Over the years, fretting has been a leading cause of fuel failures for water cooled nuclear reactors. Implementation of liquid lead coolant increases the need for fretting and corrosion-resistant materials. Fe–10Cr–4Al alloy has shown good resistance to thermal aging, oxidation, liquid metal corrosion, and embrittlement in liquid lead environment. The performance of Fe-10Cr-4Al under fretting wear conditions has not been studied previously. This work aims to investigate the fretting wear and friction behaviour of self-mated Fe-10Cr-4Al alloy at varying temperatures, in the presence of a reducing gas environment and liquid lead. The results show that an increase in test temperature from RT to 550 °C decreases the coefficient of friction and promotes the formation of Cr and Fe oxide third body layer. At high temperature in reducing gas atmosphere, the initial plastic deformation and severe adhesion leads to early seizure. Presence of liquid lead has a lubricating effect and allows a third body layer to form on worn surfaces. A detailed description of the initial wear mechanisms of Fe-10Cr-4Al alloy and friction levels under various conditions provides a base for further investigation of this alloy for long-duration fretting wear.

Additive manufacturing (AM) of ferrous alloys has achieved a technological maturity level that allows for the production of high-performance steel components. Among these alloys, tool steels and maraging steels can be used in die manufacturing for different hot forming processes as both materials have good mechanical properties and thermal stability. In recent years, several works have successfully produced these alloys through selective laser melting, focusing on the optimization and characterization of their microstructure and mechanical properties. However, few studies look into the tribological aspects of these newly produced materials and even fewer consider high temperature friction and wear performance. Therefore, there is a need to understand the high temperature tribological response of tool materials produced by additive manufacturing. In this context, the aim of this work is to investigate the tribological behavior of a tool steel and a maraging steel, both produced by selective laser melting, at different elevated temperatures. A conventionally produced tool steel was used as reference. A reciprocating sliding tribometer was used to perform tests at 40 °C, 200 °C and 400 °C. The counter-body was a WC-Co cemented carbide. Friction and wear of the AM tool steel and reference tool steel were very similar, thus no signs of the AM route having an impact on the tribological behavior were observed. Both tool steels showed reduced wear volume with increasing temperature, while the opposite was observed for their respective WC-Co counter-bodies. Higher temperature also resulted in increased amount of W transferred onto the tool steel wear scars. AM maraging steel showed higher and more unstable friction level, as well as a much larger wear volume at all temperatures; material transfer onto WC-Co was observed at certain temperatures. Overall, tribolayer formation (or lack thereof) was the dominant aspect in the tribological responses.

The increasing interest in liquid metal cooled nuclear reactors provides technical and scientific challenges such as the understanding, prevention, and prediction of the degradation of materials in liquid lead. Critical components include the fuel rods, heat exchanger tubes, and pump impellers. These functional elements are exposed to mechanical loading (up to 40 MPa), high temperatures (450–550 °C), and fluid-induced vibrations (up to 25 Hz). Under such conditions, fretting wear occurs between e.g., the spacer wire and the outer surface of the fuel or heat exchanger tubes. This work is aimed to establish a laboratory-scale fretting wear test setup and develop test methodology to enable systematic material characterisation in liquid metal environments. The results obtained by using the described methodology indicate that adhesive wear is the dominant degradation mechanism, and 316L stainless steel shows a higher coefficient of friction but a lower wear volume/tribolayer volume compared to 100Cr6 bearing steel. These results are in agreement with those reported in open literature and demonstrates the suitability of the presented method for conducting fretting tests and analysis for various materials and contact configurations in liquid lead environment.

Wear is a complex phenomenon taking place as two bodies in relative motion are brought into contact with each other. There are many different types of wear, for example, sliding, fretting, surface fatigue, and combinations thereof. Wear occurs over a wide range of scales, and it largely depends on the mechanical properties of the material. For instance, at the micro-scale, sliding wear is the result of material detachment that occurs due to fracture. An accurate numerical simulation of sliding wear requires a robust and efficient solver, based on a realistic fracture mechanics model that can handle large deformations. In the present work, a fully coupled thermo-mechanical and meshfree approach, based on the momentum-consistent smoothed particle Galerkin (MC-SPG) method, is adapted and employed to predict wear of colliding asperities. The MC-SPG-based approach is used to study how plastic deformation, thermal response, and wear are influenced by the variation of the vertical overlap between colliding spherical asperities. The findings demonstrate a critical overlap value where the wear mechanism transitions from plastic deformation to brittle fracture. In addition, the results reveal a linear relationship between the average temperature and the increasing overlap size, up until the critical overlap value. Beyond this critical point, the average temperature reaches a steady-state value.

There is a high demand for environmentally friendly lubricants in order to support a transition to sustainable transport and manufacturing since conventional mineral oils derived from fossil sources are inherently harmful for the environment. Glycerol aqueous solutions have the potential to be used as environmentally friendly base fluids, due to their high solubility in water, and non-toxicity. In this investigation a micropitting test rig (MPR), was used to study the friction, wear and micropitting behaviour of Glycerol-based lubricants in a rolling/sliding contact. Micropitting and wear profiles were analysed through optical profilometry, and the morphology and evolution of micropits were studied trough scanning electron microscopy (SEM). The results showed that the steel-steel contact lubricated with a Glycerol-water-glycol lubricant reduced mild-wear, promoting micro-pitting as a main failure mode at low sliding levels compared to a commercial fully formulated gear oil. It was also shown that friction was significantly lower for the Glycerol-water and Glycerol-water-glycol lubricants which is mainly attributed to an effect of a low pressure-viscosity coefficient.

Iron-based coatings with the incorporation of solid lubricants have been prepared by means of laser cladding, in an effort to control friction and decrease tool wear at high temperatures during metal forming applications. The choice of a Fe-based powder has been considered advantageous, as it can lead to decreased costs compared to nickel-based claddings previously studied by the authors, in addition to having a lower environmental impact. In particular, the incorporation of transition metal dichalcogenides such as MoS2 as precursors leads to the encapsulation of silver in Fe-based self-lubricating claddings, resulting in a uniform distribution of the soft metal across the thickness of the coating. Subsequent tribological evaluation of the claddings at high temperatures shows that the addition of lubricious compounds leads to lower friction at room temperature and significantly decreased wear up to 600 °C compared to the unmodified iron-based reference alloy, although higher than similar self-lubricating Ni-based claddings. In order to cast light into these observed differences, the corresponding microstructures, phase composition, and self-lubricating mechanisms have been studied and compared for Fe- and Ni-based claddings having both of them the addition of silver and MoS2. The results suggest a key role of the formation of protective tribolayers on the counter body during high temperature sliding contact. Additional simulation of the phase evolution during solidification reveals that the formation of different chromium- and nickel-based metal sulfides in Fe- and Ni-claddings during laser cladding by the decomposition of MoS2 plays a key role in determining their tribological behaviour at high temperatures.

Hot stamping is characterised by severe contact conditions, especially when forming aluminium components. In order to improve the tool lifetime, process economy, and component quality, understanding the initiation mechanisms behind aluminium transfer onto the tool surface at high temperatures is critical. To date, the tribological interaction between tools and aluminium sheets at high temperature has received limited attention. Lubricants, combined with surface engineering techniques (e.g. coatings, nitriding and surface topography control), show great potential for reducing the severity of material transfer at high temperatures. However, there is still, limited knowledge about their interaction and performance in this tribological context. In this study, high temperature tribological tests were carried out to characterise the synergetic effects of surface coatings/treatments with and without lubrication on friction and wear. A commercially available lubricant was evaluated when used in combination with uncoated, nitrided and CrWN- or DLC ta-C-based PVD coated tool steel. The tests were carried out on a hot strip drawing tribometer, employing an open contact configuration representative of the hot stamping contact conditions at two different temperatures. The counter-material was a 6082 aluminium alloy, heated up following a thermal cycle relevant for the hot stamping process. The results showed that the tribological response was highly dependent on the retention of the lubricant in the contact and the type of surface modification technique. The results show that bonding of the lubricant to the tool surface is critical. In the case of lubricant failure, severe adhesive wear and aluminium transfer onto the tool surface occurred, correlated with an increase in friction. The use of different surface engineering methods led to different results: lower friction levels could be reached when combining use of lubricant and PVD coatings compared to using uncoated or plasma nitrided tool steel. In this study, the best combination to minimise aluminium transfer and friction is the association of the lubricant with CrWN PVD coating in this study.

Aluminium alloys are commonly used as lightweight materials in the automotive industry. This non-ferrous family of metallic alloys offers a high versatility of properties and designs. To reduce weight and improve safety, high strength-to-weight ratio alloys (e.g. 6XXX and 7XXX), are increasingly implemented in vehicles. However, these alloys exhibit low formability and experience considerable springback during cold forming, and are therefore hot formed. During forming, severe adhesion (i.e. galling) of aluminium onto the die surface takes place. This phenomenon has a detrimental effect on the surface properties, geometrical tolerances of the formed parts and maintenance of the dies. The effect of surface engineering as well as lubricant chemistry on galling has not been sufficiently investigated. Diamond-like carbon (DLC) and CrN physical vapour deposition (PVD) coated steel have been studied to reduce aluminium transfer. However, the interaction between lubricants and PVD coatings during hot forming of aluminium alloys is not yet fully understood. The present study thus aims to characterise the high temperature tribological behaviour of selected PVD coatings and lubricants during sliding against aluminium alloy. The objectives are to first select promising lubricant-coating combinations and then to study their tribological response in a high-temperature reciprocating friction and wear tester. Dry and lubricated tests were carried out at 300 °C using a commercial polymer lubricant. Tests using DLC, CrN, CrTiN, and CrAlN coated tool steel were compared to uncoated tool steel reference tests. The initial and worn test specimen surfaces were analysed with a 3-dimensional (3D) optical profiler, scanning electron microscope (SEM) and energy dispersive X-ray spectroscope (EDS) as to understand the wear mechanisms. The results showed formation of tribolayers in the contact zone, reducing both friction and wear. The stability of these layers highly depends on both the coatings’ roughness and chemical affinity towards aluminium. The DLC and CrN coatings combined with the polymer lubricant were the most effective in reducing aluminium transfer.