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A Holistic and Experimentally-Based View on Recycling of Off-Gas Dust within the Integrated Steel Plant
Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Mineralteknik och metallurgi.
Swerea MEFOS, Luleå, Sweden.
Swerea MEFOS, Luleå, Sweden.
Swerea MEFOS, Luleå, Sweden.
Vise andre og tillknytning
2018 (engelsk)Inngår i: Metals, ISSN 2075-4701, Vol. 8, nr 10, artikkel-id 760Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Ore-based ironmaking generates a variety of residues, including slags and fines such as dust and sludges. Recycling of these residues within the integrated steel plant or in other applications is essential from a raw-material efficiency perspective. The main recycling route of off-gas dust is to the blast furnace (BF) via sinter, cold-bonded briquettes and tuyere injection. However, solely relying on the BF for recycling implicates that certain residues cannot be recycled in order to avoid build-up of unwanted elements, such as zinc. By introducing a holistic view on recycling where recycling via other process routes, such as the desulfurization (deS) station and the basic oxygen furnace (BOF), landfilling can be avoided. In the present study, process integration analyses were utilized to determine the most efficient recycling routes for off-gas dust that are currently not recycled within the integrated steel plants of Sweden. The feasibility of recycling was studied in experiments conducted in laboratory, pilot, and full-scale trials in the BF, deS station, and BOF. The process integration analyses suggested that recycling to the BF should be maximized before considering the deS station and BOF. The experiments indicated that the amount of residue that are not recycled could be minimized.

sted, utgiver, år, opplag, sider
Basel: MDPI, 2018. Vol. 8, nr 10, artikkel-id 760
Emneord [en]
Recycling, Cold-bonded briquettes, Blast furnace, Desulfurization, Basic oxygen furnace, Dust, Sludge, Fines
HSV kategori
Forskningsprogram
Processmetallurgi
Identifikatorer
URN: urn:nbn:se:ltu:diva-71130DOI: 10.3390/met8100760ISI: 000448658700024Scopus ID: 2-s2.0-85054764975OAI: oai:DiVA.org:ltu-71130DiVA, id: diva2:1253930
Forskningsfinansiär
Swedish Energy Agency
Merknad

Validerad;2018;Nivå 2;2018-10-19 (marisr)

Tilgjengelig fra: 2018-10-08 Laget: 2018-10-08 Sist oppdatert: 2019-08-22bibliografisk kontrollert
Inngår i avhandling
1. Recycling of Blast Furnace Sludge within the Integrated Steel Plant: Potential for Complete Recycling and Influence on Operation
Åpne denne publikasjonen i ny fane eller vindu >>Recycling of Blast Furnace Sludge within the Integrated Steel Plant: Potential for Complete Recycling and Influence on Operation
2019 (engelsk)Doktoravhandling, med artikler (Annet vitenskapelig)
Abstract [en]

Ore-based steelmaking generates various residues including dust, sludges, scales and slags. Internal and external recycling has allowed for 68-90 % of the dust, sludges and scales to be recycled. However, several residues are landfilled despite containing elements valuable as raw material in the production of steel. One such residue is the blast furnace (BF) sludge which has a chemical composition dominated by iron and carbon. In 2008, the annual worldwide landfilling of BF sludge was estimated to 8 million metric tons in dry weight. Furthermore, as the iron production via the BF route has increased significantly since 2008, the landfilling of BF sludge could be even higher as of today. Thus, the potential to reclaim valuable iron and carbon while improving the raw material efficiency is substantial.

Traditionally, in-plant recycling of residues generated in the integrated steel plant is conducted via the sinter or, in the case of pellet-based BFs, via cold-bonded briquettes and injection in the BF tuyeres. The challenges in recycling BF sludge via these routes are the fine particle size distribution, the high water content and the zinc content. Of these challenges, the latter is the main concern as too high zinc loads in the BF lead to increased reductant rates, reduced lining life of carbon-based bricks and scaffold formation, which may disturb the process. The challenge regarding zinc has previously been addressed by pretreating the sludge, generating a low-zinc and high-zinc fraction where the former has been recycled to the BF via the sinter or cold-bonded pellets. Although pretreatment and recycling of the low-zinc fraction have been achieved in industrial scale, the reported sludges are generally coarse in size and high in zinc. Furthermore, recycling of pretreated BF sludge to the BF utilizing cold-bonded briquettes has not been reported and the internal recycling of the high-zinc fraction has not been considered.

In the present thesis, newly produced BF sludge with a fine particle size distribution and low zinc content was characterized finding that a majority of the zinc was present in weak acid soluble phases and that the finest fraction of the sludge carried most of the zinc. Based on these findings, the BF sludge was pretreated using sulfuric acid leaching, hydrocycloning and tornado treatment, respectively. Sulfuric acid leaching was the most effective method in selectively separating zinc from the iron, carbon and solids. However, both hydrocycloning and tornado treatment were successful in generating a fraction low in zinc.

The low-zinc fraction of the tornado-treated BF sludge was incorporated in cold-bonded briquettes and tested for strength, swelling and intrinsic reducibility. Furthermore, the briquettes were charged as basket samples in the LKAB Experimental Blast Furnace (EBF) in order to study the behavior in actual BF conditions. The results suggested that the low-zinc fraction of the BF sludge could be added to the briquettes without negatively affecting the performance of the briquettes in the BF. The results were confirmed in industrial-scale trials where non-treated BF sludge was added to cold-bonded briquettes in an amount that would facilitate complete recycling of the low-zinc fraction. Charging these briquettes to the BF did not induce any negative effects on the process or the hot metal (HM) quality.

The high-zinc fraction of the tornado-treated BF sludge was added in self-reducing cold-bonded agglomerates and studied in technical-scale smelting reduction experiments aiming at recycling to the HM desulfurization plant. The experiments suggested that melt-in problems could be expected when using either briquettes or pellets. Nonetheless, industrial-scale trials were performed aiming to study the feasibility of recycling cold-bonded briquettes to both the HM desulfurization plant and basic oxygen furnace (BOF). These trials suggested that a substantial amount could be recycled without affecting the final quality of the steel. However, additional experiments were identified to be required in order to enable 100 % recycling of the high-zinc fraction of the tornado-treated BF sludge.

Based on the results from the experimental work, a holistic concept to completely recycle the BF sludge within the integrated steel plant was suggested.

sted, utgiver, år, opplag, sider
Luleå University of Technology, 2019. s. 104
Serie
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
HSV kategori
Forskningsprogram
Processmetallurgi
Identifikatorer
urn:nbn:se:ltu:diva-75651 (URN)978-91-7790-419-9 (ISBN)978-91-7790-420-5 (ISBN)
Disputas
2019-10-18, 09:00 (engelsk)
Opponent
Veileder
Forskningsfinansiär
Swedish Energy Agency, JK21069
Tilgjengelig fra: 2019-08-22 Laget: 2019-08-22 Sist oppdatert: 2019-09-13bibliografisk kontrollert

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