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Luminescent copper(I) coordination polymer with 1-methyl-1H-benzotriazole, iodide and acetonitrile as ligands
Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari Venezia, Mestre, VE, Italy;Consorzio Interuniversitario Reattività Chimica e Catalisi (CIRCC), Bari, Italy.
Departamento de Química Inorgánica, Universidade de Vigo, Facultade de Química, Edificio de Ciencias Experimentais, Galicia, Spain.
Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari Venezia, Mestre, VE, Italy.
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Material Science. Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari Venezia, Mestre, VE, Italy.ORCID iD: 0000-0002-3443-3707
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2019 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 102, p. 141-146Article in journal (Refereed) Published
Abstract [en]

The Cu(I) coordination polymer [Cu33-I)3(μ-btzMe)(NCCH3)]n (btzMe = 1-methyl-1H-benzotriazole) was prepared and characterized by X-Ray diffraction. The compound showed strong green emission upon excitation with wavelengths below 475 nm, with lifetime of 47 μs. The emission was attributed to 3(X,M)LCT transition on the basis of experimental data and DFT calculations.

Place, publisher, year, edition, pages
Elsevier, 2019. Vol. 102, p. 141-146
Keywords [en]
Copper iodide, Coordination polymer, N-donor ligands, Luminescence
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Experimental Physics
Identifiers
URN: urn:nbn:se:ltu:diva-73034DOI: 10.1016/j.inoche.2019.02.016ISI: 000462803900027Scopus ID: 2-s2.0-85061636648OAI: oai:DiVA.org:ltu-73034DiVA, id: diva2:1292122
Note

Validerad;2019;Nivå 2;2019-08-19 (johcin)

Available from: 2019-02-27 Created: 2019-02-27 Last updated: 2019-08-19Bibliographically approved

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Enrichi, FrancescoVomiero, Alberto

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