Ändra sökning
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Self-Constructed Multiple Plasmonic Hotspots on an Individual Fractal to Amplify Broadband Hot Electron Generation
School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P.R. China; Key Laboratory of Efficient Utilization of Low and Medium Grade Energy, Ministry of Education, Tianjin University, Tianjin 300350, P.R. China.
Hybrid Nanosystems, Nanoinstitute Munich, Faculty of Physics, Ludwig-Maximilians-Universität München, D-80539 München, Germany.
School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P.R. China.
School of Materials Science and Engineering, Tianjin University, Tianjin 300350, P.R. China.
Visa övriga samt affilieringar
2021 (Engelska)Ingår i: ACS Nano, ISSN 1936-0851, E-ISSN 1936-086X, Vol. 15, nr 6, s. 10553-10564Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Plasmonic nanoparticles are ideal candidates for hot-electron-assisted applications, but their narrow resonance region and limited hotspot number hindered the energy utilization of broadband solar energy. Inspired by tree branches, we designed and chemically synthesized silver fractals, which enable self-constructed hotspots and multiple plasmonic resonances, extending the broadband generation of hot electrons for better matching with the solar radiation spectrum. We directly revealed the plasmonic origin, the spatial distribution, and the decay dynamics of hot electrons on the single-particle level by using ab initio simulation, dark-field spectroscopy, pump–probe measurements, and electron energy loss spectroscopy. Our results show that fractals with acute tips and narrow gaps can support broadband resonances (400–1100 nm) and a large number of randomly distributed hotspots, which can provide unpolarized enhanced near field and promote hot electron generation. As a proof-of-concept, hot-electron-triggered dimerization of p-nitropthiophenol and hydrogen production are investigated under various irradiations, and the promoted hot electron generation on fractals was confirmed with significantly improved efficiency.

Ort, förlag, år, upplaga, sidor
American Chemical Society (ACS), 2021. Vol. 15, nr 6, s. 10553-10564
Nyckelord [en]
dendritic fractal, broadband hot electron generation, plasmonic resonances, electron energy loss spectroscopy, plasmon-assisted photocatalysis
Nationell ämneskategori
Den kondenserade materiens fysik
Forskningsämne
Experimentell fysik
Identifikatorer
URN: urn:nbn:se:ltu:diva-85497DOI: 10.1021/acsnano.1c03218ISI: 000665748900121PubMedID: 34114794Scopus ID: 2-s2.0-85108891316OAI: oai:DiVA.org:ltu-85497DiVA, id: diva2:1567195
Anmärkning

Validerad;2021;Nivå 2;2021-07-14 (johcin);

Finansiär: National Natural Science Foundation of China (51771132); Alexander von Humboldt Foundation; Deutsche Forschungsgemeinschaft Centre of Excellence (EXC 2089/1 -390776260); Bavaria SolTech program; Lee−Lucas Chair in Physics; EPSRC Reactive Plasmonics Programme (EP/M013812/1); European Commission through the ERC Starting Grant CATALIGHT (802989)

Tillgänglig från: 2021-06-16 Skapad: 2021-06-16 Senast uppdaterad: 2021-12-13Bibliografiskt granskad

Open Access i DiVA

Fulltext saknas i DiVA

Övriga länkar

Förlagets fulltextPubMedScopus

Person

Vomiero, Alberto

Sök vidare i DiVA

Av författaren/redaktören
Vomiero, Alberto
Av organisationen
Materialvetenskap
I samma tidskrift
ACS Nano
Den kondenserade materiens fysik

Sök vidare utanför DiVA

GoogleGoogle Scholar

doi
pubmed
urn-nbn

Altmetricpoäng

doi
pubmed
urn-nbn
Totalt: 15 träffar
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf