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Assessment of the natural variability of B, Cd, Cu, Fe, Pb, Sr, Tl and Zn concentrations and isotopic compositions in leaves, needles and mushrooms using single sample digestion and two-column matrix separation
ALS Scandinavia AB.ORCID iD: 0000-0003-4505-4590
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.
ALS Scandinavia AB.
ALS Scandinavia AB.
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2016 (English)In: Journal of Analytical Atomic Spectrometry, ISSN 0267-9477, E-ISSN 1364-5544, Vol. 31, no 1, p. 220-233Article in journal (Refereed) Published
Abstract [en]

An analytical procedure allowing multi-elemental analyses and isotope ratio measurements of eight of these (B, Cd, Cu, Fe, Pb, Sr, Tl and Zn) in matrices relevant for bio-monitoring using a single highpressure acid digestion was developed. Method blanks, separation efficiency of matrix elements, repeatability and reproducibility were evaluated using sets of preparation blanks, certified reference materials and duplicate samples prepared and analyzed over a period of several months. The method was used to assess the natural variability of concentrations and isotopic compositions in bio-indicators (tree leaves, needles and mushrooms, over 240 samples) collected mainly from a confined area in North-East Sweden. Ranges found from leaves and needles were compared with data obtained for limited numbers of samples collected in Spain, Italy, France, United Kingdom and Iceland.

Place, publisher, year, edition, pages
2016. Vol. 31, no 1, p. 220-233
National Category
Geochemistry
Research subject
Applied Geology
Identifiers
URN: urn:nbn:se:ltu:diva-14151DOI: 10.1039/C5JA00274EISI: 000367315200018Scopus ID: 2-s2.0-84952898602Local ID: d7cbb017-e0af-48ac-b1b7-ca535fa94cc0OAI: oai:DiVA.org:ltu-14151DiVA, id: diva2:987105
Note
Validerad; 2016; Nivå 2; 20151201 (nicpal)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2018-07-10Bibliographically approved

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Rodushkin, IliaPallavicini, NicolaEngström, EmmaÖhlander, BjörnIngri, JohanBaxter, Douglas C.

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