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Filippov, Andrei, PhDORCID iD iconorcid.org/0000-0002-6810-1882
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Publications (10 of 109) Show all publications
Ahmed, M., Kushwaha, A., Filippov, A., Johansson, P. & Shah, F. U. (2025). Saccharinate-based ionic liquids and lithium battery electrolytes. Batteries & Supercaps, Article ID e202400758.
Open this publication in new window or tab >>Saccharinate-based ionic liquids and lithium battery electrolytes
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2025 (English)In: Batteries & Supercaps, E-ISSN 2566-6223, article id e202400758Article in journal (Refereed) Accepted
Place, publisher, year, edition, pages
John Wiley & Sons, 2025
Keywords
Saccharine, ionic liquids, ion transport, electrochemistry, lithium battery electrolytes
National Category
Materials Chemistry
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-111458 (URN)10.1002/batt.202400758 (DOI)
Funder
Swedish Energy Agency, 48194-1Swedish Research Council, #2021-00613
Available from: 2025-01-29 Created: 2025-01-29 Last updated: 2025-01-29
Tatrari, G., Bhowmick, S., Filippov, A., An, R. & Shah, F. U. (2024). Charge storage performance of a structurally flexible hybrid ionic liquid electrolyte. Energy Storage, Article ID e535.
Open this publication in new window or tab >>Charge storage performance of a structurally flexible hybrid ionic liquid electrolyte
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2024 (English)In: Energy Storage, ISSN 2578-4862, article id e535Article in journal (Refereed) Published
Abstract [en]

The electrochemical and charge storage performance of a fluorine-free structurally flexible hybrid pyrrolidinium-based ionic liquid electrolyte (HILE) in a symmetric graphite-based supercapacitor is thoroughly investigated. The HILE revealed thermal decomposition at above 230°C, a glass transition (Tg) temperature of below −70°C, and ionic conductivity of 0.16 mS cm−1 at 30°C. The chemical and electrochemical properties are investigated using a systematic variable temperature 1H and 31P NMR spectroscopy and diffusometry, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic charge-discharge (GCD). The supercapacitor demonstrated a notable specific capacitance of 186 F g−1 at a scan rate of 1 mV s−1 and a specific capacitance of 122 F g−1 at a current density of 0.5 A g−1. The maximum energy density of 48.8 Wh kg−1, a power density of 450 W kg−1 at a current density of 0.5 A g−1, and a potential window of 4 V were obtained. Altogether, this study demonstrates that the new HILE can be used in symmetric graphite-based supercapacitors over a wide potential window of 4 V and a temperature range from −20°C to 90°C. 

Place, publisher, year, edition, pages
John Wiley & Sons, 2024
National Category
Materials Chemistry Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-103048 (URN)10.1002/est2.535 (DOI)001109089200001 ()2-s2.0-85177600157 (Scopus ID)
Funder
European CommissionThe Kempe Foundations, JCK22-0045, SMK21-0013
Note

Validerad;2024;Nivå 1;2024-04-04 (signyg);

License full text: CC BY-NC-ND 4.0

Available from: 2023-11-28 Created: 2023-11-28 Last updated: 2024-12-06Bibliographically approved
Xu, Y., Filippov, A., Shimpi, M. R., Shah, F. U. & Johansson, P. (2024). Fluorine‐Free Bis(glycolato)borate Anion‐Based Salts and Electrolytes: Structures, Properties, and Lithium Compatibility. Batteries & Supercaps
Open this publication in new window or tab >>Fluorine‐Free Bis(glycolato)borate Anion‐Based Salts and Electrolytes: Structures, Properties, and Lithium Compatibility
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2024 (English)In: Batteries & Supercaps, E-ISSN 2566-6223Article in journal (Refereed) Epub ahead of print
Abstract [en]

A number of bis(glycolato)borate (BGB) anion-based salts, comprising Li+, Na+, K+, Mg2+ and Ca2+ cations, has been synthesized and characterized. Fluorine-free electrolytes based on LiBGB and organic solvents, such as dimethyl sulfoxide (DMSO), triethyl phosphate (TEP), and trimethyl phosphate (TMP) have been created and their transport properties, thermal and electrochemical stabilities, and lithium compatibility examined. The ionic conductivities of the 1 M LiBGB-TEP and 1 M LiBGB-TMP electrolytes are ca. 2-3 times lower than for the 1 M LiBGB-DMSO electrolytes (2.05, 2.65 vs. 5.70 mS cm-1 at 25 °C), and as compared to the state-of-the-art 1 M lithium hexafluorophosphate (LiPF6) in EC:DEC (EC:DEC=1:1 in vol., LP40) they display lower ionic conductivities, but the formers’ redox stability on aluminum (Al) and glassy carbon electrodes are much better. Concentrated (>1 M) LiBGB-DMSO electrolytes display enhanced redox stability, but worse Al passivation. Among the electrolytes, 1 M LiBGB-TMP achieves the best long-term stability over 300 h at 0.1 mA/cm2 for Li plating-stripping while the Li compatibility needs to be further improved. Overall, this study introduces a family of versatile fluorine-free orthoborate salts and electrolytes for mono- and divalent batteries, and a fundamental understanding of their transport and electrochemical properties, aiming towards battery applications.

Place, publisher, year, edition, pages
John Wiley & Sons, 2024
National Category
Materials Chemistry
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-110769 (URN)10.1002/batt.202400672 (DOI)001366256400001 ()2-s2.0-85210473493 (Scopus ID)
Available from: 2024-11-21 Created: 2024-11-21 Last updated: 2025-01-14
Xu, Y., Filippov, A., Bhowmick, S., Johansson, P. & Shah, F. U. (2024). Fluorine-Free “Solvent-in-Salt” Sodium Battery Electrolytes: Solvation Structure and Dynamics. Energy Advances, 3(3), 564-573
Open this publication in new window or tab >>Fluorine-Free “Solvent-in-Salt” Sodium Battery Electrolytes: Solvation Structure and Dynamics
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2024 (English)In: Energy Advances, E-ISSN 2753-1457, Vol. 3, no 3, p. 564-573Article in journal (Refereed) Published
Abstract [en]

The solvation structure, dynamics, and transport properties, as well as thermal and electrochemical stabilities of “solvent-in-salt” (SIS) electrolytes, also known as highly concentrated electrolytes, are far from fully understood. Furthermore, these special types of electrolytes are almost without exception based on fluorinated salts. In contrast, here we report on fluorine-free SIS electrolytes comprising ambient temperature liquid sodium bis(2-(2-ethoxyethoxy)ethyl)phosphate (NaDEEP) salt and tris(2-(2-ethoxyethoxy)ethyl)phosphate (TEOP) solvent, for which the ionic conductivities and ion diffusivities are altered profoundly as the salt concentration is increased. A careful molecular level analysis reveals a microstructure with a “solvent-rich” phase with almost an order of magnitude faster ion diffusion than in a “salt-rich” phase. Aggregated ionic structures in these SIS electrolytes lead to higher ionic conductivities alongside lower glass transition temperatures, <−80 °C, but also agreeable thermal stabilities, up to 270 °C, and improved anodic stabilities, possibly up to 7.8 V vs. Na/Na+ and at least >5 V vs. Na/Na+. Altogether, this provides a foundation for both better understanding and further development of fluorine-free SIS electrolytes for sodium batteries.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2024
National Category
Materials Chemistry
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-104259 (URN)10.1039/d4ya00002a (DOI)001166636300001 ()2-s2.0-85186486575 (Scopus ID)
Funder
Swedish Research Council, 2020-00969
Note

Validerad;2024;Nivå 1;2024-04-09 (sofila);

Full text license: CC BY 3.0

Available from: 2024-02-12 Created: 2024-02-12 Last updated: 2024-06-17Bibliographically approved
Filippov, A., Rudakova, M., Archipov, V. P. & Shah, F. U. (2024). Nanoconfinement effects on the dynamics of ionic liquid-based electrolyte probed by multinuclear NMR. Soft Matter (42), 8436-8445
Open this publication in new window or tab >>Nanoconfinement effects on the dynamics of ionic liquid-based electrolyte probed by multinuclear NMR
2024 (English)In: Soft Matter, ISSN 1744-683X, E-ISSN 1744-6848, no 42, p. 8436-8445Article in journal (Refereed) Published
Abstract [en]

The measurement of ion diffusivity inside nanoporous materials by Pulsed-Field Gradient (PFG) NMR is not an easy task due to enhanced NMR relaxation. Here, we employed multinuclear (1H, 31P, and 7Li) NMR spectrometry and diffusometry to probe ion dynamics of a fluorine-free battery electrolyte comprising the [P4,4,4,4][MEEA] ionic liquid (IL) and LiMEEA salt in a 7 : 3 molar ratio, confined in three different nanoporous SiO2 glasses with pore diameters of 3.7, 7 and 98 nm. Confinement of the electrolyte leads to NMR resonance line broadening and variation in the 31P and 7Li NMR chemical shifts. The complicated diffusion decays are explained taking into consideration the complex porous structure of the porous glasses, the presence of pore “necks” and the “partially isolated volumes” containing the liquid, which is in a “slow exchange” regime with the rest of the liquid. The mean apparent diffusivity is controlled by the exchange of ions between the “narrow” and the “large” pores and the boundary separating these pores to measure diffusion coefficients by PFG NMR is in the range of pore sizes of Vycor and Varapor. The temperature-dependent ion diffusivities in the “large” pores deviate from the Arrhenius law and the exchange of diffusing units between the “narrow” and the “large” pores leads to abnormal temperature-dependent diffusion coefficients. Like the bulk, diffusivity of the small Li+ is slower than that of the larger organic ions in the confinement, demonstrating the solvation of Li+ inside the pores.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2024
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-110285 (URN)10.1039/d4sm01058b (DOI)001330649700001 ()39397718 (PubMedID)2-s2.0-85206457046 (Scopus ID)
Funder
Swedish Research Council Formas, 2020-00969
Note

Validerad;2024;Nivå 2;2024-11-19 (signyg);

Fulltext licence: CC BY

Available from: 2024-10-08 Created: 2024-10-08 Last updated: 2024-12-10Bibliographically approved
Filippov, A., Gnezdilov, O. I., Rudakova, M., Gimatdinov, R., Arkhipov, V. P. & Antzutkin, O. N. (2024). NMR study of nitrate ionic liquids confined between micrometerspaced plates. Applied Chemical Engineering, 7(2), Article ID ACE-5462.
Open this publication in new window or tab >>NMR study of nitrate ionic liquids confined between micrometerspaced plates
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2024 (English)In: Applied Chemical Engineering, E-ISSN 2578-2010, Vol. 7, no 2, article id ACE-5462Article in journal (Refereed) Published
Abstract [en]

This review paper presents the results of a study conducted using nuclear magnetic resonance (NMR) methods to investigate the dynamic behaviour of ionic liquid-based compositions in micrometre-spaced confinement. Ethylammonium nitrate (EAN) and other ionic liquid (IL) systems with nitrate anion in glass or quartz spaced confinement demonstrate anomalous cation dynamics that differ from those observed in bulk and in nano-confinement. It was demonstrated that the principal axis of the nitrate anion exhibits preferential orientation to the surface, akin to that in liquid crystals. It was shown that the cation translational mobility reversibly changes during exposure to a static magnetic field. This phenomenon was interpreted as a result of intermolecular structure transformations occurring in the confined ILs. The mechanisms of these transformations were discussed.

Place, publisher, year, edition, pages
Arts and Science Press Pte. Ltd., 2024
Keywords
confined ionic liquid, diffusivity, ion dynamics, phase transformation
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-108391 (URN)10.59429/ace.v7i2.5462 (DOI)2-s2.0-85197416769 (Scopus ID)
Funder
Swedish Foundation for Strategic Research, EM16-0013
Note

Godkänd;2024;Nivå 0;2024-07-31 (signyg);

Funder: Kazan Federal University (FZSM-2023-0016);

Full text license: CC BY

Available from: 2024-07-31 Created: 2024-07-31 Last updated: 2024-07-31Bibliographically approved
Ahmed, M., Filippov, A., Johansson, P. & Shah, F. U. (2024). Pyrrolidium- and Imidazolium-Based Ionic Liquids and Electrolytes with Flexible Oligoether Anions. ChemPhysChem, 25(9), Article ID e202300810.
Open this publication in new window or tab >>Pyrrolidium- and Imidazolium-Based Ionic Liquids and Electrolytes with Flexible Oligoether Anions
2024 (English)In: ChemPhysChem, ISSN 1439-4235, E-ISSN 1439-7641, Vol. 25, no 9, article id e202300810Article in journal (Refereed) Published
Abstract [en]

A new class of fluorine-free ionic liquids (ILs) and electrolytes based on aliphatic flexible oligoether anions, 2-(2-methoxyethoxy)acetate (MEA) and 2-[2-(2-methoxyethoxy)ethoxy]acetate (MEEA), coupled with pyrrolidinium and imidazolium cations is introduced. For the ILs with MEEA anions, Li+ conducting electrolytes are created by doping the ILs with 30 mol % of LiMEEA. The structural flexibility of the oligoether functionality in the anion results in glass transition temperatures (Tg) as low as −60 °C for the neat ILs and the electrolytes. The imidazolium-based ILs and electrolytes reveal better thermal stabilities but higher Tg and lower electrochemical stabilities than the corresponding pyrrolidinium-based analogues. All neat ILs show comparable transport properties for the cations and these decrease by the addition of lithium salt – the pyrrolidinium-based electrolyte being affected the most.

Place, publisher, year, edition, pages
John Wiley & Sons, 2024
National Category
Energy Engineering
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-104277 (URN)10.1002/cphc.202300810 (DOI)001175326700001 ()38349198 (PubMedID)2-s2.0-85186208330 (Scopus ID)
Funder
Swedish Energy Agency, 48194-1
Note

Validerad;2024;Nivå 2;2024-05-22 (joosat);

Full text: CC BY license

Available from: 2024-02-14 Created: 2024-02-14 Last updated: 2024-11-20Bibliographically approved
Sashina, A. N., Khakimzyanova, A. R., Khakimov, A. M., Filippov, A. V. & Khaliullina, A. V. (2024). Structure and Mobility of the Lipid System in Mixtures of Ethylammonium Nitrate and Water: Magnetic Resonance Measurements and Molecular Dynamics Simulations. Applied Magnetic Resonance
Open this publication in new window or tab >>Structure and Mobility of the Lipid System in Mixtures of Ethylammonium Nitrate and Water: Magnetic Resonance Measurements and Molecular Dynamics Simulations
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2024 (English)In: Applied Magnetic Resonance, ISSN 0937-9347, E-ISSN 1613-7507Article in journal (Refereed) Epub ahead of print
Abstract [en]

Ionic liquids (ILs) are salts which persist in liquid state near room temperature. They are characterized by high thermal and chemical resistance, good solubility, and high ionic conductivity. ILs can be used as permeability enhancers for transdermal delivery of drugs. The study of the interaction of ILs with lipids is important for understanding their potential toxicity to cells and the environment. In this work, we discuss features of the molecular structure and mobility of the aqueous system consisting of 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) and ethylammonium nitrate ionic liquid (EAN) mixtures studied by NMR and computer simulation MD methods. The 31P NMR line shape analysis revealed two lipid states in the systems: in D2O it is a lamellar liquid crystalline state associated with the formed vesicle-like structures of DMPC, while in EAN it is isotopic. The ratio of these states correlates with the ratio of solvents in the system. Based on the self-diffusion coefficients obtained by NMR, sizes of the diffusing particles were estimated. The method of MD showed that DMPC molecules assemble into micelles in the presence of water. In the mixtures of EAN and water the configuration of DMPC molecules changed. When DMPC interacts only with EAN, the micelle disintegrates. It is thus inferred that the presence of IL in the environment significantly affects the structure of the lipid system. The comparative analysis of the SDCs revealed a correlation between values obtained by MD and NMR methods.

Place, publisher, year, edition, pages
Springer Nature, 2024
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-110922 (URN)10.1007/s00723-024-01739-8 (DOI)001366650400001 ()2-s2.0-85210551868 (Scopus ID)
Available from: 2024-12-02 Created: 2024-12-02 Last updated: 2024-12-17
Arkhipov, V. P., Arkhipov, R. V. & Filippov, A. (2024). The efficiency of micellar solubilization of naphthalene from aqueous solutions using rhamnolipid as a biological surfactant according to NMR diffusometry. Magnetic Resonance in Chemistry, 62(10), 712-717
Open this publication in new window or tab >>The efficiency of micellar solubilization of naphthalene from aqueous solutions using rhamnolipid as a biological surfactant according to NMR diffusometry
2024 (English)In: Magnetic Resonance in Chemistry, ISSN 0749-1581, E-ISSN 1097-458X, Vol. 62, no 10, p. 712-717Article in journal (Refereed) Published
Abstract [en]

The micellar solubilization of naphthalene from its saturated aqueous solutions using the biosurfactant rhamnolipid was studied. Using the NMR diffusion method, selective measurements of the self-diffusion coefficients of molecules of all components of the solution—naphthalene, rhamnolipid, and water—were carried out at various rhamnolipid concentrations from 0.06 to 100 g/L. Based on the results of diffusometry, the distribution of naphthalene molecules between the states free in solution and states bound by micelles was found. With an increase in the concentration of rhamnolipids, the proportion of bound naphthalene molecules increases from 50% at CRL = 2 g/L to 100% at CRL ≥ 50 g/L. The micelle-water partition coefficient Km and the molar solubilization ratio MSR were calculated.

Place, publisher, year, edition, pages
John Wiley & Sons, 2024
Keywords
diffusometry, micelles, naphthalene, NMR, rhamnolipid, solubilization
National Category
Other Chemical Engineering
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-106179 (URN)10.1002/mrc.5468 (DOI)001235131300001 ()38816348 (PubMedID)2-s2.0-85194742316 (Scopus ID)
Note

Validerad;2024;Nivå 2;2024-09-11 (joosat);

Full text license: CC BY;

Funder: Kazan Federal University (FZSM-2023-0016)

Available from: 2024-06-12 Created: 2024-06-12 Last updated: 2024-12-16Bibliographically approved
Arkhipov, V. P., Arkhipov, R. V., Kuzina, N., Petrova, E. V. & Filippov, A. (2023). Aggregation Properties of Triton X-100 in a Mixture of Ordinary and Heavy Water. Applied Magnetic Resonance, 54(3), 415-425
Open this publication in new window or tab >>Aggregation Properties of Triton X-100 in a Mixture of Ordinary and Heavy Water
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2023 (English)In: Applied Magnetic Resonance, ISSN 0937-9347, E-ISSN 1613-7507, Vol. 54, no 3, p. 415-425Article in journal (Refereed) Published
Abstract [en]

The dynamic and aggregation properties of Triton X-100 in a mixture of ordinary and heavy water in a wide temperature range from room temperature to the cloud point and above were studied. The ratio of ordinary and heavy water was calculated in such a way as to ensure equal densities of Triton X-100 and the water mixture. This made it possible to exclude the effects of sedimentation and study the evolution of Triton X-100 micelles and aggregates, without complication by the effects of spatial phase separation above the cloud point. Self-diffusion coefficients of Triton X-100 molecules were measured by NMR, and the effective hydrodynamic radii of micelles and aggregates were calculated using the Stokes-Einstein relation. The anomalous temperature behavior of the diffusion coefficient of Triton X-100 molecules is explained by changes in the sizes of diffusing objects during their evolution from micelles to dehydrated aggregates below the cloud point and by changes in the sizes of aggregates above the cloud point. The results of the NMR studies are confirmed by data obtained by dynamic light scattering.

Place, publisher, year, edition, pages
Springer Nature, 2023
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
urn:nbn:se:ltu:diva-95862 (URN)10.1007/s00723-023-01529-8 (DOI)000934332600001 ()2-s2.0-85147927821 (Scopus ID)
Note

Validerad;2023;Nivå 2;2023-03-15 (hanlid);

Funder: Ministry of Science and Higher Education of the Russian Federation (075-10-2021-115); Program Priority-2030 for Kazan Federal University

Available from: 2023-03-13 Created: 2023-03-13 Last updated: 2023-03-15Bibliographically approved
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ORCID iD: ORCID iD iconorcid.org/0000-0002-6810-1882

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