, 2024
Emneord
Gold characterization, Gold as a by-product, Geometallurgy of gold, Lappberget ore, Garpenberg Mine
HSV kategori
Forskningsprogram
Malmgeologi
Identifikatorer
urn:nbn:se:ltu:diva-108390 (URN)10.1016/j.oregeorev.2024.106174 (DOI)001284501400001 ()2-s2.0-85199718431 (Scopus ID)
Merknad

Validerad;2024;Nivå 2;2024-08-14 (sofila);

Full text license CC BY 4.0

Tilgjengelig fra: 2024-07-24 Laget: 2024-07-24 Sist oppdatert: 2024-12-16bibliografisk kontrollert
Rincon, J., Jansson, N., Thomas, H., Kaiser, M. C., Persson, M. F., Nordfeldt, E. & Wanhainen, C. (2024). Ore Remobilization History of the Metamorphosed Rävliden North Volcanogenic Massive Sulfide Deposit, Skellefte District, Sweden. Economic geology and the bulletin of the Society of Economic Geologists, 119(4), 907-934
Åpne denne publikasjonen i ny fane eller vindu >>Ore Remobilization History of the Metamorphosed Rävliden North Volcanogenic Massive Sulfide Deposit, Skellefte District, Sweden
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2024 (engelsk)Inngår i: Economic geology and the bulletin of the Society of Economic Geologists, ISSN 0361-0128, E-ISSN 1554-0774, Vol. 119, nr 4, s. 907-934Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

The Skellefte district in northern Sweden hosts many volcanogenic massive sulfide (VMS) deposits and is considered one of the most important European mining districts for Cu, Zn, Pb, Ag, and Au. The volcanic and sedimentary rocks that the VMS deposits are hosted in were deformed during the Svecokarelian orogeny, with three documented regional deformation phases. These events imparted a distinct attitude and geometry to the deposits, their host succession, and discordant zones of synvolcanic hydrothermal alteration. Few studies have investigated the detailed deformation effects on the sulfide minerals.

In this contribution, we document the structural characteristics and remobilization history of mineralization at the Rävliden North Zn-Pb-Cu-Ag deposit—one of the most important recent discoveries in the district consisting of 8.5 million tonnes (Mt) grading 1.01% Cu, 3.45% Zn, 0.53% Pb, 78.60 g/t Ag, and 0.23 g/t Au. At Rävliden, massive to semimassive sphalerite-rich mineralization with lesser pyrrhotite, galena, pyrite, and silver minerals occurs structurally above stringer-type mineralization dominated by chalcopyrite, pyrrhotite, and pyrite. These mineralization types exhibit evidence of deformation and remobilization such as (1) sulfide-alignment parallel to tectonic foliations; (2) rounded wall-rock tectonoclasts in a ductile deformed sulfide matrix (“ball ore” or durchbewegt ore); and (3) sulfides in tension gashes, strain shadows, piercement veins, and late, straight veinlets crosscutting tectonic fabrics. These features are attributed to polyphase deformation during the D1, D2, and D3 events at temperature ranging from 200° to 550°C. Remobilization of sulfides was mostly within the bounds of the main mineralization (i.e., 10–100 m), with few local external occurrences. A combination of solid-state and fluid-assisted remobilization processes are inferred.

Rare brittle veinlets and zeolite-cemented breccias with sphalerite, galena, and silver minerals occur in the stratigraphic hanging wall, where they crosscut all Svecokarelian structures. This mineralization type is highly reminiscent of Phanerozoic low-T vein- and breccia-hosted Pb-Zn deposits of the Lycksele-Storuman area west of Rävliden North, which have been linked to far-field effects associated with the opening of the Iapetus Ocean (0.7–0.5 Ga). We suggest that this Zn-Pb mineralizing event led to the formation of the late sulfide-zeolite veinlets and breccias at Rävliden North, and that elements such as Ag and Sb within this mineralization were locally remobilized from Rävliden.

sted, utgiver, år, opplag, sider
Society of Economic Geologists, 2024
HSV kategori
Forskningsprogram
Malmgeologi
Identifikatorer
urn:nbn:se:ltu:diva-107577 (URN)10.5382/econgeo.5083 (DOI)001250593500002 ()2-s2.0-85196307375 (Scopus ID)
Forskningsfinansiär
The Geological Survey of Sweden (SGU), 36-2031/2018
Merknad

Validerad;2024;Nivå 2;2024-06-27 (joosat);

Full text license: CC-BY;

Funder: Boliden;

Tilgjengelig fra: 2024-06-18 Laget: 2024-06-18 Sist oppdatert: 2024-11-20bibliografisk kontrollert
Nina, L., Paula-Santos, G. M., Bark, G., Kampmann, T. C., Wanhainen, C. & Blanco, M. (2024). Trace metal geochemistry of Bolivian carbonate rock formations - Patches of life during the Permian mass extinction. Journal of South American Earth Sciences, 148, Article ID 105083.
Åpne denne publikasjonen i ny fane eller vindu >>Trace metal geochemistry of Bolivian carbonate rock formations - Patches of life during the Permian mass extinction
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2024 (engelsk)Inngår i: Journal of South American Earth Sciences, ISSN 0895-9811, E-ISSN 1873-0647, Vol. 148, artikkel-id 105083Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Trace metal (molybdenum, uranium, vanadium, zinc, and nickel) mass changes are used to investigate secular variations in oceanic redox conditions in the succession of Copacabana (Upper Pennsylvanian-Early Permian) and Chutani (Upper Permian) formations of the Titicaca sub-basin (western Bolivia). These trace metal mass variations display evidence of suboxic depositional conditions, with episodes of oxygenation in the shallow carbonate platform of the Titicaca Basin. These episodes are consistent with the unrestricted renewal of deep waters of the Late Pennsylvanian Midcontinent Sea via lateral advection of oxygen-deficient waters of the western tropical Panthalassic Ocean. Trace metals in the Chutani Formation also attest intermittent suboxic conditions with oxic periods being recorded. These results, compared to other Upper Permian sections worldwide, suggest the idea that shallower platforms had oxygen during the mass extinction events of that period.

sted, utgiver, år, opplag, sider
Elsevier Ltd, 2024
Emneord
Titicaca sub-basin, Redox, Seawater chemistry, Late Permian
HSV kategori
Forskningsprogram
Malmgeologi
Identifikatorer
urn:nbn:se:ltu:diva-110082 (URN)10.1016/j.jsames.2024.105083 (DOI)001318113800001 ()2-s2.0-85204024325 (Scopus ID)
Merknad

Validerad;2024;Nivå 2;2024-11-26 (sarsun);

Funder: Swedish Development Agency (SIDA);

Tilgjengelig fra: 2024-09-23 Laget: 2024-09-23 Sist oppdatert: 2025-02-27bibliografisk kontrollert
Tiu, G., Ghorbani, Y., Jansson, N., Wanhainen, C. & Bolin, N.-J. (2023). Quantifying the variability of a complex ore using geometallurgical domains. Minerals Engineering, 203, Article ID 108323.
Åpne denne publikasjonen i ny fane eller vindu >>Quantifying the variability of a complex ore using geometallurgical domains
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2023 (engelsk)Inngår i: Minerals Engineering, ISSN 0892-6875, E-ISSN 1872-9444, Vol. 203, artikkel-id 108323Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

This comprehensive study focuses on the geometallurgical characterization of the complex Lappberget polymetallic Zn-Pb-Ag-(Cu-Au) sulfide deposit at the Garpenberg mine, one of Sweden’s largest and most significant sources of zinc, lead, and silver. The research explores the intricate mineralogy and texture of the ore, investigating its impact on the variability of flotation performance for different ore types. QEMSCAN® analysis and element-to-mineral conversion (EMC) were employed to quantitatively characterize the ore in terms of mineral distribution and occurrence. The study revealed significant variability in Cu-Pb flotation compared to Zn flotation due to the targeted mineral varieties. While zinc primarily occurred in sphalerite grains, Cu-Pb flotation aimed to recover multiple Pb-, Cu-, Ag- and Au-bearing minerals that were finely grained and intricately intergrown with other sulfides. Grain size and the degree of liberation emerged as primary rate-limiting factors, especially in the Zn flotation circuit. Seven geometallurgical domains were defined based on the concentration efficiencies (i.e., selectivity and recovery) for sphalerite, galena, chalcopyrite, and Ag-bearing phases. The proposed geometallurgical characterization approach aims to transform geologically defined classes into geometallurgical domains by relating the deposit's key mineralogical and textural characteristics to metallurgical performance.

sted, utgiver, år, opplag, sider
Elsevier, 2023
Emneord
Zinc-lead-silver deposit, Geometallurgy, Flotation performance, Mineralogy, QEMSCAN, Element-to-mineral conversion
HSV kategori
Forskningsprogram
Malmgeologi
Identifikatorer
urn:nbn:se:ltu:diva-94879 (URN)10.1016/j.mineng.2023.108323 (DOI)001081460900001 ()2-s2.0-85170428284 (Scopus ID)
Forskningsfinansiär
EU, Horizon 2020, 72267
Merknad

Validerad;2023;Nivå 2;2023-09-14 (joosat);

Funder: Boliden Mineral AB

CC BY 4.0 License

This article has previously appeared as a manuscript in a thesis.

Tilgjengelig fra: 2022-12-16 Laget: 2022-12-16 Sist oppdatert: 2024-03-07bibliografisk kontrollert
Ghorbani, S., Hoseinie, S. H., Ghasemi, E., Sherizadeh, T. & Wanhainen, C. (2022). A new rock hardness classification system based on portable dynamic testing. Bulletin of Engineering Geology and the Environment, 81(5), Article ID 179.
Åpne denne publikasjonen i ny fane eller vindu >>A new rock hardness classification system based on portable dynamic testing
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2022 (engelsk)Inngår i: Bulletin of Engineering Geology and the Environment, ISSN 1435-9529, E-ISSN 1435-9537, Vol. 81, nr 5, artikkel-id 179Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Hardness is one of the critical physical characteristics of minerals and rocks, which indicates the resistance of the rock to penetration, scratch, or permanent deformation. As a basic concept, rock hardness has a significant role in rock mechanics and geological engineering and is an appropriate diagnostic tool for the classification of minerals and rocks. The main purpose of this study is to guide rock engineers to measure the rock hardness faster, easier, and more accurately using Leeb’s dynamic hardness test. Accordingly, this paper presents a new rock hardness classification system based on the Leeb dynamic and portable hardness testing method. It is a well-known method for its fast and straightforward procedure testing equipment. A set of 33 different rock types were collected and tested during this study. Next, in-depth microscopic mineralogical studies were performed to determine the precise Mohs hardness value. The Mohs hardness was considered the leading hardness benchmark during the experimental studies, and the Leeb hardness was adopted to classify based on this hardness. A series of laboratory studies and statistical analysis was performed to predict the Shore and Vickers hardness using Leeb hardness. Finally, based on the comparative studies, it is recommended to classify the rocks considering the Leeb hardness method in six different categories: extremely soft (1–250), soft (250–450), moderately soft (450–750), moderately hard (750–850), hard (850–920), and extremely hard (920–1000). The provided classification could be useful in a vast range of rock engineering applications, especially for feasibility studies of rock engineering projects and engineering geology.

sted, utgiver, år, opplag, sider
Springer, 2022
Emneord
Dynamics, Minerals, Rock mechanics, Vickers hardness, Well testing, Classification system, Dynamic hardness, Dynamic testing, Leeb dynamic hardness, Moh hardness, Rock engineering, Rock hardness, Rock hardness classification system, Shore, Vickers, Rocks, classification, dynamic analysis, hardness, physical property, rock mechanics, testing method
HSV kategori
Forskningsprogram
Malmgeologi
Identifikatorer
urn:nbn:se:ltu:diva-90403 (URN)10.1007/s10064-022-02690-3 (DOI)000783159600002 ()2-s2.0-85128064674 (Scopus ID)
Merknad

Validerad;2022;Nivå 2;2022-05-01 (johcin)

Tilgjengelig fra: 2022-04-25 Laget: 2022-04-25 Sist oppdatert: 2022-04-28bibliografisk kontrollert
Crafoord, E., Bark, G. & Wanhainen, C. (2022). Carbon Capture and Storage (CCS) – the potential for mineral carbonation in the Swedish onshore bedrock. In: Þorsteinn Sæmundsson, Ásta Rut Hjartardóttir, Bjarni Gautason, Halldór Geirsson (Ed.), The 35th Nordic Geological Winter Meeting: Program and Abstracts: . Paper presented at 35th Nordic Geological Winter Meeting, Reykjavík, Iceland, May 11-13, 2022. Geoscience Society of Iceland
Åpne denne publikasjonen i ny fane eller vindu >>Carbon Capture and Storage (CCS) – the potential for mineral carbonation in the Swedish onshore bedrock
2022 (engelsk)Inngår i: The 35th Nordic Geological Winter Meeting: Program and Abstracts / [ed] Þorsteinn Sæmundsson, Ásta Rut Hjartardóttir, Bjarni Gautason, Halldór Geirsson, Geoscience Society of Iceland , 2022Konferansepaper, Poster (with or without abstract) (Fagfellevurdert)
sted, utgiver, år, opplag, sider
Geoscience Society of Iceland, 2022
Emneord
CO2, BECCS, mineral carbonation, geological storage, Sweden
HSV kategori
Forskningsprogram
Malmgeologi
Identifikatorer
urn:nbn:se:ltu:diva-94452 (URN)
Konferanse
35th Nordic Geological Winter Meeting, Reykjavík, Iceland, May 11-13, 2022
Merknad

ISBN för värdpublikation: 978-9935-25-178-7

Tilgjengelig fra: 2022-12-01 Laget: 2022-12-01 Sist oppdatert: 2023-02-14bibliografisk kontrollert
Martinsson, O. & Wanhainen, C. (2022). Economic potential of battery metals and minerals in Sweden. In: Anthony B. Christie (Ed.), Proceedings volume for the 16th SGA Biennial Meeting: Volume 1 Introduction and papers. Paper presented at 16th SGA Biennial Meeting 2022, Rotorua, New Zealand, March 28-31, 2022 (pp. 227-230). Society for Geology Applied to Mineral Deposits (SGA)
Åpne denne publikasjonen i ny fane eller vindu >>Economic potential of battery metals and minerals in Sweden
2022 (engelsk)Inngår i: Proceedings volume for the 16th SGA Biennial Meeting: Volume 1 Introduction and papers / [ed] Anthony B. Christie, Society for Geology Applied to Mineral Deposits (SGA) , 2022, s. 227-230Konferansepaper, Publicerat paper (Fagfellevurdert)
Abstract [en]

The potential for battery metal production in Sweden is difficult to predict with the present geological knowledge. The Swedish bedrock are known to containnumerous occurrences of lithium, cobalt, nickel, manganese, vanadium, and graphite, but a waste majority of them have not been studied in any detail recently and data to estimate their potential is therefore limited. However, known alum shales and graphite schists probably constitute world class deposits of vanadium and graphite if extracted and processed in an economically feasible and environmentally responsible manner, while the potential to find significant manganese and cobalt deposits in Sweden is probably low. These metals, as well as vanadium, could rather be extracted from the waste material of active and historic mines. The geology of parts of Sweden also suggests that significant sulphidic nickel deposits might exist, as well as lithium-pegmatites similar to those in the same crustal domain in Finland.

sted, utgiver, år, opplag, sider
Society for Geology Applied to Mineral Deposits (SGA), 2022
HSV kategori
Forskningsprogram
Malmgeologi
Identifikatorer
urn:nbn:se:ltu:diva-90100 (URN)001234906200058 ()
Konferanse
16th SGA Biennial Meeting 2022, Rotorua, New Zealand, March 28-31, 2022
Tilgjengelig fra: 2022-04-07 Laget: 2022-04-07 Sist oppdatert: 2025-02-27bibliografisk kontrollert
Warlo, M., Bark, G., Wanhainen, C., McElroy, I., Björling, A. & Johansson, U. (2022). Extreme-Resolution Synchrotron X-Ray Fluorescence Mapping of Ore Samples. Ore Geology Reviews, 140, Article ID 104620.
Åpne denne publikasjonen i ny fane eller vindu >>Extreme-Resolution Synchrotron X-Ray Fluorescence Mapping of Ore Samples
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2022 (engelsk)Inngår i: Ore Geology Reviews, ISSN 0169-1368, E-ISSN 1872-7360, Vol. 140, artikkel-id 104620Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

In order to maximise profit and sustainability of a mining operation, knowledge of the chemistry, mineralogy, texture, and structure of the ore is essential. Continuous advancements in analytical techniques enable studying these features with increasing detail. Synchrotron radiation X-ray fluorescence is unparalleled in its simultaneously high spatial resolution and detection range. Yet, its application in ore geology research and the mining industry is still in its infancy. This study investigated opportunities of extreme-resolution synchrotron X-ray fluorescence mapping of ore samples. Analysis was performed at the NanoMAX beamline at the MAX IV synchrotron facility in Lund, Sweden. The samples investigated are from the Liikavaara Östra Cu-(W-Au) deposit, northern Sweden. Analysis covered areas of several hundreds of ÎŒm2 in grains of molybdenite, pyrite, and native Bi. Key results included successful mapping of the lattice-bound distribution of Re, Se, and W in molybdenite at 200 nm spot/step size and detection of nanometre inclusions of Au in native Bi at 50 nm spot/step size. Challenges were encountered concerning data acquisition and processing. In order to achieve satisfactory resolution of both light and heavy elements and to limit mapping artefacts, repeated scans of the same area with varied experimental parameters and very thin (quasi-2d) samples are required. For complex geological samples, the software used for analysing spectral data (PyMCA) requires a considerable degree of human examination, which may be a source of error. Overall, synchrotron X-ray fluorescence mapping has a strong analytical potential for ore geology research, in analysing and imaging trace elements that would constitute potential by-products in mining operations. Knowing in detail how these trace elements occur in the ores, appropriate metal extraction programs can be developed, and a larger part of the ore may then be utilized.

sted, utgiver, år, opplag, sider
Elsevier, 2022
Emneord
synchrotron, x-ray fluorescence mapping, nanoscale, trace metals, gold, rhenium, bismuth, molybdenite
HSV kategori
Forskningsprogram
Malmgeologi
Identifikatorer
urn:nbn:se:ltu:diva-88182 (URN)10.1016/j.oregeorev.2021.104620 (DOI)000731503200002 ()2-s2.0-85120981445 (Scopus ID)
Merknad

Validerad;2022;Nivå 2;2022-01-01 (beamah)

Tilgjengelig fra: 2021-12-03 Laget: 2021-12-03 Sist oppdatert: 2025-01-08bibliografisk kontrollert
Organisasjoner
Identifikatorer
ORCID-id: ORCID iD iconorcid.org/0000-0003-4711-7671