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Time‐dependent properties of graphene nanoplatelets reinforced high‐density polyethylene
Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Materialvetenskap.ORCID-id: 0000-0001-5550-2962
Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Materialvetenskap. Riga Technical University, Institute of Construction and Reconstruction, Riga, Latvia.ORCID-id: 0000-0001-8050-2294
RISE SICOMP AB, Composite materials and product development, Piteå, Sweden.ORCID-id: 0000-0003-3449-8233
Luleå tekniska universitet, Institutionen för teknikvetenskap och matematik, Maskinelement.ORCID-id: 0000-0001-8676-8819
Visa övriga samt affilieringar
2021 (Engelska)Ingår i: Journal of Applied Polymer Science, ISSN 0021-8995, E-ISSN 1097-4628, Vol. 138, nr 30, artikel-id 50783Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

The deformation of polymers at constant applied stress is one of their major drawbacks, limiting their use in advanced applications. The study of this property using classical techniques requires extensive testing over long periods of time. It is well known that reinforced polymers show improved behavior over time compared to their neat counterparts. In this study, the effect of adding different amounts of graphene nanoplatelets (GNPs) on the time‐dependent properties of high‐density polyethylene (HDPE) is investigated using short‐term creep tests and load/unload recovery tests. The results are discussed in terms of the test profile and the influence of loading history. Viscoplasticity/viscoelasticity analysis is performed using Zapas model and by comparing creep, creep compliance and pure viscoelasticity curves. The results show that the reinforcement of 15 wt% GNP have the most significant effect on the time‐dependent behavior, reducing the strain by more than 50%. The creep compliance curves show that nano‐reinforced HDPE behaves nonlinearly viscoelastically even at very low stresses. In addition to demonstrating the effect of nano‐reinforcement, the discussion of the results concludes that the influence of loading history can be quite significant and should not be neglected in the design and evaluation of material behavior.

Ort, förlag, år, upplaga, sidor
John Wiley & Sons, 2021. Vol. 138, nr 30, artikel-id 50783
Nyckelord [en]
graphene and fullerenes, mechanical properties, theory and modeling, thermoplastics, viscosity and viscoelasticity
Nationell ämneskategori
Kompositmaterial och -teknik
Forskningsämne
Polymera kompositmaterial; Maskinelement
Identifikatorer
URN: urn:nbn:se:ltu:diva-83561DOI: 10.1002/app.50783ISI: 000636776700001Scopus ID: 2-s2.0-85103565338OAI: oai:DiVA.org:ltu-83561DiVA, id: diva2:1543088
Forskningsfinansiär
EU, Horisont 2020, 777810Interreg NordLuleå tekniska universitet
Anmärkning

Validerad;2021;Nivå 2;2021-06-10 (alebob);

An image from this article was selected for the cover image of the issue, it can be found here: https://doi.org/10.1002/app.50972

This article has previously appeared as a manuscript in a thesis.

Tillgänglig från: 2021-04-09 Skapad: 2021-04-09 Senast uppdaterad: 2023-03-16Bibliografiskt granskad
Ingår i avhandling
1. Multifunctionality and Durability of Cellulosic Fiber Reinforced Polymer Composites
Öppna denna publikation i ny flik eller fönster >>Multifunctionality and Durability of Cellulosic Fiber Reinforced Polymer Composites
2022 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Alternativ titel[sv]
Multifunktionalitet och beständighet hos cellulosabaserade fiberkompositer
Abstract [en]

The overall objective of this thesis is to develop and evaluate cellulose-based fiber composites with added multifunctionality for advanced applications. In the strive towards sustainable societies and industries, materials as well as production processes need to be assessed against the sustainability criteria and selected accordingly. Cellulosic fibers reinforced polymer composites are being increasingly used in applications where weight saving, and environmental friendliness is as important as structural performance. Nonetheless, these materials have their limitations regarding durability and stability of the properties, but their potential in use for advanced applications can be expanded if functionalized and considered beyond their structural performance. Such multi-functionality of composites can be achieved by the coating of fibers and/or modifying the matrix with functional reinforcement, or by both of these routes combined. Coating of fibers and modifying the matrix with nano-reinforcement are two selected approaches for imparting functionality to the cellulosic fiber composites in the current study. 

Conductive Regenerated Cellulose Fibers (RCFs) were produced by coating commercial RCFs with copper via electroless plating process. Electrical conductivity and mechanical performance were evaluated, and the coated fibers were transformed into an embedded strains sensor-like assembly that could be used as structural health monitoring system in composites structures. A noticeable degradation in the mechanical strength of fibers was realized and it was attributed to the influence of the chemicals of the final plating step of process on the chains of cellulose as well as the loss of crystalline order in the RCF. 

In order to obtain modified matrix (nanocomposites) for multifunctional wood polymer composites (WPC), the commercial masterbatches based on Graphene Nanoplatelets (GNPs) were utilized by melt extrusion process. Effect of the processing parameters in terms of change in screw configurations and the change in composition of the constituents on the structure and mechanical performance of the nanocomposites was studied.  Results showed that there is insignificant effect of the change in the screw configuration in comparison with the effect of increasing the content of the GNPs. Stronger shear forces did not result in better dispersion of the nanoparticles. Addition of the compatibilizer, on the other hand, resulted in an adverse effect on the properties compared to the formulations where it is absent. The use of GNPs with larger aspect ratio resulted in much better improvement in the mechanical performance. Addition of the nanoparticles did not only improve mechanical performance but also resulted in increased thermal conductivity and diffusivity, especially when micro-scale reinforcement was added because of synergy between wood fibers and the GNPs. This synergy was reflected also in the significant 99% improved wear resistance and the >80% reduction in the creep strains of wood and graphene reinforced composites. 

During the design and selection of materials, quasi-static properties are often used as a selection criterion. However, in reality structures in use are often loaded during lengthy periods of time which are followed by multiple steps of unloading/reloading, depending on the service conditions.  In such cases their time-dependent response becomes more crucial than instantaneous mechanical response. Typically, characterization of these properties requires a lot of time, but it may be significantly shortened if proper modeling and analysis are employed. The effect of addition of GNPs to the polymer and wood composites has been studied experimentally by short term creep tests. The materials showed highly nonlinear response even at very low loading stresses, but the addition of the nanoparticles resulted in a decrease in the nonlinearity and in the irreversible strains due to plasticity. Modelling approaches have been used to extract parameters from experimental data that could be used in predicting long term performance using Zapas model for viscoplasticity and Schapery’s model for nonlinear viscoelasticity. 

Overall, the results of the performed work contribute to enriching the research field with the potential the bio-based composites have to offer in the advanced application and how nano-scale reinforcement can interact synergistically with the micro-sized fibers to improve the overall performance of WPC and under different loading scenarios.  

Ort, förlag, år, upplaga, sidor
Luleå University of Technology, 2022
Serie
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
Nationell ämneskategori
Kompositmaterial och -teknik
Forskningsämne
Polymera kompositmaterial
Identifikatorer
urn:nbn:se:ltu:diva-90138 (URN)978-91-8048-057-4 (ISBN)978-91-8048-058-1 (ISBN)
Disputation
2022-06-09, E632, Universitetsområdet Porsön, Luleå, 12:30 (Engelska)
Opponent
Handledare
Tillgänglig från: 2022-04-08 Skapad: 2022-04-08 Senast uppdaterad: 2022-05-19Bibliografiskt granskad
2. Development of Constituents for Multi-functional Composites Reinforced with Cellulosic Fibers
Öppna denna publikation i ny flik eller fönster >>Development of Constituents for Multi-functional Composites Reinforced with Cellulosic Fibers
2019 (Engelska)Licentiatavhandling, sammanläggning (Övrigt vetenskapligt)
Alternativ titel[sv]
Utveckling av beståndsdelar för multifunktionella kompositer förstärkta med cellulosafibrer
Abstract [en]

Bio-basedcomposites are being increasingly used in applications where weight saving,and environmental friendliness is as important as structural performance. Obviously, bio-based materials have their limitations regarding durability and stability of the properties,but their potential in use for advanced applications can be expanded if they were functionalized and considered beyond their structural performance.

Multifunctionalityincomposites can be achieved by modifyingeither of the composite constituents at different levelsso that they can perform energy-associated roles besides their structural reinforcement in the system. For the fibers, this can be done at the microscale by altering theirmicrostructure during spinning process or by applying functional coatings. As for the matrix, it is usually done by incorporating additives that can impart the required characteristics to the matrix. The nano-sized additives that mightbe considered for this objective are graphene and carbon nano-tubes. A big challenge with such materials is the difficulty to reachthe dispersionstate necessary for formation ofstable network to overcome the percolation threshold for conductivity. However, once the network is formed, the composite can have improved mechanical performance together with one or more of the added functionalities such as barrier capabilities,thermal and/or electrical conductivities or electromagnetic interference ability.

Enormous work has been done to achieve the functionality incomposites produced with special care in laboratories. However, when it comes to mass production, it is both cost and energy inefficient to use tedious,complex methods for the manufacturing. Hence there is a need to investigate the potential of using scalable and industrial-relevant techniques and materials with acceptable compromise between cost and properties.

The work presented in this thesis is performedwithin two projects aiming to achieve functional composites based on natural and man-made cellulosic fibers suitable for industrial upscaling. Conductive Regenerated Cellulose Fibers (RCFs) were produced by coating them with copper by electroless coating process using commercial materials. On the other hand, commercial masterbatches based on Graphene Nano-Platelets (GNPs) were used to produce wood polymer composites (WPC) with added multifunctionality by melt extrusion process. The process is one of the conventional methods used inpolymerproductionand needsno modifications for processingfunctional composites. Both materials together can be used to produce hybrid functional composites.

The incorporation of the GNP into HDPE has resulted in improvement in the mechanical propertiesof polymer as well as composite reinforced with wood fibers. Stiffness has increased to a large extent while effect on the strength was less pronounced(>100% and 18% for stiffness and strength at 15%GNP loading). The enhancement of thermal conductivityat higher graphene loadingswas also observed. Moreover, time-dependent response of the polymer has also been affected and the addition of GNP has resulted in reduced viscoplastic strains and improved creep behavior.

The copper-coated cellulose fibers showed a significant increasein electrical conductivity(<1Ω/50mm of coated samples) and a potential in use as sensor materials. However, these results come with the cost of reduction in mechanical properties of fibers (10% and 70% for tensile stiffness and strength, respectively) due to theeffect ofchemicals involved in the process.

Ort, förlag, år, upplaga, sidor
Luleå: Luleå tekniska universitet, 2019
Serie
Licentiate thesis / Luleå University of Technology, ISSN 1402-1757
Nyckelord
cellulose fibers, multi-functional, composites, nano-reinforcement, thermoplastics, development
Nationell ämneskategori
Kompositmaterial och -teknik
Forskningsämne
Polymera kompositmaterial
Identifikatorer
urn:nbn:se:ltu:diva-73736 (URN)978-91-7790-372-7 (ISBN)978-91-7790-373-4 (ISBN)
Presentation
2019-06-05, E231, Luleå, 10:00 (Engelska)
Opponent
Handledare
Tillgänglig från: 2019-04-25 Skapad: 2019-04-24 Senast uppdaterad: 2023-03-16Bibliografiskt granskad

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