A new approach for the diffusion coefficient evaluation of sulfur in CaO-SiO 2-Al 2O 3 slag
2011 (English)In: Diffusion and defect data, solid state data. Part A, Defect and diffusion forum, ISSN 1012-0386, E-ISSN 1662-9507, Vol. 312-315, 626-634 p.Article in journal (Refereed) Published
The Diffusion coefficient of sulfur in a ternary slag with composition of 51.5% CaO- 9.6% SiO 2- 38.9% Al 2O 3 was measured at 1723 K by chemical diffusion from the variation of concentration of sulfur in silver metal. A MATLAB program was developed to find the concentration variation of sulfur in silver metal using various critical parameters like the diffusion coefficient of sulfur in slag available in literature, sulfur partition ratio, sulfide capacity of the slag and the its density. The P S2 and P O2 pressures were calculated from the Gibbs energy of the equilibrium reaction between CaO in the slag and solid CaS and confirming the same by using ThermoCalc. The density of the slag at 1723 K was obtained from earlier experiments. Initially the order of magnitude for the diffusion coefficient was taken from the works of Saito and Kawai but later was modified so that the concentration changes of Sulfur obtained from the program agreed with the experimental results. The diffusion coefficient of sulfur in 51.5% CaO- 9.6% SiO 2- 38.9% Al 2O 3 slag at 1723 K was estimated as 4.14×10 -6 cm 2/sec
Place, publisher, year, edition, pages
2011. Vol. 312-315, 626-634 p.
IdentifiersURN: urn:nbn:se:ltu:diva-34344DOI: 10.4028/www.scientific.net/DDF.312-315.626Local ID: 8858705d-f47e-4584-9635-cfa1ce01628bOAI: oai:DiVA.org:ltu-34344DiVA: diva2:1007594
International Conference on Diffusion in Solids and Liquids, Mass Transfer - Heat Transfer - Microstructure & Properties - Nanodiffusion and Nanostructured Materials : 05/07/2010 - 07/07/2010
Upprättat; 2011; 20121203 (andbra); Konferensartikel i tidskrift2016-09-302016-09-30Bibliographically approved