In this paper, the investigation of energy transfer efficiency in Tb³⁺-Yb³⁺ co-doped SiO₂-HfO₂ glass and glass-ceramic waveguides is presented. Cooperative energy transfer between these two ions allows to cut one UV or 488 nm photon in two 980 nm photons and could have important applications in improving the performance of photovoltaic solar cells. Thin films with different molar concentrations of rare earths, up to a total concentration of 21%, were prepared by a sol-gel route, using dip-coating deposition technique on SiO₂ substrates. The ratio between Yb³⁺ and Tb³⁺ ions in all the prepared thin films is constant and equal to 4. The energy transfer between Tb³⁺ and Yb³⁺ ions in glass and glass-ceramic waveguides shows the higher efficiency for glass-ceramic with a maximum quantum transfer efficiency of about 190% for the sample containing 19% of rare earths.