System disruptions
We are currently experiencing disruptions on the search portals due to high traffic. We are working to resolve the issue, you may temporarily encounter an error message.
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Aggregation Properties of Triton X-100 in a Mixture of Ordinary and Heavy Water
Department of Physics, Kazan National Research Technological University, 420015, Kazan, Russian Federation.
Institute of Physics, Kazan Federal University, 420008, Kazan, Russian Federation.
Department of Physics, Kazan National Research Technological University, 420015, Kazan, Russian Federation.
Department of Analytical Chemistry, Kazan National Research Technological University, 420015, Kazan, Russian Federation.
Show others and affiliations
2023 (English)In: Applied Magnetic Resonance, ISSN 0937-9347, E-ISSN 1613-7507, Vol. 54, no 3, p. 415-425Article in journal (Refereed) Published
Abstract [en]

The dynamic and aggregation properties of Triton X-100 in a mixture of ordinary and heavy water in a wide temperature range from room temperature to the cloud point and above were studied. The ratio of ordinary and heavy water was calculated in such a way as to ensure equal densities of Triton X-100 and the water mixture. This made it possible to exclude the effects of sedimentation and study the evolution of Triton X-100 micelles and aggregates, without complication by the effects of spatial phase separation above the cloud point. Self-diffusion coefficients of Triton X-100 molecules were measured by NMR, and the effective hydrodynamic radii of micelles and aggregates were calculated using the Stokes-Einstein relation. The anomalous temperature behavior of the diffusion coefficient of Triton X-100 molecules is explained by changes in the sizes of diffusing objects during their evolution from micelles to dehydrated aggregates below the cloud point and by changes in the sizes of aggregates above the cloud point. The results of the NMR studies are confirmed by data obtained by dynamic light scattering.

Place, publisher, year, edition, pages
Springer Nature , 2023. Vol. 54, no 3, p. 415-425
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-95862DOI: 10.1007/s00723-023-01529-8ISI: 000934332600001Scopus ID: 2-s2.0-85147927821OAI: oai:DiVA.org:ltu-95862DiVA, id: diva2:1743018
Note

Validerad;2023;Nivå 2;2023-03-15 (hanlid);

Funder: Ministry of Science and Higher Education of the Russian Federation (075-10-2021-115); Program Priority-2030 for Kazan Federal University

Available from: 2023-03-13 Created: 2023-03-13 Last updated: 2023-03-15Bibliographically approved

Open Access in DiVA

fulltext(756 kB)305 downloads
File information
File name FULLTEXT01.pdfFile size 756 kBChecksum SHA-512
2db171b78cd86d80ceaa7b54b050042e7cf6326cccc6cc4194b4e996679287249cf9788b386a9edd2d65b0fae005f54a7823a1159870049721f2ed5bc09d1dae
Type fulltextMimetype application/pdf

Other links

Publisher's full textScopus

Authority records

Filippov, Andrei

Search in DiVA

By author/editor
Filippov, Andrei
By organisation
Chemical Engineering
In the same journal
Applied Magnetic Resonance
Physical Chemistry

Search outside of DiVA

GoogleGoogle Scholar
Total: 305 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 339 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf