Ändra sökning
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Vibrational spectra of CO and CO2 adsorbed on potassium modified Fe(100)
1989 (Engelska)Ingår i: Surface Science, ISSN 0039-6028, E-ISSN 1879-2758, Vol. 224, nr 1-3, s. 348-358Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

High resolution electron energy loss (EEL) spectra for CO adsorbed on potassium modified Fe(100) are presented. Five CO vibrational bands are clearly distinguishable. Two bands at or above 2000 cm-1 correspond to the *1- and *2-states on the clean surface. Two more bands, residing between 1450 and 1850 cm-1, reveal adsorption at potassium modified sites. The response of these bands to changes in potassium coverage and annealing temperature is highly predictable and similar to the situation on Fe(111) [1]. This suggests a local K: CO coordination. A fifth band is observed around 950 cm-1 and interpreted as CO adsorbed at potassium modified *3-sites, redshifted from 1200 cm-1 at unmofidied sites. The present results are complementary to a previous study of the same adsorption system utilizing photoemission spectroscopy and thermal desorption spectroscopy [2]. Finally, we present novel vibrational and thermal desorption (TDS) data for Fe(100)/K exposed to CO2 and point at similarities between intermediate states following CO and CO2 adsorption on different potassium promoted iron surfaces.

Ort, förlag, år, upplaga, sidor
1989. Vol. 224, nr 1-3, s. 348-358
Nationell ämneskategori
Annan fysik
Forskningsämne
Fysik
Identifikatorer
URN: urn:nbn:se:ltu:diva-11808DOI: 10.1016/0039-6028(89)90919-9Lokalt ID: ad193aa0-386f-11dd-8721-000ea68e967bOAI: oai:DiVA.org:ltu-11808DiVA, id: diva2:984758
Anmärkning
Upprättat; 1989; 20080612 (ysko)Tillgänglig från: 2016-09-29 Skapad: 2016-09-29 Senast uppdaterad: 2017-11-24Bibliografiskt granskad

Open Access i DiVA

Fulltext saknas i DiVA

Övriga länkar

Förlagets fulltext

Personposter BETA

Paul, Jan

Sök vidare i DiVA

Av författaren/redaktören
Paul, Jan
I samma tidskrift
Surface Science
Annan fysik

Sök vidare utanför DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetricpoäng

doi
urn-nbn
Totalt: 8 träffar
RefereraExporteraLänk till posten
Permanent länk

Direktlänk
Referera
Referensformat
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annat format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annat språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf