Raman spectroscopic studies of the structure of supersaturated ammonium dihydrogen phosphate solutions
1984 (English)In: Industrial crystallization 84: proceedings of the 9th Symposium on industrial crystallization, the Hague, the Netherlands, September 25-28, 1984 / [ed] S.J. Jančić; E.J. de Jong, Amsterdam: Elsevier, 1984, 233-236 p.Conference paper (Refereed)
Raman spectroscopic studies of quiescent under and supersaturated ammonium dihydrogen phosphate (ADP) aqueous solutions were performed on the nu //1 (totally symmetric or breathing mode) and nu //3 (symmetric twist) H//2PO//4 OVER BAR bands as well as for the nu //1 band of solid ADP and solid diammonium hydrogen phosphate (DHP). The splitting of the non-degenerate ADP nu //1 band in concentrated solution is interpreted in terms of a well-ordered quasi-crystalline solution structure. Increases in nu //1 half-width at half-height support this view.
Place, publisher, year, edition, pages
Amsterdam: Elsevier, 1984. 233-236 p.
, Process technology proceedings, 2
Research subject Biochemical Process Engineering
IdentifiersURN: urn:nbn:se:ltu:diva-37991Local ID: c399d420-3efd-11de-bf5b-000ea68e967bISBN: 0-444-42406-7OAI: oai:DiVA.org:ltu-37991DiVA: diva2:1011490
Symposium on industrial crystallization : 25/09/1984 - 28/09/1984
Upprättat; 1984; 20090512 (ysko)2016-10-032016-10-03