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Porphyrin supramolecular solids assembled with the aid of lanthanide ions
Tel Aviv UniVersity, School of Chemistry, Sackler Faculty of Exact Sciences.
Tel Aviv UniVersity, School of Chemistry, Sackler.
2006 (English)In: Crystal Growth & Design, ISSN 1528-7483, E-ISSN 1528-7505, Vol. 6, no 12, p. 2651-2654Article in journal (Refereed) Published
Abstract [en]

Reactions of free-base tetra(4-carboxyphenyl)porphyrin with lanthanide ions as Pr3+, Dy3+, and Nd3+ led to open metal-organic framework solids sustained by polynuclear metal-carboxylate clusters. Their three-dimensional structures are characterized by channel voids accessible to other guest components (e.g., water, small organics). Crystalline solids obtained by the hydrothermal synthesis with Dy3+ and Nd3+ reagents reveal remarkable stability and represent the first example of hybrid porphyrin-lanthanide single framework architectures.

Place, publisher, year, edition, pages
2006. Vol. 6, no 12, p. 2651-2654
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URN: urn:nbn:se:ltu:diva-14631DOI: 10.1021/cg060520rLocal ID: e082be50-07b6-11dd-97e0-000ea68e967bOAI: oai:DiVA.org:ltu-14631DiVA, id: diva2:987604
Note
Upprättat; 2006; 20080411 (andbra)Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2017-11-24Bibliographically approved

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George, Sumod

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