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Ion dynamics in halogen-free phosphonium bis(salicylato)borate ionic liquid electrolytes for lithium-ion batteries
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering.ORCID iD: 0000-0003-3652-7798
Institute of Physics, Kazan Federal University .
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering. Institute of Physics, Kazan Federal University.ORCID iD: 0000-0002-6810-1882
2017 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 19, no 25, 16721-16730 p.Article in journal (Refereed) Published
Abstract [en]

This study was focused on the investigation of ion dynamics in halogen-free, hydrophobic, and hydrolytically stable phosphonium bis(salicylato)borate [P4,4,4,8][BScB] ionic liquid electrolytes for lithium-ion batteries. The structure and purity of the synthesized ionic liquid and lithium bis(salicylato)borate Li[BScB] salt were characterized using 1H, 13C, 31P, and 11B NMR spectroscopy. The Li[BScB] salt was mixed with an ionic liquid at the concentrations ranging from 2.5 mol% to 20 mol%. The physicochemical properties of the resulting electrolytes were characterized using thermal analysis (TGA and DSC), electrical impedance spectroscopy, and pulsed-field gradient (PFG) NMR and ATR-FTIR spectroscopy. The apparent transfer numbers of the individual ions were calculated from the diffusion coefficients of the cation and anion as determined via the PFG NMR spectroscopy. NMR and ATR-FTIR spectroscopic techniques revealed dynamic interactions between the lithium cation and bis(salicylato)borate anion in the electrolytes. The ion–ion interactions were found to increase with the increasing concentration of the Li[BScB] salt, which resulted in ionic clustering at the concentrations higher than 15 mol% of Li salt in the ionic liquid.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2017. Vol. 19, no 25, 16721-16730 p.
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-63622DOI: 10.1039/C7CP02722BISI: 000404530600045PubMedID: 28621370Scopus ID: 2-s2.0-85021881483OAI: oai:DiVA.org:ltu-63622DiVA: diva2:1103753
Note

Validerad;2017;Nivå 2;2017-08-11 (rokbeg)

Available from: 2017-05-30 Created: 2017-05-30 Last updated: 2017-11-24Bibliographically approved

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Publisher's full textPubMedScopushttp://pubs.rsc.org/en/content/articlelanding/2017/cp/c7cp02722b#!divAbstract

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Shah, Faiz UllahFilippov, Andrei

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