A novel modification layer on the surface of pearlite-ferrite matrix ductile iron was fabricated under irradiation of Nd:YAG laser beam equipped with self-designed diffractive optical element (DOE) which produces a 5×5 two-dimensional array distribution at the focal plane. The microstructure of the layer along the surface and the direction of the layer depth had obvious gradient distribution, and therefore the two-dimensional microhardness map of the layer alternated higher hardness with lower hardness. The results showed that the novel modification layer is expected to have excellent combination of strength and toughness