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Characterization of Mould Fungi Growth on Scots Pine Sapwood Surfaces
Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Träteknik.ORCID-id: 0000-0001-7864-8091
2019 (Engelska)Licentiatavhandling, sammanläggning (Övrigt vetenskapligt)
Ort, förlag, år, upplaga, sidor
Luleå: Luleå tekniska universitet, 2019.
Nationell ämneskategori
Trävetenskap Annan maskinteknik
Forskningsämne
Träteknik
Identifikatorer
URN: urn:nbn:se:ltu:diva-73793ISBN: 978-91-7790-380-2 (tryckt)ISBN: 978-91-7790-381-9 (digital)OAI: oai:DiVA.org:ltu-73793DiVA, id: diva2:1308115
Presentation
2019-06-12, A193, Forskargatan 1, Skellefteå, 09:00 (Engelska)
Opponent
Handledare
Tillgänglig från: 2019-05-02 Skapad: 2019-04-30 Senast uppdaterad: 2020-01-28Bibliografiskt granskad
Delarbeten
1. Distribution of low-molecular lipophilic extractives beneath the surface of air- and kiln-dried Scots pine sapwood boards
Öppna denna publikation i ny flik eller fönster >>Distribution of low-molecular lipophilic extractives beneath the surface of air- and kiln-dried Scots pine sapwood boards
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2018 (Engelska)Ingår i: PLoS ONE, ISSN 1932-6203, E-ISSN 1932-6203, Vol. 13, nr 10, artikel-id e0204212Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

During industrial wood drying, extractives migrate towards the wood surfaces and make the material more susceptible to photo/biodegradation. The present work provides information about the distribution, quantity and nature of lipophilic substances beneath the surface in air- and kiln-dried Scots pine (Pinus sylvestris L.) sapwood boards. Samples were taken from knot-free sapwood surfaces and the composition of lipophilic extractives, phenols and low-molecular fatty/resin acids layers at different nominal depths below the surface was studied gravimetrically, by UV-spectrometry and by gas chromatography-mass spectrometry (GC-MS). The concentration of total extractives was significantly higher in kiln-dried than in air-dried samples and was higher close to the surface than in the layers beneath. The scatter in the values for the lipophilic extractives was high in both drying types, being highest for linoleic acid and slightly lower for palmitic, oleic and stearic acids. The amount of fatty acids was low in kiln-dried boards, probably due to a stronger degradation due to the high temperature employed. The most abundant resin acid was dehydroabietic acid followed by pimaric, isopimaric, and abietic acids in both drying types. It is concluded that during kiln-drying a migration front is created at a depth of 0.25 mm with a thickness of about 0.5 mm.

Ort, förlag, år, upplaga, sidor
PLOS, 2018
Nationell ämneskategori
Trävetenskap Annan maskinteknik
Forskningsämne
Träteknik
Identifikatorer
urn:nbn:se:ltu:diva-71200 (URN)10.1371/journal.pone.0204212 (DOI)000446921100033 ()30303988 (PubMedID)2-s2.0-85054716404 (Scopus ID)
Projekt
Experimental studies of capillary phenomena in bio-based materialsFungal growth on modified wood-based products under subarctic conditionsModWoodLifeUnderstanding wood modification through an integrated scientific and environmental impact approach
Forskningsfinansiär
Vetenskapsrådet
Anmärkning

Validerad;2018;Nivå 2;2018-10-29 (svasva)

Tillgänglig från: 2018-10-13 Skapad: 2018-10-13 Senast uppdaterad: 2020-01-28Bibliografiskt granskad
2. Multivariate modeling of mould growth in relation to extractives in dried Scots pine sapwood
Öppna denna publikation i ny flik eller fönster >>Multivariate modeling of mould growth in relation to extractives in dried Scots pine sapwood
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2017 (Engelska)Ingår i: Proceedings IRG Annual Meetin, 2017, artikel-id 17-20629Konferensbidrag, Poster (med eller utan abstract) (Refereegranskat)
Abstract [en]

Influence of extractives on mould growth on Scots pine sapwood dried in air or in kiln was studied. Boards were sprayed with water mixtures of spores of the fungal species Penicillium sp., Aspergillus sp., Mucor sp., Paecilomyces sp., Trichoderma sp., treated at a temperature of 22ºC at 90% RH, classified into a percentage of covered area. Acetone and water extracts were isolated and analyzed for sugars, nitrogen, ash, resin/fatty acids, glycerol, and phenols. A multivariate Orthogonal Partial Least Squares (OPLS) regression model was developed to study relations between the extent of mould coverage of boards and chemical content. The model describes 51% variability in X and 69% in Y with prediction power of 55%. The results indicated that total acetone soluble extractives and sugars like glucose contributed to increased mould growth whereas fatty acids prevent mould growth.

Nyckelord
Multivariate analysis, sapwood, fungi
Nationell ämneskategori
Materialteknik Annan maskinteknik
Forskningsämne
Träteknik
Identifikatorer
urn:nbn:se:ltu:diva-63985 (URN)
Konferens
48th Conference of the International Research Group on Wood Protection, IRG48, Ghent, Belgium, 4-8 Jun 2017
Tillgänglig från: 2017-06-14 Skapad: 2017-06-14 Senast uppdaterad: 2020-01-28Bibliografiskt granskad
3. Hyperspectral Imaging Surface Analysis for Dried and Thermally Modified Wood: An Exploratory Study
Öppna denna publikation i ny flik eller fönster >>Hyperspectral Imaging Surface Analysis for Dried and Thermally Modified Wood: An Exploratory Study
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2018 (Engelska)Ingår i: Journal of Spectroscopy, ISSN 2314-4920, E-ISSN 2314-4939, artikel-id 7423501Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Naturally seasoned, kiln-dried, and thermally modified wood has been studied by hyperspectral near-infrared imaging between 980 and 2500 nm in order to obtain spatial chemical information. Evince software was used to explore, preprocess, and analyse spectral data from image pixels and link these data to chemical information via spectral wavelength assignment. A PCA model showed that regions with high absorbance were related to extractives with phenolic groups and aliphatic hydrocarbons. The sharp wavelength band at 2135 nm was found by multivariate analysis to be useful for multivariate calibration. This peak represents the largest variation that characterizes the knot area and can be related to areas in wood rich in hydrocarbons and phenol, and it can perhaps be used for future calibration of other wood surfaces. The discriminant analysis of thermally treated wood showed the strongest differentiation between the planed and rip-cut wood surfaces and a fairly clear discrimination between the two thermal processes. The wavelength band at 2100 nm showed the greatest difference and may correspond to stretching of C=O-O of polymeric acetyl groups, but this requires confirmation by chemical analysis.

Ort, förlag, år, upplaga, sidor
Hindawi Publishing Corporation, 2018
Nationell ämneskategori
Trävetenskap
Forskningsämne
Träteknik
Identifikatorer
urn:nbn:se:ltu:diva-71584 (URN)10.1155/2018/7423501 (DOI)2-s2.0-85057402277 (Scopus ID)
Anmärkning

Validerad;2018;Nivå 2;2018-11-20 (svasva)

Tillgänglig från: 2018-11-14 Skapad: 2018-11-14 Senast uppdaterad: 2020-01-28Bibliografiskt granskad

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