Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Simple directed material design through in situ substitution of proton with Cu+ ions
Institute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China.
Institute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China.
Institute of Chemistry and Chemical Engineering, University of Jinan, No.106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Sustainable Process Engineering.ORCID iD: 0000-0001-9794-8305
2009 (English)In: Journal of Inorganic and Organometallic Polymers and Materials, ISSN 1574-1443, Vol. 19, no 4, p. 485-493Article in journal (Refereed) Published
Abstract [en]

A new inorganic-organic hybrid material (C10H8N2H)2(Mo8O26) · 2NH4 (1) was prepared under solvothermal conditions (H2O/ethanol), which was then used as a starting material in the synthesis of another material, (C10H8N2Cu)2(Mo8O26) · 2NH4 (2). Each compound has been characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, thermogravimetric analysis, fluorescence, FT-IR, and bond valence sum calculations. The comparative study focuses on the transformation and structural change between 1 and 2, which arises from the simple substitution of the proton in 1 with the Cu+ ions. The other surprising feature is that Cu+ ions can not only directly be used to substitute the proton of 1 but also ameliorate its photoluminescence property. It means that 1 appears to have recognizable functional protons in the solid-state structure and, hence, can very well be considered as an ideal precursor agent to design the functional materials with special architectures and photoactive properties.

Place, publisher, year, edition, pages
2009. Vol. 19, no 4, p. 485-493
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-16023DOI: 10.1007/s10904-009-9290-8ISI: 000272035600008Scopus ID: 2-s2.0-77349115477Local ID: f9ae3100-672f-11de-9f57-000ea68e967bOAI: oai:DiVA.org:ltu-16023DiVA, id: diva2:988999
Note

Validerad; 2009; 20090702 (ysko)

Available from: 2016-09-29 Created: 2016-09-29 Last updated: 2023-10-14Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textScopus

Authority records

Holmgren, Allan

Search in DiVA

By author/editor
Holmgren, Allan
By organisation
Sustainable Process Engineering
Physical Chemistry

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 23 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf