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Viscometric Analysis of Miscibility and Interactions for Binary, Ternary Polycarbonate/Brominated Polystyrene + Chloroform Systems at Different Temperatures
Department of Chemistry, Faculty of Engineering, Istanbul University.
Department of Chemistry, Faculty of Engineering, Istanbul University.
2013 (English)In: Journal of macromolecular science. Pure and applied chemistry (Print), ISSN 1060-1325, E-ISSN 1520-5738, Vol. 50, no 9, 1007-1011 p.Article in journal (Refereed) Published
Abstract [en]

Viscosities of ternary systems consist of polycarbonate (PC)/brominated polystyrene (PBrS) in chloroform and their corresponding binary systems were measured at different temperatures (20, 25, and 30°C). All the measurements were carried out at the concentration ranges of 0.1–0.6 g·dL−1. The mass ratio of PC to PBrS was selected as 75:25, 50:50, and 25:75 in the ternary solutions. Two empirical expressions of Huggins and Kraemer equations with three-parameters were used for reproducing of the experimental viscosity data. The fitting parameters were obtained for the corresponding temperatures. The miscibility criteria on the basis of the sign of Δ[η]m based on the difference between experimental and ideal values of [η]m, was calculated by applying the Garcia et al., theoretical equation. The effect of temperature on the viscosity data was also studied. The results from this method were correlated with the miscibility data obtained for the same system by differential scanning calorimeter (DSC) findings.

Place, publisher, year, edition, pages
Taylor & Francis, 2013. Vol. 50, no 9, 1007-1011 p.
National Category
Polymer Technologies Other Materials Engineering
Research subject
Engineering Materials
Identifiers
URN: urn:nbn:se:ltu:diva-61897DOI: 10.1080/10601325.2013.814337ISI: 000322616500012Scopus ID: 2-s2.0-84882360474OAI: oai:DiVA.org:ltu-61897DiVA: diva2:1073170
Available from: 2017-02-09 Created: 2017-02-09 Last updated: 2017-11-24Bibliographically approved

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Nikjoo, Dariush

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