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Demonstrating Fuel Design To Reduce Particulate Emissions and Control Slagging in Industrial-Scale Grate Combustion of Woody Biomass
Thermochemical Energy Conversion Laboratory, Department of Applied Physics and Electronics, Umeå University, Sweden.
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Energy Science.ORCID iD: 0000-0001-5801-3590
Thermochemical Energy Conversion Laboratory, Department of Applied Physics and Electronics, Umeå University, Sweden.
Thermochemical Energy Conversion Laboratory, Department of Applied Physics and Electronics, Umeå University, Sweden.
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2020 (English)In: Energy & Fuels, ISSN 0887-0624, E-ISSN 1520-5029, Vol. 34, no 2, p. 2574-2583Article in journal (Refereed) Published
Abstract [en]

The demand for increased overall efficiency, improved fuel flexibility, and more stringent environmental legislations promotes the development of new fuel- and technology-related concepts for the bioenergy sector. Previous research has shown that careful consideration of the fuel ash composition and the adjustment of the same via various routes, i.e., fuel design, have the potential to alter the ash transformation reactions, leading to, e.g., a reduction of the formation of slag or entrained inorganic ash particles. The objective of the present work was, therefore, to demonstrate the use of fuel design as a primary measure to reduce the emission of PM1 during combustion of woody biomass in medium-scale grate-fired boilers while keeping the slag formation at a manageable level. This was achieved by designing fuel blends of woody biomass with carefully selected Scandinavian peats rich in Si, Ca, and S. The work includes results from three experimental campaigns, performed in three separate grate-fired boilers of different sizes, specifically 0.2 MWth, 2 MWth, and 4 MWth. In one of the campaigns, softwood-based stemwood pellets were copelletized with different additions of peat (5 and 15 wt %) before combustion. In the other campaigns, peat was added in a separate fuel feed to Salix chips (15 wt % peat) and softwood-based stemwood pellets (10 and 20 wt % peat). Particulate matter and bottom ashes were characterized by scanning electron microscopy–energy-dispersive X-ray spectroscopy for morphology and elemental composition as well as by powder X-ray diffraction for crystalline phase composition. The results show that the fuel design approach provided PM1 reduction for all fuel blends between 30 and 50%. The PM1 reduction could be achieved without causing operational problems due to slagging for any of the three commercial boilers used, although an expected increased slagging tendency was observed. Overall, this paper illustrates that fuel design can be implemented on an industrial scale by achieving the desired ash transformation reactions, in this case, leading to a reduction of fine particulate emissions by up to 50% without any operational disturbances due to slag formation on the grate.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2020. Vol. 34, no 2, p. 2574-2583
National Category
Energy Engineering
Research subject
Energy Engineering
Identifiers
URN: urn:nbn:se:ltu:diva-78113DOI: 10.1021/acs.energyfuels.9b03935ISI: 000518215400147Scopus ID: 2-s2.0-85080925129OAI: oai:DiVA.org:ltu-78113DiVA, id: diva2:1415867
Note

Validerad;2020;Nivå 2;2020-03-20 (alebob)

Available from: 2020-03-20 Created: 2020-03-20 Last updated: 2023-09-05Bibliographically approved
In thesis
1. Implication of pellet quality on combustion performance
Open this publication in new window or tab >>Implication of pellet quality on combustion performance
2021 (English)Licentiate thesis, comprehensive summary (Other academic)
Abstract [en]

Quality aspects of wood pellets and their use have been of utmost importance since the development of the pellet market in the early 1980s. Research and hard-earned knowledge have resulted in advancements in the field, but there are still uncertainties in the pellet industry about how different quality aspects affect combustion performance. The focus of this work has been on pellet quality, with investigations divided into three main topics: 1) the effect of physical properties of pellets on their combustion properties, 2) the effect on particle emissions due to manipulation of the ash chemistry by means of additives and, 3) how radio frequency identification (RFID) technology can be used to achieve traceability of bulk pellets.In the literature it is not clear how physical pellet quality parameters affect the combustion behavior. To gain knowledge regarding the perception of pellet quality in practice, interviews with pellet industry representatives were made initially. This was followed by detailed combustion experiments to investigate how the key quality parameters moisture content, density, and durability affect the ignition behavior and the conversion time. A large number of well-defined pellet samples produced from four different raw material mixes were used. The results showed that during stable combustion conditions, i.e., high temperature and sufficient air supply in a fully functioning combustion system, these parameters have little practical influence on the combustion performance. However, the results from the detailed laboratory experiments indicated that the choice of raw material can have a more profound effect on both ignition behavior and conversion rates, although the full-scale tests indicated that this was of little practical importance. Fuel design, i.e. choosing fuels or making adjustments to the fuel based on ash composition, can be used to lower particle emissions. This concept was demonstrated during combustion tests that were performed in three individual campaigns in medium scale boilers, 0.2 MWth, 2 MWth and 4 MWth respectively. In the campaigns, peat was utilized to alter the ash transformation reactions, reducing the emission of particulate matter less than 1 micron (PM1) during combustion of woody biomass, while keeping the slag formation at a manageable level. This was achieved by designing fuel blends of woody biomass with carefully selected Scandinavian peats rich in Si, Ca, and S. In one of the campaigns, softwood-based stemwood pellets were co-pelletized with different additions of peat (5 and 15 wt %) before combustion. In the other campaigns, peat was added as a separate fuel feed to Salix chips (15 wt % peat) and softwood-based stemwood pellets (10 and 20 wt % peat). The results showed that, no matter how peat was added to the fuel, the fuel design approach provided PM1 reductions of between 30 - 50 % for all fuel blends. The PM1 reduction could be achieved without causing operational problems due to slagging in any of the three commercial boilers used, although an expected increased slagging tendency was observed. RFID systems are used today for the tracking of well-defined entities; i.e. the RFID tag is linked to an object - a container, a person etc. While RFID technology has been used in this way in the energy sector to monitor biofuel transport to and from transshipment sites and energy plants, it is not known to have been used for tracing bulk biofuels, i.e. a fuel that cannot be seen as a stand-alone entity. To demonstrate the potential of using RFID technology to trace bulk fuel transportation, three tests were performed. RFID tags were placed together with biomass pellets before being conveyed through a distribution chain, from pellet producer to combustion plant. The two first tests were large-scale trials to investigate if specific RFID tags could be correlated to a specific fuel when fed into the furnace. The third test was performed to see how RFID tags distributed over time in a logistics chain. The results showed that it is possible to trace a bulk biofuel flow using RFID technology, from production site to furnace, although care must be taken to optimize the method, such as using an appropriate number of tags. 

Place, publisher, year, edition, pages
Luleå University of Technology, 2021. p. 52
National Category
Energy Engineering
Research subject
Energy Engineering
Identifiers
urn:nbn:se:ltu:diva-83989 (URN)978-91-7790-920-0 (ISBN)978-91-7790-921-7 (ISBN)
Presentation
2021-11-18, E632, Luleå, 10:00 (English)
Opponent
Supervisors
Available from: 2021-05-04 Created: 2021-05-03 Last updated: 2023-09-05Bibliographically approved

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Sundberg, PeterTullin, ClaesÖhman, Marcus

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