Ändra sökning
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Catalytic Fast Pyrolysis of Lignin Isolated by Hybrid Organosolv—Steam Explosion Pretreatment of Hardwood and Softwood Biomass for the Production of Phenolics and Aromatics
Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki, Greece.
Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki, Greece.
Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki, Greece.
Chemical Process and Energy Resources Institute, Centre for Research and Technology-Hellas (CPERI/CERTH), Thessaloniki, Greece.
Visa övriga samt affilieringar
2019 (Engelska)Ingår i: Catalysts, E-ISSN 2073-4344, Vol. 9, nr 11, artikel-id 935Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Lignin, one of the three main structural biopolymers of lignocellulosic biomass, is the most abundant natural source of aromatics with a great valorization potential towards the production of fuels, chemicals, and polymers. Although kraft lignin and lignosulphonates, as byproducts of the pulp/paper industry, are available in vast amounts, other types of lignins, such as the organosolv or the hydrolysis lignin, are becoming increasingly important, as they are side-streams of new biorefinery processes aiming at the (bio)catalytic valorization of biomass sugars. Within this context, in this work, we studied the thermal (non-catalytic) and catalytic fast pyrolysis of softwood (spruce) and hardwood (birch) lignins, isolated by a hybrid organosolv–steam explosion biomass pretreatment method in order to investigate the effect of lignin origin/composition on product yields and lignin bio-oil composition. The catalysts studied were conventional microporous ZSM-5 (Zeolite Socony Mobil–5) zeolites and hierarchical ZSM-5 zeolites with intracrystal mesopores (i.e., 9 and 45 nm) or nano-sized ZSM-5 with a high external surface. All ZSM-5 zeolites were active in converting the initially produced via thermal pyrolysis alkoxy-phenols (i.e., of guaiacyl and syringyl/guaiacyl type for spruce and birch lignin, respectively) towards BTX (benzene, toluene, xylene) aromatics, alkyl-phenols and polycyclic aromatic hydrocarbons (PAHs, mainly naphthalenes), with the mesoporous ZSM-5 exhibiting higher dealkoxylation reactivity and being significantly more selective towards mono-aromatics compared to the conventional ZSM-5, for both spruce and birch lignin.

Ort, förlag, år, upplaga, sidor
MDPI, 2019. Vol. 9, nr 11, artikel-id 935
Nyckelord [en]
spruce and birch wood lignin, hybrid organosolv—steam explosion pretreatment, catalytic fast pyrolysis, model compounds, bio-oil, phenolics and aromatics, microporous and hierarchical ZSM-5 zeolite
Nationell ämneskategori
Bioprocessteknik
Forskningsämne
Biokemisk processteknik
Identifikatorer
URN: urn:nbn:se:ltu:diva-76789DOI: 10.3390/catal9110935ISI: 000502278800061Scopus ID: 2-s2.0-85074766498OAI: oai:DiVA.org:ltu-76789DiVA, id: diva2:1371631
Anmärkning

Validerad;2019;Nivå 2;2019-11-20 (johcin)

Tillgänglig från: 2019-11-20 Skapad: 2019-11-20 Senast uppdaterad: 2020-02-25Bibliografiskt granskad

Open Access i DiVA

Fulltext saknas i DiVA

Övriga länkar

Förlagets fulltextScopus

Personposter BETA

Matsakas, LeonidasRova, UlrikaChristakopoulos, Paul

Sök vidare i DiVA

Av författaren/redaktören
Matsakas, LeonidasRova, UlrikaChristakopoulos, Paul
Av organisationen
Kemiteknik
Bioprocessteknik

Sök vidare utanför DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetricpoäng

doi
urn-nbn
Totalt: 5 träffar
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf