The use of wollastonite as a natural additive for the welding of Scots pine improved the water resistance and shear strength of the welded joint. The X-ray computed tomography images revealed that the welding of Scots pine with wollastonite could postpone crack formation in the welded joints. The specimens welded for a longer time (5 s) had a more uniform distribution of wollastonite particles in welded joints. The microstructure of the wood and the thickness of the wood cell walls also had a great influence on the thickness and strength of the welded joints. Water immersion tests showed that the use of wollastonite in wood joints was able to meet the requirement of resistance to frequent short-term and long-term exposure to water.