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Prevention of sulfide oxidation in sulfide-rich waste rock
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.ORCID iD: 0000-0001-5101-9156
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.ORCID iD: 0000-0001-7291-8505
2015 (English)In: EGU General Assembly 2015, Copernicus Publications , 2015, article id EGU2015-13768Conference paper, Oral presentation with published abstract (Other academic)
Abstract [en]

The ability to reduce sulfide oxidation in waste rock after mine closure is a widely researched area, but to reduce and/or inhibit the oxidation during operation is less common. Sulfide-rich (ca 30 % sulfur) waste rock, partially oxidized, was leached during unsaturated laboratory condition. Trace elements such as As and Sb were relatively high in the waste rock while other sulfide-associated elements such as Cu, Pb and Zn were low compared to common sulfide-rich waste rock. Leaching of unsaturated waste rock lowered the pH, from around six down to two, resulting in continuously increasing element concentrations during the leaching period of 272 days. The concentrations of As (65 mg/L), Cu (6.9 mg/L), Sb (1.2 mg/L), Zn (149 mg/L) and S (43 g/L) were strongly elevated at the end of the leaching period. Different alkaline industrial residues such as slag, lime kiln dust and cement kiln dust were added as solid or as liquid to the waste rock in an attempt to inhibit sulfide oxidation through neo-formed phases on sulfide surfaces in order to decrease the mobility of metals and metalloids over longer time scale. This will result in a lower cost and efforts of measures after mine closure. Results from the experiments will be presented.

Place, publisher, year, edition, pages
Copernicus Publications , 2015. article id EGU2015-13768
Series
Geophysical Research Abstracts, E-ISSN 1607-7962 ; 17
National Category
Geochemistry
Research subject
Applied Geochemistry
Identifiers
URN: urn:nbn:se:ltu:diva-74344OAI: oai:DiVA.org:ltu-74344DiVA, id: diva2:1322611
Conference
European Geosciences Union General Assembly 2015, 12-17 April, 2015, Vienna, Austria
Available from: 2019-06-11 Created: 2019-06-11 Last updated: 2020-09-16Bibliographically approved

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https://meetingorganizer.copernicus.org/EGU2015/EGU2015-13768-1.pdf

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Nyström, ElsaAlakangas, Lena

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