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Effect of tri-potassium phosphate on volumetric, acoustic, and transport behaviour of aqueous solutions of 1-ethyl-3-methylimidazolium bromide at T = (298.15 to 318.15) K
Physical Chemistry Department, Faculty of Chemistry (Excellence of Science for New Materials and Clean Chemistry) University of Tabriz.
2010 (English)In: Journal of Chemical Thermodynamics, ISSN 0021-9614, E-ISSN 1096-3626, Vol. 42, no 10, 1213-1221 p.Article in journal (Refereed) Published
Abstract [en]

Density, sound velocity, and viscosity of 1-ethyl-3-methylimidazolium bromide, [Emim][Br], in aqueous solutions of tri-potassium phosphate with salt weight fractions (ws = 0.00, 0.10, 0.15, and 0.20) have been measured as a function of concentration of [Emim][Br] at atmospheric pressure and T = (298.15, 303.15, 308.15, 313.15, and 318.15) K. The apparent molar volume, isentropic compressibility, apparent isentropic compressibility, and relative viscosity values have been evaluated from the experimental data. The partial molar volume and isentropic compressibility at infinite dilution, and viscosity B-coefficient obtained from these data have been used to calculate the corresponding transfer parameters for the studied IL from water to the aqueous tri-potassium phosphate solutions. Also, an empirical equation was satisfactorily used to correlate the experimental viscosity data.

Place, publisher, year, edition, pages
Elsevier, 2010. Vol. 42, no 10, 1213-1221 p.
National Category
Engineering and Technology Bio Materials
Research subject
Wood and Bionanocomposites
Identifiers
URN: urn:nbn:se:ltu:diva-61901DOI: 10.1016/j.jct.2010.04.025OAI: oai:DiVA.org:ltu-61901DiVA: diva2:1073174
Available from: 2017-02-09 Created: 2017-02-09 Last updated: 2017-11-24Bibliographically approved

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Sarmad, Shokat

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