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Facile Preparation of Hydrophobic Colloidal MFI and CHA Crystals and Oriented Ultra-thin Films
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering.ORCID iD: 0000-0002-7477-4960
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering.ORCID iD: 0000-0003-1053-4623
2018 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 130, no 34, p. 11132-11136Article in journal (Refereed) Published
Abstract [en]

We report novel routes for synthesis of defect-free, hydrophobic and monodispersed 10 nm (5 unit cells) thick MFI crystals and 100 nm CHA crystals. The crystals are obtained in high yield and display very high 1-butanol adsorption from aqueous solution. These crystals are assembled in monolayers for the growth of ultra-thin and uniformly oriented films with thicknesses of 36 nm and 330 nm, respectively, using a synthesis gel in the form of a powder. This method is very simple and may open up for industrial preparation of materials with improved performances.

Place, publisher, year, edition, pages
John Wiley & Sons, 2018. Vol. 130, no 34, p. 11132-11136
National Category
Chemical Process Engineering
Research subject
Chemical Technology
Identifiers
URN: urn:nbn:se:ltu:diva-70084DOI: 10.1002/anie.201806502ISI: 000442863700029PubMedID: 29969534Scopus ID: 2-s2.0-85050593367OAI: oai:DiVA.org:ltu-70084DiVA, id: diva2:1231271
Note

Validerad;2018;Nivå 2;2018-08-14 (andbra)

Available from: 2018-07-06 Created: 2018-07-06 Last updated: 2023-09-05Bibliographically approved

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Zhou, MingHedlund, Jonas

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