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Green-emitting manganese (II) complexes with phosphoramide and phenylphosphonic diamide ligands
Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia.
Departamento de Química Inorgánica, Universidade de Vigo, Facultade de Química, Edificio de Ciencias Experimentais.
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science. Consorzio Interuniversitario Reattività Chimica e Catalisi (CIRCC) .ORCID iD: 0000-0002-3443-3707
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science.
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2018 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 92, p. 145-150Article in journal (Refereed) Published
Abstract [en]

Tetrahedral manganese(II) complexes having formulae [MnX2{O = PR(NMe2)2}2] (X = Br, I; R = NMe2, Ph) were isolated and characterized, and in the case of [MnBr2{O = PPh(NMe2)2}2] the structure was ascertained by means of single crystal X-ray diffraction. All the complexes showed intense green emission assigned to the Mn(II) 4T1(4G) → 6A1(6S) transition upon excitation with UV light, with photoluminescence lifetimes in the range 100–1000 μs. Bromo-complexes maintain their luminescence features once dispersed in polycaprolactone matrix.

Place, publisher, year, edition, pages
Elsevier, 2018. Vol. 92, p. 145-150
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Experimental Physics
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URN: urn:nbn:se:ltu:diva-68509DOI: 10.1016/j.inoche.2018.04.023Scopus ID: 2-s2.0-85046357935OAI: oai:DiVA.org:ltu-68509DiVA, id: diva2:1201445
Note

Validerad;2018;Nivå 2;2018-05-15 (andbra)

Available from: 2018-04-25 Created: 2018-04-25 Last updated: 2018-05-15Bibliographically approved

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