The cellulose pulp refining process is crucial for achieving high-quality paper characteristics. This research aims to enhance energy efficiency while maintaining good fiber quality using hydrodynamic and acoustic cavitation (HAC). Experiments were conducted with an in-house developed flow-through sonicator combined with a novel Venturi nozzle for hydrodynamic cavitation. The Venturi design was determined by analytical modeling and verified by CFD simulation with multi-phase turbulence models to balance cavitation intensity and turbulence against the acoustic cavitation effect. Experimental evaluation of two batches of CTMP fibers, pre-processed in different ways, showed significant improvements in paper strength and fiber properties. The best results for Batch 1 (HC and LC) were obtained with 386 kWh/bdt for AC and 350 kWh/bdt for HC (60 °C, 2 % concentration). The tensile strength index increased by 26 %, and the TEA-index, related to freeness, increased by 55 %. HAC treatment (750 kWh/bdt, 70 °C, 1.5 % concentration) of the less refined Batch2 (HC) yielded results better than the Batch 1 reference. These findings confirm the energy-efficient potential of the sonicator concept compared to traditional industrial processes. The conclusion is that HAC-refining of softwood pulp requires a proper balance between hydrodynamic and acoustic cavitation intensities. Both fiber concentration by weight and temperature are critical for an energy-efficient process.

The study focuses on developing a comprehensive design approach for a flow-through ultrasonic reactor (sonicator) to tackle challenges like low energy transfer efficiency and unstable system performance. The simulation accounts for structural vibrations, structural-fluid interactions, and pressure distributions within the cavitation zone under single-frequency excitation. Different geometrical designs of cylindrical sonicators are analyzed, with input parameters tailored to acquire higher acoustic cavitation intensity. The findings reveal a novel hexagonal ring-shaped excitation structure that reduces coupling losses, ensures uniform acoustic pressure distribution, and generates symmetric vibration mode shapes. The study emphasizes the separation of parasitic modes from the desired resonance frequency response and simulates the influence of bubbly liquid properties through complex wave numbers and harmonic responses. Experimental validation on a manufactured prototype, including mechanical and electrical impedance, sound pressure spectrum, and cavitation intensity, supports the simulated results. Ultimately, the sonicator exhibits three feasible resonance frequencies to be used pairwise at the certain temperature and input power interval for different applications.

Fibrillation is identified as the most energy intensive process step in pulp and paper manufacturing and improved energy efficiency is the motivation for development of alternative technologies. The aim of this study is to explore the potential of a new refining concept based on cavitation, focusing on the optimization of acoustic cavitation efficiency of the proposed flow-through sonicator concept. The simulations utilize the linearized wave equation in the frequency domain with an addition of nonlinear attenuation introduced by cavitation bubbles. Verification is made by pressure measurements, calorimetry, and foil tests. The fibrillation capability was validated on chemi-thermo mechanical pulp fibers at low consistencies. Fiber properties was characterized by ultrasonic spectroscopy, fiber analysis and SEM. The objective is to optimize the energy transfer efficiency from electrical input power to acoustic cavitation intensity for efficient fibrillation of cellulose fibers. Results showed changes in fiber dimensions and fiber morphology, however, improvements in tensile strength index, measured and predicted by ultrasonic spectroscopy, was limited to 20 % at an energy level of 804 kWh/bdt. To enhance energy efficiency and paper strength properties, it is suggested to add a hydrodynamic cavitation device prior to the sonicator to initiate cavitation bubbles and to increase turbulence intensity.

Acoustic cavitation has been utilized in many industrial applications to enhance the process intensity. To obtain the most energy-efficient sonochemical activity, the excitation signal specifications are of great importance. This investigation focuses on the effect of different wave characteristics on sonochemical activity including erosion rate and measured sound pressure levels below the surface and beside the high power sonotrode. Signal characteristics as frequency bandwidth, sweep rate, and direction are considered aspects of time signal shape transformation. Altogether eight groups of factors were evaluated in a two-level and replicated design. Numerical simulation has been conducted to achieve the optimized geometrical design and to prevent parasitic modes in sonotrode’s configuration. Results show that negative direction with 100 ms sweep rate and 800 Hz frequency bandwidth generates both the highest sound pressure level and erosion rate. The findings from this study are aimed to be implemented in an energy-efficient flow through sonochemical reactor design.

The primary purpose of this study is to investigate the effects of hydrodynamic and acoustic cavitation (HAC) on the leaching efficiency of tungsten. The aim is to reduce energy use and to improve the recovery rate. The goal is also to carry out a leaching process at a much lower temperature than in an autoclave process that is currently used in the industry. Energy-efficient initiation and collapse of cavitation bubbles require optimization of (i) vibro-acoustic response of the reactor structure, (ii) multiple excitation frequencies adapted to the optimized reactor geometry, and (iii) hydrodynamic cavitation with respect to orifice geometry and flow conditions. The objective is to modify and apply a previously in house developed high power cavitation reactor in order to recover tungsten by leaching of the dissolution of scheelite in sodium hydroxide. In this process, various experimental conditions like dual-frequency excitation, different orifice geometry have been investigated. The numerically optimized reactor concept was excited by two frequencies 23 kHz and 39–43 kHz in various flow conditions. The effects of leaching time, leaching temperature, ultrasonic power and geometry of orifice plates have been studied. The leaching temperature was varied from 40 °C to 80 °C. The concentration of leaching reagent sodium hydroxide (NaOH) was 10 mol/L.The results were compared to conventional chemical leaching. Energy supplement with acoustic cavitation of 130 kWh/kg concentrate resulted in a leaching recovery of tungsten (WO3) of 71.5%, compared to 36.7% obtained in absence of ultrasound. The results confirm that the method developed is energy efficient and gives a recovery rate potentially better than current autoclave technology.

A new model for turbulent fibre suspension flow is proposed by introducing a model for the fibre orientation distribution function (ODF). The coupling between suspended fibres and the fluid momentum is then introduced through the second and fourth order fibre orientation tensors, respectively. From the modelled ODF, a method to construct explicit expressions for the components of the orientation tensors as functions of the flow field is derived. The implementation of the method provides a fibre model that includes the anisotropic detail of the stresses introduced due to presence of the fibres, while being significantly cheaper than solving the transport of the ODF and computing the orientation tensors from numerical integration in each iteration. The model was validated and trimmed using experimental data from flow over a backwards facing step. The model was then further validated with experimental data from a turbulent fibre suspension channel flow. Simulations were also carried out using a Bingham viscoplastic fluid model for comparison. The ODF model and the Bingham model performed reasonably well for the turbulent flow areas, and the latter model showed to be slightly better given the parameter settings tested in the present study. The ODF model may have good potential, but more rigorous study is needed to fully evaluate the model.

The pulp and paper industry is in continuous need for energy-efficient production processes. In the refining process of mechanical pulp, fibrillation is one of the essential unit operations that count for up to 80% of the total energy use. This initial study explores the potential and development of new type of scalable ultrasound reactor for energy efficient mechanical pulping. The developed reactor is of continuous flow type and based on both hydrodynamic and acoustic cavitation in order to modify the mechanical properties of cellulose fibers. A comparison of the prototype tube reactor is made with a batch reactor type where the ultrasonic horn is inserted in the fluid. The pulp samples were sonicated by high-intensity ultrasound, using tuned sonotrodes enhancing the sound pressure and cavitation intensity by a controlled resonance in the contained fluid. The resonant frequency of the batch reactor is 20.8 kHz and for the tube reactor it is 22.8 kHz. The power conversion efficiency for the beaker setup is 25% and 36% in case of the tube reactor in stationary mode. The objective is to verify the benefit of resonance enhanced cavitation intensity when avoiding the effect of Bjerkenes forces. The setup used enables to keep the fibers in the pressure antinodes of the contained fluid. In case of the continuous flow reactor the effect of hydrodynamic cavitation is also induced. The intensity of the ultrasound in both reactors was found to be high enough to produce cavitation in the fluid suspension to enhance the fiber wall treatment. Results show that the mechanical properties of the fibers were changed by the sonification in all tests. The continuous flow type was approximately 50% more efficient than the beaker. The effect of keeping fibers in the antinode of the resonant mode shape of the irradiation frequency was also significant. The effect on fiber properties for the tested mass fraction was determined by a low-intensity ultrasound pulse-echo based measurement method, and by a standard pulp analyzer.

Ultrasound has many uses, such as in medical imaging, monitoring of crystallization, characterization of emulsions and suspensions, and disruption of cell membranes in the food industry. It can also affect microbial cells by promoting or slowing their growth and increasing the production of some metabolites. However, the exact mechanism explaining the effect of ultrasound has not been identified yet. Most equipment employed to study the effect of ultrasound on microorganisms has been designed for other applications and then only slightly modified. This results in limited control over ultrasound frequency and input power, or pressure distribution in the reactor. The present study aimed to obtain a well-defined reactor by simulating the pressure distribution of a sonobioreactor. Specifically, we optimized a sonotrode to match the bottle frequency and compared it to measured results to verify the accuracy of the simulation. The measured pressure distribution spectrum presented the same overall trend as the simulated spectrum. However, the peaks were much less intense, likely due to non-linear events such as the collapse of cavitation bubbles. To test the application of the sonobioreactor in biological systems, two biotechnologically interesting microorganisms were assessed: an electroactive bacterium, Geobacter sulfurreducens, and a lignocellulose-degrading fungus, Fusarium oxysporum. Sonication resulted in increased malate production by G. sulfurreducens, but no major effect on growth. In comparison, morphology and growth of F. oxysporum were more sensitive to ultrasound intensity. Despite considerable morphological changes at 4 W input power, the growth rate was not adversely affected; however, at 12 W, growth was nearly halted. The above findings indicate that the novel sonobioreactor provides an effective tool for studying the impact of ultrasound on microorganisms.

Energy-efficient process intensification is a key aspect for a sustainable industrial production. To improve energy conversion efficiency high intensity cavitation is a promising method, especially in cases where the material to be treated is valuable and on the micro meter scale. Transient collapsing cavitation bubbles gives powerful effects on objects immersed in fluids, like cellulose fibers, mineral particles, enzymes, etc. The cavitation process needs optimization and control, since optimal conditions is multivariate challenge. This study focuses on different design principles to achieve high intensity cavitation in a specific volume in a continuous flow. This study explores some potential design principles to obtain energy efficient process intensification. The objective is to tune several different resonance phenomena to create a powerful excitation of a flowing suspension (two-phase flow and cavitation bubbles). The reactor is excited by sonotrodes, connected to two coupled resonant tube structures, at the critical frequency. Finally cavitation bubbles are initiated by a flow through a venturi nozzle. The acoustically optimised reactor geometry is modelled in Comsol Multiphysics®, and excited by dedicated ultrasound signals at three different frequencies. The effect of the high intensity cavitation is experimentally evaluated by calorimetric method, foil tests and degree of fibrillation on cellulose fibers.

This study investigate the impact of high-intensity ultrasound treatment on the mechanical properties of pulp fibers. The pulp fiber samples are sonicated in an acoustically optimized beaker where high-intensity ultrasound is generated using a tuned sonotrode device. The idea is to create a controlled resonance to efficiently enhance the sound pressure in the beaker. Input power was 90 W. The objective is to define the difference between freely suspended fibers in a beaker compared to keeping fibers in a fixed position. The hypothesis is that fiber treatment at a specific input power will be more efficient in the case when fibers are kept in a high pressure zone. Since the fiber wall is a layered structure, it is likely to delaminate internally which will affect the mechanical properties of the fiber. The effect on fiber properties is verified by measuring the ultrasound attenuation spectra for the treated fibers. The attenuation measurements are based on measurements of a low-intensity ultrasound pulse-echo technique. On a macroscopic scale, changes in the attenuation spectra relates to a change in mechanical properties of the fiber wall, since the suspended fibers more or less retain their diameter and length distributions.