Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n
Institute of Geology and Nature Management, Far-Eastern Branch of the Russian Academy of Sciences, Blagoveschensk, Russian Federation.
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation. Novosibirsk State University, Novosibirsk, Russian Federation.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering. University of Warwick, Coventry, United Kingdom.ORCID iD: 0000-0003-1067-7990
Institute of Geology and Nature Management, Far-Eastern Branch of the Russian Academy of Sciences, Blagoveschensk, Russian Federation.
2019 (English)In: Russian chemical bulletin, ISSN 1066-5285, E-ISSN 1573-9171, Vol. 68, no 1, p. 40-47Article in journal (Refereed) Published
Abstract [en]

The double ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S2CNPr2)2]+ (A and B) and the discrete linear anion [AgCl2]. Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl2] anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl2] anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.

Place, publisher, year, edition, pages
Springer, 2019. Vol. 68, no 1, p. 40-47
Keywords [en]
dialkyldithiocarbamates, binary complexes, noble metals, gold silver compounds, supramolecular self-assembly, secondary interactions, 13C MAS NMR spectroscopy, thermal behavior
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-73818DOI: 10.1007/s11172-019-2413-7ISI: 000464854400006Scopus ID: 2-s2.0-85064434277OAI: oai:DiVA.org:ltu-73818DiVA, id: diva2:1313199
Note

Validerad;2019;Nivå 2;2019-05-02 (johcin)

Available from: 2019-05-02 Created: 2019-05-02 Last updated: 2019-05-02Bibliographically approved

Open Access in DiVA

No full text in DiVA

Other links

Publisher's full textScopus

Authority records BETA

Antzutkin, Oleg

Search in DiVA

By author/editor
Antzutkin, Oleg
By organisation
Chemical Engineering
In the same journal
Russian chemical bulletin
Physical Chemistry

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 15 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf