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Removal of metal(oid)s from contaminated water using iron-coated peat sorbent
Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Geovetenskap och miljöteknik.ORCID-id: 0000-0001-5375-8825
Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Geovetenskap och miljöteknik.
Department of Sustainable Development, Environmental Science and Engineering, Royal Institute of Technology.
Department of Agricultural Sciences, University of Naples Federico II.
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2018 (Engelska)Ingår i: Chemosphere, ISSN 0045-6535, E-ISSN 1879-1298, Vol. 198, s. 290-296Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

This study aimed at combining iron and peat to produce a sorbent suitable for a simultaneous removal of cations and anions from a solution. Peat powder, an industrial residue, was coated with iron by immersing peat into iron salt solutions. The adsorption efficiency of the newly produced sorbent towards As, Cr, Cu and Zn was tested by means of batch adsorption experiments at a constant pH value of 5. Coating of Fe on peat significantly increased the adsorption of As (from <5% to 80%) and Cr (from <3% to 25%) in comparison to uncoated peat. Removal of cations on coated peat slightly decreased (by 10–15%), yet remained within acceptable range. Electron Microscopy combined with X-Ray Energy Dispersive Spectroscopy revealed that iron coating on the peat was rather homogenous and As and Cr were abundantly adsorbed on the surface. By contrast, Cu and Zn displayed a sparing distribution on the surface of the iron coated peat. These results indicate that iron-peat simultaneously target sufficient amounts of both cations and anions and can be used for a one-step treatment of contaminated groundwater

Ort, förlag, år, upplaga, sidor
Elsevier, 2018. Vol. 198, s. 290-296
Nationell ämneskategori
Annan naturresursteknik
Forskningsämne
Avfallsteknik
Identifikatorer
URN: urn:nbn:se:ltu:diva-67545DOI: 10.1016/j.chemosphere.2018.01.139ISI: 000427338800033PubMedID: 29421741Scopus ID: 2-s2.0-85041488356OAI: oai:DiVA.org:ltu-67545DiVA, id: diva2:1180910
Anmärkning

Validerad;2018;Nivå 2;2018-02-07 (andbra)

Tillgänglig från: 2018-02-07 Skapad: 2018-02-07 Senast uppdaterad: 2019-10-09Bibliografiskt granskad
Ingår i avhandling
1. Peat Coated with Iron Oxides: Purification of Metal(loid)-Contaminated Water and Treatment of the Spent Adsorbent
Öppna denna publikation i ny flik eller fönster >>Peat Coated with Iron Oxides: Purification of Metal(loid)-Contaminated Water and Treatment of the Spent Adsorbent
2019 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

In Sweden due to the industrial activities, such as wood impregnation, multiple point sources of arsenic (As) contamination in soil and water bodies are scattered over the country. Metals, such as chromium (Cr), copper (Cu), lead (Pb), nickel (Ni), cadmium (Cd) or zinc (Zn) at varying concentrations are usually present as well. Since adsorption is a common method to purify contaminated water, research and development of adsorbents have been actively carried out in the last few decades. However, seldom spent sorbent is safely handled afterwards and often end up in landfill, thus creating new problems and posing new risks to humans and environment.

The aim of this study was to develop a waste-based adsorbent for simultaneous removal of As and associated metals: Cr, Cu and Zn, and to analyse sustainable ways how to manage the spent adsorbent without creating secondary pollution.

In the model system two well-establish adsorbents: Fe oxides (deriving from FeCl3) and peat (waste-based), were combined and the concept of simultaneous removal of cationic and anionic contaminants was tested in a batch adsorption experiment. Due to Fe coating, removal of As and Cr increased by 80% and 30%, respectively, as compared to non-coated peat. Removal of Cu and Zn was higher (up to 15%) on non-coated peat than on Fe-coated peat. Similar results were obtained in the up-scaled column adsorption experiment, where Fe salt was substituted with a waste-based Fe hydrosol. Within the same pH environment (pH=5), Fe-coated peat effectively adsorbed all four investigated contaminants (As, Cr, Cu and Zn). Non-coated peat was effective for Cr, Cu and Zn. While, Fe oxides (coated on sand) adsorbed only As.

Three management strategies for spent adsorbents, obtained after column adsorption experiment, were investigated in this study. i) Long-term deposit in a landfill was simulated by exposing spent adsorbents to a reducing environment and evaluating metal(loid) leaching. Leaching of As increased manifold (up to 60% in a 200-day experiment) as compared to the standardized batch leaching experiment under oxidizing conditions. It was determined that about one third of As(V) was reduced to As(III), which is more mobile and toxic. ii) Valorisation of the spent adsorbent was attempted through hydrothermal carbonisation. It was expected that obtained hydrochar could be used as a beneficial soil amendment. However, treatment resulted in the process liquid and the hydrochar both having high loads of As, Cu and Zn. Additional treatment of process water and hydrochar imply higher management costs for spent adsorbents. iii) Possibility of thermal destruction was investigated by combusting spent adsorbents. After the treatment volume of the waste (ash) was by 80-85% smaller as compared to spent adsorbents. Combustion at higher temperature (1100 °C vs 850 °C) resulted into a weaker metal(loid) leaching from ashes. Furthermore, co-combustion with calcium (Ca)-rich lime (waste-based) decreased leaching of all four investigated elements, Cr in particular, below the limit values for waste being accepted at landfills for hazardous waste. Therefore, combustion enabled possibility of safe and long-term deposit of As-bearing ashes. At the same time, less As would be circulating in society. 

For the future work, studies that could broaden the spectrum of contaminants targeted by Fe-coated peat would be beneficial. At the same time it is important not only to find alternative utilisation methods for Fe-coated peat, but also investigate other management options for the spent adsorbents.

Ort, förlag, år, upplaga, sidor
Luleå: Luleå University of Technology, 2019
Serie
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
Nyckelord
iron-peat, adsorption, arsenic, metals, combustion, hydrothermal carbonisation, landfilling
Nationell ämneskategori
Miljöledning Annan naturresursteknik
Forskningsämne
Avfallsteknik
Identifikatorer
urn:nbn:se:ltu:diva-76325 (URN)978-91-7790-462-5 (ISBN)978-91-7790-463-2 (ISBN)
Disputation
2019-12-05, D770, Luleå, 10:00 (Engelska)
Opponent
Handledare
Tillgänglig från: 2019-10-09 Skapad: 2019-10-09 Senast uppdaterad: 2019-11-14Bibliografiskt granskad

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