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Luminescent europium(III) complexes containing an electron rich 1,2,3-triazolyl-pyridyl ligand
Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, 30172 Mestre (VE), Italy .
Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, 30172 Mestre (VE), Italy .
Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca’ Foscari Venezia, Via Torino 155, 30172 Mestre (VE), Italy .
Dipartimento di Scienze del Farmaco Università di Padova, via Marzolo 5, 35131 Padova, Italy.
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2018 (English)In: New Journal of Chemistry, ISSN 1144-0546, E-ISSN 1369-9261, Vol. 42, no 13, p. 11064-11072Article in journal (Refereed) Published
Abstract [en]

An improved synthesis of the electron-rich N,N-chelating ligand, 2-(1-t-butyl-1H-1,2,3-triazol-4-yl)pyridine (L), has been developed by coupling t-butyl-azide with ethynylpyridine in the presence of a Cu(I) catalyst. L has been employed in the preparation of lanthanide coordination compounds having formulae [Ln(κ2-NO3)3L2] and [Eu(dbm)3L] (Ln = Eu, Tb; dbm = dibenzoylmethanate). The molecular structure of [Eu(dbm)3L] has been determined by X-ray diffraction studies. All the new complexes exhibit good photoluminescence properties and [Eu(dbm)3L] has been successfully used as the dopant for the preparation of luminescent plastic materials.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2018. Vol. 42, no 13, p. 11064-11072
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Experimental Physics
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URN: urn:nbn:se:ltu:diva-69503DOI: 10.1039/C8NJ01390JISI: 000436517300073Scopus ID: 2-s2.0-85049158841OAI: oai:DiVA.org:ltu-69503DiVA, id: diva2:1218223
Note

Validerad;2018;Nivå 2;2018-06-27 (svasva)

Available from: 2018-06-14 Created: 2018-06-14 Last updated: 2018-08-20Bibliographically approved

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Enrichi, FrancescoMazzaro, RaffaelloVomiero, Alberto

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