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Chemisorption Activity of Mercury(II) Cyclopentamethylenedithiocarbamate: Synthesis, Structure, and Thermal Behavior of the [Hg2{S2CN(CH2)5}4] and [Au3{S2CN(CH2)5}6][Au{S2CN(CH2)5}2][Hg2Cl6]2 Complexes
Institute of Geology and Nature Management, Far-East Branch, Russian Academy of Sciences, Blagoveshchensk, Russia.
Amur State University, Blagoveshchensk, Russia.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering. University of Warwick, Coventry, United Kingdom.ORCID iD: 0000-0003-1067-7990
Institute of Geology and Nature Management, Far-East Branch, Russian Academy of Sciences, Blagoveshchensk, Russia.
2018 (English)In: Russian journal of general chemistry, ISSN 1070-3632, E-ISSN 1608-3350, Vol. 88, no 12, p. 2540-2549Article in journal (Refereed) Published
Abstract [en]

The dinuclear complex mercury(II) cyclopentamethylenedithiocarbamate (piperidine-1-carbodithioate) [Hg2{S2CN(CH2)5}4] was synthesized and its chemisorption activity toward a solution of AuCl3 in 2 M HCl was studied. The chemisorption of gold from the solution forms an ionic gold(III)‒mercury(II) dithiocarbamato-chlorido complex comprising three isomeric gold cations and an unsymmetrical hexachlorodimercurate anion. The structural organization and thermal behavior of the resulting compounds was studied.

Place, publisher, year, edition, pages
Springer, 2018. Vol. 88, no 12, p. 2540-2549
Keywords [en]
mercury(II) alkylenedithiocarbamates, chemisorption activity, gold(III)‒mercury(II) double complexes, secondary Au···S bonds
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-73595DOI: 10.1134/S1070363218120149ISI: 000462933000014Scopus ID: 2-s2.0-85063604736OAI: oai:DiVA.org:ltu-73595DiVA, id: diva2:1304178
Note

Validerad;2019;Nivå 2;2019-04-11 (johcin)

Available from: 2019-04-11 Created: 2019-04-11 Last updated: 2019-04-17Bibliographically approved

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Antzutkin, Oleg

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