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Zeolite MFI adsorbent for recovery of butanol from ABE fermentation broths produced from an inexpensive black liquor-derived hydrolyzate
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering. Department of Chemical Engineering COMSATS Institute of Information Technology Lahore.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering.ORCID iD: 0000-0002-7477-4960
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering.ORCID iD: 0000-0003-1053-4623
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering.ORCID iD: 0000-0002-4755-5754
2018 (English)In: Biomass Conversion and Biorefinery, ISSN 2190-6815, E-ISSN 2190-6823Article in journal (Refereed) Epub ahead of print
Abstract [en]

In this work, high-silica MFI zeolite adsorbent was evaluated for selective recovery of butanol from a real ABE (acetone, butanol, and ethanol) fermentation broth by batch adsorption measurements. The fermentation broth was produced using a hydrolyzate originating from Kraft black liquor, an internal stream in pulp mills, i.e., a low-cost substrate. The adsorbent was very selective towards butanol and butyric acid and became nearly saturated with a mixture of butanol and butyric acid with relative amounts of butanol and butyric acid depending on the pH. The presence of phenolic compounds in significant amounts in the fermentation broths, originating from the black liquor hydrolyzate, did not affect the adsorption of butanol and butyric acid.

Place, publisher, year, edition, pages
2018.
National Category
Chemical Engineering
Research subject
Chemical Technology
Identifiers
URN: urn:nbn:se:ltu:diva-68742DOI: 10.1007/s13399-018-0315-9OAI: oai:DiVA.org:ltu-68742DiVA, id: diva2:1206101
Available from: 2018-05-16 Created: 2018-05-16 Last updated: 2018-05-16

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Faisal, AbrarZhou, MingHedlund, JonasGrahn, Mattias
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