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Selective N-alkylation of primary amines with R-NH2·HBr and alkyl bromides using a competitive deprotonation/protonation strategy
Synthetic Chemistry Division, Defence R and D Establishment.ORCID iD: 0000-0002-6295-4112
Synthetic Chemistry Division, Defence R and D Establishment.
Synthetic Chemistry Division, Defence R and D Establishment.
Synthetic Chemistry Division, Defence R and D Establishment.
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Number of Authors: 52014 (English)In: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 4, no 35, p. 18229-18233Article in journal (Refereed) Published
Abstract [en]

Monoalkylation of primary amines using amine hydrobromides and alkyl bromides has been carried out. Under controlled reaction conditions the reactant primary amine was selectively deprotonated and made available for reaction, while the newly generated secondary amine remained protonated, and did not participate in alkylation further. Reaction was carried out under mild reaction conditions and was applicable to a wide range of primary amines and alkyl bromides.

Place, publisher, year, edition, pages
2014. Vol. 4, no 35, p. 18229-18233
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
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URN: urn:nbn:se:ltu:diva-62811DOI: 10.1039/c4ra01915fOAI: oai:DiVA.org:ltu-62811DiVA, id: diva2:1085859
Available from: 2017-03-30 Created: 2017-03-30 Last updated: 2017-11-29Bibliographically approved

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Bhattacharyya, Shubhankar

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