System disruptions
We are currently experiencing disruptions on the search portals due to high traffic. We are working to resolve the issue, you may temporarily encounter an error message.
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Extrusion of Polylactic acid (PLA) Nanocomposites using Liquid Feeding of Cellulose Nanocrystals
2014 (English)Independent thesis Advanced level (degree of Master (Two Years)), 20 credits / 30 HE creditsStudent thesis
Abstract [en]

The purpose of this work was to prepare, polylactic acid (PLA) based nanocomposites with cellulose nanocrystals (CNCs) as reinforcement and triethyl citrate (TEC) as an additive using compounding extrusion. The final nanocomposites thermal- and mechanical properties, as well as the crystallinity, the transparency and the morphology were characterized. Prior the extrusion process, CNC suspensions were prepared by dispersing the CNCs in TEC and water:ethanol or TEC:ethanol mixtures to facilitate their dispersion and distribution in the final composite. The prepared suspensions were then liquid fed into the extruder. After the compounding process, the obtained nanocomposites were compression molded to sheets, from which test samples were cut. The feeding of the liquid suspensions resulted in nanocomposites with CNCs content 1 and 5 wt% and the TEC content varied between 4 and 17 wt%. The study showed that is possible to prepare nanocomposites using liquid feeding of CNCs, although it was found that the high liquid phase content in the suspensions together with a high feeding rate affected the final composition of the materials. It was also demonstrated that the presence of water in the feeding suspensions improves the CNCs dispersion in the nanocomposite matrix. OM and SEM microscopy showed the presence of CNCs agglomerations in the obtained nanocomposites although the materials produced with low content of CNCs resulted in better CNC dispersion and higher transparency. The nanocomposite containing 5 wt% CNCs and prepared by CNCs aqueous suspension presented increased tensile strength and E-modulus values respect to the reference material. The elongation was completely affected by the amount of plasticizer since values up to 295% for 17 wt% TEC content were detected. Finally, X-ray diffraction study revealed low crystallinity in almost all the obtained nanocomposites; only one material exhibited a crystalline structure since, in this case, CNCs were expected to act as nucleating agents, facilitating the crystallization of the PLA matrix.

Place, publisher, year, edition, pages
2014. , p. 57
Keywords [en]
Technology, extrusion, liquid feeding, biopolymers, cellulose nanocrystals, melt mixing
Keywords [sv]
Teknik
Identifiers
URN: urn:nbn:se:ltu:diva-45031Local ID: 2c5e34e5-ff32-4066-92ea-c09132ebe0b7OAI: oai:DiVA.org:ltu-45031DiVA, id: diva2:1018310
Subject / course
Student thesis, at least 30 credits
Educational program
Materials Engineering, master's level
Examiners
Note
Validerat; 20140930 (global_studentproject_submitter)Available from: 2016-10-04 Created: 2016-10-04Bibliographically approved

Open Access in DiVA

fulltext(2418 kB)766 downloads
File information
File name FULLTEXT02.pdfFile size 2418 kBChecksum SHA-512
5f3ea5241c5fbed163c9bb763c1e1531aa1ac11c4802c252fe7b045b18e04c6460a9b4a24b8856e81a7af0c9bb924006f72d3b47b6f8fb62b7525844c5e2e21a
Type fulltextMimetype application/pdf

Search outside of DiVA

GoogleGoogle Scholar
Total: 766 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

urn-nbn

Altmetric score

urn-nbn
Total: 270 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf