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Structural and Ion Dynamics in Fluorine-Free Oligoether Carboxylate Ionic Liquid-Based Electrolytes
Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.ORCID-id: 0000-0003-3652-7798
Institute of Physics, Kazan Federal University, 420008 Kazan, Russia.
Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik.ORCID-id: 0000-0002-7940-7297
Luleå tekniska universitet, Institutionen för samhällsbyggnad och naturresurser, Kemiteknik. Medical and Biological Physics, Kazan Medical University, 420012 Kazan, Russia.ORCID-id: 0000-0002-6810-1882
Vise andre og tillknytning
2020 (engelsk)Inngår i: Journal of Physical Chemistry B, ISSN 1520-6106, E-ISSN 1520-5207, Vol. 124, nr 43, s. 9690-9700Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Here, we investigate the physicochemical and electrochemical properties of fluorine-free ionic liquid (IL)-based electrolytes with two different cations, tetrabutylphosphonium, (P4,4,4,4)+, and tetrabutylammonium, (N4,4,4,4)+, coupled to a new anion, 2-[2-(2-methoxyethoxy)ethoxy]acetate anion (MEEA)−, for both neat and (P4,4,4,4)(MEEA) also doped with 10–40 mol % of Li(MEEA). We find relatively weaker cation–anion interactions in (P4,4,4,4)(MEEA) than in (N4,4,4,4)(MEEA), and for both ILs, the structural flexibility of the oligoether functionality in the anion results in low glass transition temperatures, also for the electrolytes made. The pulsed field gradient nuclear magnetic resonance (PFG NMR) data suggest faster diffusion of the (MEEA)− anion than (P4,4,4,4)+ cation in the neat IL, but the addition of a Li salt results in slightly lower mobility of the former than the latter and lower ionic conductivity. This agrees with the combined 7Li NMR and attenuated total reflection–Fourier transform infrared (ATR–FTIR) spectroscopy data, which unambiguously reveal preferential interactions between the lithium cations and the carboxylate groups of the IL anions, which also increased as a function of the lithium salt concentration. In total, these systems provide a stepping stone for further design of fluorine-free and low glass transition temperature IL-based electrolytes and also stress how crucial it is to control the strength of ion–ion interactions.

sted, utgiver, år, opplag, sider
American Chemical Society (ACS), 2020. Vol. 124, nr 43, s. 9690-9700
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URN: urn:nbn:se:ltu:diva-81192DOI: 10.1021/acs.jpcb.0c04749ISI: 000587719800021PubMedID: 33078951Scopus ID: 2-s2.0-85094931121OAI: oai:DiVA.org:ltu-81192DiVA, id: diva2:1478117
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Validerad;2020;Nivå 2;2020-11-09 (johcin)

Tilgjengelig fra: 2020-10-21 Laget: 2020-10-21 Sist oppdatert: 2020-12-17bibliografisk kontrollert

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Shah, Faiz UllahKhan, Inayat AliFilippov, Andrei

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