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Fractionation of iron isotopes during estuarine mixing in Ob, Yenisey and Lena freshwater plumes
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.ORCID iD: 0000-0003-2276-0564
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering. ALS Laboratory Group, ALS Scandinavia AB, Luleå, Sweden.
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2009 (English)In: Geochimica et Cosmochimica Acta, ISSN 0016-7037, E-ISSN 1872-9533, Vol. 73, no 13, Suppl. S, p. A569-Article in journal, Meeting abstract (Other academic) Published
Abstract [en]

Iron isotopes were measured in suspended matter (>0.2 µm) in the Ob, Yenisey and Lena River freshwater plumes during the International Siberian Shelf Study 2008 (ISSS-08). The δ56Fe value was around zero within the Lena River and close to the river mouth, but changed to more negative values in the outer parts of the plume. In both the Ob and Yenisey plumes suspended matter in the surface water had clearly negative values whereas samples close to the bottom showed values close to zero.

It has previously been suggested that total Fe in river suspended matter (>0.2µm) in boreal regions is roughly a mixture of three phases, detrital particles (δ56Fe around zero), oxyhydroxide particles (δ56Fe positive) and C-Fe particles (δ56Fe negative). We suggest that the δ56Fe pattern observed in this study is the result of relatively rapid removal of detrital particles and Fe-oxyhydroxides, leaving a suspended fraction with negative values in the surface water in the outer parts of the freshwater plumes. Hence, during estuarine mixing of suspended particles heavy iron isotopes are deposited close to the river mouth, whereas light isotopes are exported to open ocean water.

Place, publisher, year, edition, pages
2009. Vol. 73, no 13, Suppl. S, p. A569-
National Category
Geochemistry
Research subject
Applied Geology
Identifiers
URN: urn:nbn:se:ltu:diva-32058Local ID: 66ab1020-7dab-11de-8da0-000ea68e967bOAI: oai:DiVA.org:ltu-32058DiVA, id: diva2:1005292
Conference
Annual V.M. Goldschmidt Conference : 21/06/2009 - 26/06/2009
Note

Godkänd; 2009; 20090731 (ysko)

Available from: 2016-09-30 Created: 2016-09-30 Last updated: 2022-09-08Bibliographically approved

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Ingri, JohanGelting, JohanNordblad, FredrikEngström, EmmaRodushkin, IlyaÖhlander, Björn

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