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Synthesis and Structural Evaluation of Five Coordination Complexes of Benzenepentacarboxylic Acid with Aza-donor Ligands
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering.ORCID iD: 0000-0001-7469-4197
Solid State and Supramolecular Structural Chemistry Laboratory, School of Basic Sciences, Indian Institute of Technology Bhubaneswar.
Solid State and Supramolecular Structural Chemistry Laboratory, School of Basic Sciences, Indian Institute of Technology Bhubaneswar.
Solid State and Supramolecular Structural Chemistry Laboratory, School of Basic Sciences, Indian Institute of Technology Bhubaneswar.
2016 (English)In: Journal of Molecular Structure, ISSN 0022-2860, E-ISSN 1872-8014, Vol. 1114, p. 38-47Article in journal (Refereed) Published
Abstract [en]

Synthesis and structural features of five new coordination assemblies, [Co(bpyH)(H2O)5](BPCH)·(bpyH2)0.5·(H2O) (1a), [{Cu(H2O)3}·{Cu0.5(bpy)0.5(H2O)0.5}2(μ-BPCH)] (1b), [{Cd0.5(BPCH)}2·{Cd0.5(bpy)(H2O)2}2]·6(H2O) (1c), [Cu(BPCH2)(bpyeaH)].2(H2O) (1d) and [Cd2 (bpyea)0.5(oxalate)0.5(μ-BPC)(H2O)]·(bpyeaH2)·2(H2O) (1e), have been reported. All the assemblies were prepared by co-crystallization of benzenepentacarboxylic acid (BPCH5) either with 4,4′-bipyridine (bpy) or 1,2-bis(4-pyridyl)ethane (bpyea) in the presence of a transition metal ion (either Co(II), Cu(II) or Cd(II)) as the case may be. All the five compounds were synthesized by hydrothermal method and structures were determined by single crystal X-ray diffraction. All the obtained compounds, 1a-1e, exhibit distinct 3-D polymeric architectures either in the form of stacked layers or host-guest networks in which water molecules play a pivotal role providing additional stabilization by coordinate bonds as well as hydrogen bonds. Other non-covalent interactions such as C–H…π and π…π stacking also participate in the formation of exotic 3-D structures of these complexes.

Place, publisher, year, edition, pages
2016. Vol. 1114, p. 38-47
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-12136DOI: 10.1016/j.molstruc.2016.02.010ISI: 000374073800006Scopus ID: 2-s2.0-84977672684Local ID: b368f282-a5e8-478e-9d88-dcf3c8c96a27OAI: oai:DiVA.org:ltu-12136DiVA, id: diva2:985086
Note
Validerad; 2016; Nivå 2; 20160212 (andbra)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Shimpi, Manishkumar

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