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Wang, D., Zhao, J., Claesson, P., Christakopoulos, P., Rova, U., Matsakas, L., . . . Shi, Y. (2024). A strong enhancement of corrosion and wear resistance of polyurethane-based coating by chemically grafting of organosolv lignin. Materials Today Chemistry, 35, Article ID 101833.
Open this publication in new window or tab >>A strong enhancement of corrosion and wear resistance of polyurethane-based coating by chemically grafting of organosolv lignin
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2024 (English)In: Materials Today Chemistry, E-ISSN 2468-5194, Vol. 35, article id 101833Article in journal (Refereed) Published
Abstract [en]

Corrosion and wear pose significant challenges to equipment operating in harsh environments. Thus, protective coatings are needed. Anti-corrosion and anti-wear coatings are traditionally fossil-based and often contain environmentally harmful additives. Achieving anti-corrosion and anti-wear coatings based on environmentally benign and sustainable materials is important and a significant challenge. This work focused on the development of organosolv lignin-based polyurethane (OS_lignin-PU) coatings. The coatings were synthesised and evaluated for corrosion protection using electrochemical impedance spectroscopy (EIS) and for wear properties using nanoindentation and nano scratch measurements. EIS revealed that the optimal lignin content for corrosion protection purposes in the OS_lignin-PU coatings was 15 wt%. Moreover, addition of 15 wt% lignin to the OS_lignin-PU coatings also enhanced their wear resistance, as evidenced by reduced thickness loss during tribometer tests. The nano scratch measurements revealed that OS_lignin-PU coatings containing 15 wt% lignin exhibited the lowest scratch depth and friction coefficient. It is found that the developed lignin-containing coating exhibits remarkable corrosion and wear resistance, making it a promising sustainable material in various applications for pursuing sustainable development.

Place, publisher, year, edition, pages
Elsevier, 2024
Keywords
Organosolv lignin, Polyurethane, Coating, Anti-corrosion, Wear resistance
National Category
Corrosion Engineering
Research subject
Machine Elements; Biochemical Process Engineering
Identifiers
urn:nbn:se:ltu:diva-103257 (URN)10.1016/j.mtchem.2023.101833 (DOI)001135558500001 ()2-s2.0-85179131576 (Scopus ID)
Funder
Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning, (Formas, Project No. 2022- 01047, 2021-00728, 2020-01258)
Note

Validerad;2023;Nivå 2;2023-12-08 (joosat);

Full text: CC BY License;

Funder: Engineering and Physical Sciences Research Council (EPSRC), (EP/Y022009/1);

Available from: 2023-12-08 Created: 2023-12-08 Last updated: 2024-03-07Bibliographically approved
Wang, D., Zhao, J., Claesson, P., Zhang, F., Pan, J. & Shi, Y. (2024). Green synergy: Eco-friendly, high-performance anti-corrosion and wear-resistant coatings utilizing organosolv lignin and polydimethylsiloxane. Progress in organic coatings, 190, Article ID 108365.
Open this publication in new window or tab >>Green synergy: Eco-friendly, high-performance anti-corrosion and wear-resistant coatings utilizing organosolv lignin and polydimethylsiloxane
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2024 (English)In: Progress in organic coatings, ISSN 0300-9440, E-ISSN 1873-331X, Vol. 190, article id 108365Article in journal (Refereed) Published
Abstract [en]

Anti-corrosion and anti-wear coatings provide an effective solution. However, traditional coatings are often fossil-based and contain heavy metals, posing environmental concerns. The drive for eco-friendly coatings has led to the exploration of green materials. This study combined lignin, an abundant organic material, and polydimethylsiloxane (PDMS), a known hydrophobic material, to address the challenges. Organosolv lignin was functionalised with (3-Aminopropyl)triethoxysilane (APTES), then chemically grafted on PDMS for the final coating synthesis. The optimised coating achieved through an eco-friendly process, exhibiting enhanced hydrophobicity and barrier properties, showing excellent long-term corrosion resistance in NaCl solution. The optimal coating formulation contained 15 wt% lignin and 40 wt% PDMS, demonstrating a high corrosion resistance (measured impedance of 1010 Ω·cm2), which remains effective even after 3 weeks of immersion in 1 M NaCl solution. This coating also showed good wear resistance, with a low friction coefficient evident from nano scratch tests.

Place, publisher, year, edition, pages
Elsevier B.V., 2024
Keywords
Anti-corrosion, Coating, Organosolv lignin, Polydimethylsiloxane, Wear resistance
National Category
Corrosion Engineering
Research subject
Machine Elements
Identifiers
urn:nbn:se:ltu:diva-104879 (URN)10.1016/j.porgcoat.2024.108365 (DOI)2-s2.0-85187216477 (Scopus ID)
Note

Validerad;2024;Nivå 2;2024-04-05 (marisr);

Funder: Swedish Research Council for Environment, Agricultural Sciences and Spatial Planning (Formas (2019-00904, 2022-01047, 2022-01988); Swedish Research Council (2019-04941); Engineering and Physical Sciences Research Council (EP/Y022009/1); Svenska Forskningsrådet Formas; Vetenskapsrådet;

Full text license: CC BY

Available from: 2024-03-26 Created: 2024-03-26 Last updated: 2024-04-05Bibliographically approved
Wang, D., Zhao, J., Zhang, F., Claesson, P., Pan, J. & Shi, Y. (2023). In-situ coating wear condition monitoring based on solid-liquid triboelectric nanogenerator and its mechanism study. Nano Energy, 112, Article ID 108479.
Open this publication in new window or tab >>In-situ coating wear condition monitoring based on solid-liquid triboelectric nanogenerator and its mechanism study
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2023 (English)In: Nano Energy, ISSN 2211-2855, E-ISSN 2211-3282, Vol. 112, article id 108479Article in journal (Refereed) Published
Abstract [en]

Various more or less wear-resistant coatings have been developed and used to protect metal substrates. However, the damage caused by wear is still a problem for most coatings. It is of great importance to monitor the wear of coatings in real-time during the applications. Recently reported wear monitoring methods (image processing, luminescent layers and the use of a sensing underlayer) require complex external equipment or additional coating preparation process steps, which limit their applications. As an emerging technology, a triboelectric nanogenerator (TENG) can convert mechanical energy into electricity, and it has been applied as a self-powered sensor. In this study, a new coating wear monitoring method is developed based on a solid-liquid TENG. The developed TENG generates electric signals corresponding to different wear states, which facilitates easy monitoring of the coating’s wear conditions. The results show that the surface composition change caused by wear is the main reason affecting the TENG signal output. The coating-liquid contact-separation motion generates real-time output signals that directly reflect the coating wear states without the need of any additional equipment. This study provides a promising new technology for in-situ coating wear monitoring.

Place, publisher, year, edition, pages
Elsevier Ltd, 2023
Keywords
Coating, in-situ monitoring, Triboelectric nanogenerator, Wear
National Category
Tribology (Interacting Surfaces including Friction, Lubrication and Wear)
Research subject
Machine Elements
Identifiers
urn:nbn:se:ltu:diva-97061 (URN)10.1016/j.nanoen.2023.108479 (DOI)000998596100001 ()2-s2.0-85154563802 (Scopus ID)
Funder
Swedish Research Council Formas, (2019-00904, 2022-01047)Swedish Research Council, (2019–04941)
Note

Validerad;2023;Nivå 2;2023-05-10 (joosat);

Licens fulltext: CC BY License

Part of Special Issue: "Triboelectric and piezoelectric advances in Europe and North America". Edited by Renyun Zhang, Wenzhuo Wu, Chris Bowen, Philippe Basset, Christian Falconi, Ana Borras, Stephanos Konstantinidis, Rainer Adelung, Joao Ventura

Available from: 2023-05-10 Created: 2023-05-10 Last updated: 2024-03-07Bibliographically approved
Zhao, J., Wang, D., Zhang, F., Pan, J., Claesson, P., Larsson, R. & Shi, Y. (2022). Self-Powered, Long-Durable, and Highly Selective Oil–Solid Triboelectric Nanogenerator for Energy Harvesting and Intelligent Monitoring. Nano-Micro Letters, 14(1), Article ID 160.
Open this publication in new window or tab >>Self-Powered, Long-Durable, and Highly Selective Oil–Solid Triboelectric Nanogenerator for Energy Harvesting and Intelligent Monitoring
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2022 (English)In: Nano-Micro Letters, ISSN 2311-6706, Vol. 14, no 1, article id 160Article in journal (Refereed) Published
Abstract [en]

Triboelectric nanogenerators (TENGs) have potential to achieve energy harvesting and condition monitoring of oils, the “lifeblood” of industry. However, oil absorption on the solid surfaces is a great challenge for oil–solid TENG (O-TENG). Here, oleophobic/superamphiphobic O-TENGs are achieved via engineering of solid surface wetting properties. The designed O-TENG can generate an excellent electricity (with a charge density of 9.1 µC m−2 and a power density of 1.23 mW m−2), which is an order of magnitude higher than other O-TENGs made from polytetrafluoroethylene and polyimide. It also has a significant durability (30,000 cycles) and can power a digital thermometer for self-powered sensor applications. Further, a superhigh-sensitivity O-TENG monitoring system is successfully developed for real-time detecting particle/water contaminants in oils. The O-TENG can detect particle contaminants at least down to 0.01 wt% and water contaminants down to 100 ppm, which are much better than previous online monitoring methods (particle > 0.1 wt%; water > 1000 ppm). More interesting, the developed O-TENG can also distinguish water from other contaminants, which means the developed O-TENG has a highly water-selective performance. This work provides an ideal strategy for enhancing the output and durability of TENGs for oil–solid contact and opens new intelligent pathways for oil–solid energy harvesting and oil condition monitoring.

Place, publisher, year, edition, pages
Springer Nature, 2022
Keywords
Oil, Triboelectric nanogenerator, Energy harvesting, Intelligent monitoring
National Category
Other Materials Engineering
Research subject
Machine Elements
Identifiers
urn:nbn:se:ltu:diva-92427 (URN)10.1007/s40820-022-00903-8 (DOI)000836616600001 ()35930162 (PubMedID)2-s2.0-85136323285 (Scopus ID)
Funder
Swedish Research Council Formas, 2019-00904Swedish Research Council, 2019-04941Stiftelsen Seth M. Kempes Minnes Stipendiefond, JCK-1903.1
Note

Validerad;2022;Nivå 2;2022-08-10 (hanlid);

Funder: National Natural Science Foundation of China (51905027)

Available from: 2022-08-10 Created: 2022-08-10 Last updated: 2023-09-05Bibliographically approved
Zhao, J., Wang, D., Zhang, F., Liu, Y., Chen, B., Wang, Z. L., . . . Shi, Y. (2021). Real-Time and Online Lubricating Oil Condition Monitoring Enabled by Triboelectric Nanogenerator. ACS Nano, 15(7), 11869-11879
Open this publication in new window or tab >>Real-Time and Online Lubricating Oil Condition Monitoring Enabled by Triboelectric Nanogenerator
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2021 (English)In: ACS Nano, ISSN 1936-0851, E-ISSN 1936-086X, Vol. 15, no 7, p. 11869-11879Article in journal (Refereed) Published
Abstract [en]

An intelligent monitoring lubricant is essential for the development of smart machines because unexpected and fatal failures of critical dynamic components in the machines happen every day, threatening the life and health of humans. Inspired by the triboelectric nanogenerators (TENGs) work on water, we present a feasible way to prepare a self-powered triboelectric sensor for real-time monitoring of lubricating oils via the contact electrification process of oil-solid contact (O-S TENG). Typical intruding contaminants in pure base oils can be successfully monitored. The O-S TENG has very good sensitivity, which even can respectively detect at least 1 mg mL-1 debris and 0.01 wt % water contaminants. Furthermore, the real-time monitoring of formulated engine lubricating oil in a real engine oil tank is achieved. Our results show that electron transfer is possible from an oil to solid surface during contact electrification. The electrical output characteristic depends on the screen effect from such as wear debris, deposited carbons, and age-induced organic molecules in oils. Previous work only qualitatively identified that the output ability of liquid can be improved by leaving less liquid adsorbed on the TENG surface, but the adsorption mass and adsorption speed of liquid and its consequences for the output performance were not studied. We quantitatively study the internal relationship between output ability and adsorbing behavior of lubricating oils by quartz crystal microbalance with dissipation (QCM-D) for liquid-solid contact interfaces. This study provides a real-time, online, self-powered strategy for intelligent diagnosis of lubricating oils.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2021
Keywords
TENG, condition monitoring, lubricating oils, smart machines, triboelectric nanogenerator
National Category
Tribology (Interacting Surfaces including Friction, Lubrication and Wear)
Research subject
Machine Elements
Identifiers
urn:nbn:se:ltu:diva-86080 (URN)10.1021/acsnano.1c02980 (DOI)000679406500079 ()34170109 (PubMedID)2-s2.0-85110304367 (Scopus ID)
Funder
The Kempe Foundations, JCK-1903.1Swedish Research Council Formas, 2019-00904Swedish Research Council, 2019-04941Swedish Energy Agency, 2017-008200, 2018-003910
Note

Validerad;2021;Nivå 2;2021-08-13 (alebob);

Finansiär: National Natural Science Foundation of China (51905027)

Available from: 2021-06-28 Created: 2021-06-28 Last updated: 2023-09-05Bibliographically approved
Organisations
Identifiers
ORCID iD: ORCID iD iconorcid.org/0000-0002-2500-2913

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