Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Phase Diagrams for Liquid-Liquid and Liquid-Solid Equilibrium of the TernaryPoly(ethylene glycol) Dimethyl Ether 2000 + Sodium Carbonate + Water System
Physical Chemistry Department, Faculty of Chemistry (Excellence of Science for New Materials and Clean Chemistry) University of Tabriz.
Physical Chemistry Department, University of Tabriz.ORCID iD: 0000-0002-4628-3857
2009 (English)In: Journal of Chemical and Engineering Data, ISSN 0021-9568, E-ISSN 1520-5134, Vol. 53, no 11, p. 2666-2670Article in journal (Refereed) Published
Abstract [en]

The complete phase diagram for the poly(ethylene glycol) dimethyl ether 2000 (PEGDME2000) + Na2CO3+ H2O system at 298.15 K was determined. Experimental liquid-liquid equilibrium phase diagrams, tielines, and plait points were obtained for the ternary system. Compositions of the liquid-liquid and the liquid-liquid-solid equilibria were determined from calibration curves of refractive index of the solutions, and atomic absorption (AA) and X-ray diffraction analyses were made on the solids. Binodal curves were described using the Merchuk equation at T ) (288.15, 293.15, 298.15, 308.15, and 318.15) K, and the fitting parameters were obtained for the corresponding temperatures. The effects of temperature on the binodal curve were also studied, and it was observed that the area of the biphasic region increased slightly with increase in temperature. Also, the tie lines were fitted to both the Othmer-Tobias and Bancroft andSetschenow-type equations. Correlation coefficients for all equations are reported.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2009. Vol. 53, no 11, p. 2666-2670
National Category
Polymer Technologies Other Materials Engineering
Research subject
Engineering Materials
Identifiers
URN: urn:nbn:se:ltu:diva-61918DOI: 10.1021/je8005858OAI: oai:DiVA.org:ltu-61918DiVA, id: diva2:1073222
Available from: 2017-02-09 Created: 2017-02-09 Last updated: 2018-03-05Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full text

Search in DiVA

By author/editor
Nikjoo, Dariush
In the same journal
Journal of Chemical and Engineering Data
Polymer TechnologiesOther Materials Engineering

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 139 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf