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Melting points of ionic liquids: Review and evaluation
Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Energivetenskap. State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, China.ORCID-id: 0009-0002-1667-6761
State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, China.
State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University, Nanjing, China.
Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Energivetenskap.ORCID-id: 0000-0002-0200-9960
2024 (engelsk)Inngår i: Artikkel, forskningsoversikt (Fagfellevurdert) In press
Abstract [en]

The melting points of ionic liquids (ILs) reported since 2020 were surveyed, collected, and reviewed, which were further combined with the previous data to provide a database with 3129 ILs ranging from 177.15 to 645.9 K in melting points. In addition, the factors that affect the melting point of ILs from macro, micro, and thermodynamic perspectives were summarized and analyzed. Then the development of the quantitative structure-property relationship (QSPR), group contribution method (GCM), and conductor-like screening model for realistic solvents (COSMO-RS) for predicting the melting points of ILs were reviewed and further analyzed. Combined with the evaluation together with the preliminary study conducted in this work, it shows that COSMO-RS is more promising and possible to further improve its performance, and a framework was thus proposed.

sted, utgiver, år, opplag, sider
KeAi Publishing Communications Ltd. , 2024.
Emneord [en]
COSMO-RS, GCM, Ionic liquids, Melting point, QSPR
HSV kategori
Forskningsprogram
Energiteknik
Identifikatorer
URN: urn:nbn:se:ltu:diva-104885DOI: 10.1016/j.gee.2024.01.009Scopus ID: 2-s2.0-85187514775OAI: oai:DiVA.org:ltu-104885DiVA, id: diva2:1846958
Merknad

Funder: Swedish Research Council (101070976); China Scholarship Council (202208320253); STINT (CH2019-8287); National Natural Science Foundation of China (21838004, 22011530112);

Full text license: CC BY-NC-ND

Tilgjengelig fra: 2024-03-26 Laget: 2024-03-26 Sist oppdatert: 2024-03-26

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