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Visible Light Photodegradation of Dyes and Paracetamol by Direct Sensitization Mechanism onto Metallic MoO2 Nanocrystals
CNR-IMM, Via S. Sofia 64, 95123 Catania, Italy.
Istituto di Chimica della Materia Condensata e Tecnologie per l’Energia, Consiglio Nazionale delle Ricerche (ICMATE-CNR) and Dipartimento di Scienze Chimiche, Università di Padova, Via F. Marzolo 1, 35131 Padova, Italy.
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.ORCID iD: 0000-0003-2099-7605
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.ORCID iD: 0000-0003-1785-7177
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2021 (English)In: Journal of Photochemistry and Photobiology A: Chemistry, ISSN 1010-6030, E-ISSN 1873-2666, Vol. 413, article id 113258Article in journal (Refereed) Published
Abstract [en]

MoO2 nanocrystals were prepared by solvothermal treatment of a Mo chloromethoxide at 250 °C in oleic acid. The monoclinic MoO2 phase, with a mean crystallite size of 29 nm, formed through reduction of molybdenum bronzes. The as-prepared MoO2 nanocrystals were free from organics, allowing their use in photodegradation tests of organic pollutants (methylene blue, rhodamine B, paracetamol), without any preliminary purification treatment of the nanocrystals. It was found that MoO2 was an efficient adsorbent of methylene blue (43 mg g-1 for 1.5 × 10−4 M concentration) in the dark and an efficient photodegradation catalyst under visible light (all methylene blue removed from the solution after 240 min). From the analysis of the combined photodegradation tests of rhodamine B and paracetamol, it was clarified that direct sensitization was responsible for photodegradation. This finding was related to the work function value of metallic MoO2, placed at more negative values if compared with other metallic materials.

Place, publisher, year, edition, pages
Elsevier, 2021. Vol. 413, article id 113258
Keywords [en]
photodegradation, dye sensitization, direct sensitization mechanism, methylene blue, MoO2, solvothermal synthesis
National Category
Materials Chemistry
Research subject
Experimental Physics
Identifiers
URN: urn:nbn:se:ltu:diva-83178DOI: 10.1016/j.jphotochem.2021.113258ISI: 000640902200004Scopus ID: 2-s2.0-85103092413OAI: oai:DiVA.org:ltu-83178DiVA, id: diva2:1534396
Funder
European Regional Development Fund (ERDF), CUP: B61G18000070009
Note

Validerad;2021;Nivå 2;2021-04-08 (alebob);

Finansiär: MIUR-PON TARANTO (ARS01_00637)

Available from: 2021-03-05 Created: 2021-03-05 Last updated: 2021-06-01Bibliographically approved
In thesis
1. Nanostructured Metal Oxide Semiconductors for Functional Applications
Open this publication in new window or tab >>Nanostructured Metal Oxide Semiconductors for Functional Applications
2021 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

This thesis is about nanostructured metal oxides, their properties, and some of their applications. Semiconducting metal oxides like TiO2, ZnO,and SnO2 have a wide band gap, which means they absorb UV light andgenerate electron-hole pairs. These charge carriers can be harnessed andused for a variety of purposes, such as electricity generation in solar cells,hydrogen production by means of photolysis and electrolysis, andenvironmental remediation by mineralizing pollutants in photocatalyticreactions. However, they are typically not very efficient when comparedwith e.g. noble metals in catalysis or silicon in solar cells , and so a widevariety of strategies have been employed to remedy their weaknesses.Such strategies include structuring the materials at the nanoscale, and thefabrication of composite materials and heterostructures.In this work, some advanced hybrid materials have been studied,composed of metal oxide and various additives, such as reduced grapheneoxide (rGO), other metal oxides, and flavonoids. The materials have beenextensively characterized in order to determine how these additives affectthe processes going on in some of the mentioned applications. Thestudied systems include rGO-ZnO, SnO2-ZnO, Rh-TiO2, MoO2, SiO2coupled to 3-hydroxyflavone and 7-hydroxyflavone, and 3-hydroxyflavone-TiO2.Particles of ZnO-encapsulated rGO exhibited a good photocatalyticactivity towards the degradation of rhodamine B and phenol, but it wasfound that the main determinant of the performance was the quality ofthe semiconductor component as opposed to any favorable interactionsbetween ZnO and rGO. However, the incorporation of rGO could stillalmost double the observed performance, which was attributed to apassivation of the defects in the metal oxide host, as well as a beneficialimpact of electrochemical properties such as charge transfer resistance anddouble-layer capacitance of the resulting material.Core-shell nanoparticles consisting of a SnO2 core and a ZnO shell weresuccessfully synthesized and employed as photocatalyst and as photoanodein dye-sensitized solar cells (DSSCs). The ZnO shell improved theperformance in both photocatalysis and DSSCs by nearly a factor of two,due to a combination of the favorable properties of the two metal oxides ,and the formation of a heterojunction in the interface between them.Rhodium as an additive to TiO2 nanocrystals proved to effectivelyimprove the response in gas sensing experiments. The rhodium exhibitedcomplex speciation, however, being distributed as a homogeneouscoating of Rh(III) as well as nanocrystals of elemental rhodium,highlighting the need for deep characterization in this class of materials.Metallic MoO2 nanocrystals were synthesized and tested in photocatalysis.Due to their electronic nature, they cannot support photocatalysisaccording to the traditional reaction scheme, because metals cannotgenerate electron-hole pairs. However, they still exhibited significantphotocatalytic activity towards methylene blue, rhodamine B, andparacetamol. This was attributed to a direct sensitization mechanismwhere the dye is photoexcited and undergoes electron transfer, madepossible due to the comparatively low work function in MoO2. This alsoenables it to assist in the degradation of non-absorbing molecules in thesolution. 3-hydroxyflavone (3HF) and 7-hydroxyflavone (7HF) were combinedwith MCM-41 silica nanoparticles via a post-doping procedure, and theirphotophysics characterized by steady-state and time-resolvedspectroscopic techniques. Both flavonoid-coated nanoparticles turned outto be highly fluorescent and stable when exposed to air at roomtemperature, showing that organic fluorophore-based solid-state emitterscan be obtained by simple methods. Furthermore, 3HF was coupled toTiO2 nanoparticles with a similarly simple adsorption procedure. In thiscase the result was a chemisorption of the flavonoid, which appears to bevery similar to a chelation of the metal ions in the metal oxide substrate.The fluorescence in the resulting materials is nearly completely quenched,but when a nanometer-thin layer of Al2O3 is applied on the TiO2, it isinstead strongly enhanced. This work therefore represents a rather noveland facile way to produce flavonoid-metal complexes.

Place, publisher, year, edition, pages
Luleå University of Technology, 2021
Series
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
National Category
Nano Technology Other Physics Topics
Research subject
Experimental Physics
Identifiers
urn:nbn:se:ltu:diva-83181 (URN)978-91-7790-773-2 (ISBN)978-91-7790-774-9 (ISBN)
Public defence
2021-06-01, E632, Luleå, 09:00 (English)
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Supervisors
Available from: 2021-03-05 Created: 2021-03-05 Last updated: 2022-06-30Bibliographically approved

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Landström, AntonConcina, Isabella

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