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Sub‐Permil Interlaboratory Consistency for Solution‐Based Boron Isotope Analyses on Marine Carbonates
GEOMAR Helmholtz Centre for Ocean Research Kiel, Wischhofstrasse 1‐3, 24148 Kiel, Germany.
Laboratoire des Sciences du Climat et de l’Environnement, LSCE/IPSL, CEA‐CNRS‐UVSQ, Université Paris‐Saclay, F‐91191 Gif‐sur‐Yvette, France.
Laboratoire des Sciences du Climat et de l’Environnement, LSCE/IPSL, CEA‐CNRS‐UVSQ, Université Paris‐Saclay, F‐91191 Gif‐sur‐Yvette, France.
Department of Earth and Environmental Sciences and Lamont‐Doherty Earth Observatory, Columbia University, 61 Route 9W Palisades, NY, 10964 USA; Princeton University, Department of Geosciences, Guyot Hall, Princeton, NJ, 08544, USA.
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2021 (English)In: Geostandards and Geoanalytical Research, ISSN 1639-4488, E-ISSN 1751-908X, Vol. 45, no 1, p. 59-75Article in journal (Refereed) Published
Abstract [en]

Boron isotopes in marine carbonates are increasingly used to reconstruct seawater pH and atmospheric pCO2 through Earth’s history. While isotope ratio measurements from individual laboratories are often of high quality, it is important that records generated in different laboratories can equally be compared. Within this Boron Isotope Intercomparison Project (BIIP), we characterised the boron isotopic composition (commonly expressed in δ11B) of two marine carbonates: Geological Survey of Japan carbonate reference materials JCp‐1 (coral Porites) and JCt‐1 (giant clam Tridacna gigas). Our study has three foci: (i) to assess the extent to which oxidative pre‐treatment, aimed at removing organic material from carbonate, can influence the resulting δ11B; (ii) to determine to what degree the chosen analytical approach may affect the resultant δ11B, and (iii) to provide well‐constrained consensus δ11B values for JCp‐1 and JCt‐1. The resultant robust mean and associated robust standard deviation (s*) for un‐oxidised JCp‐1 is 24.36 ± 0.45‰ (2s*), compared with 24.25 ± 0.22‰ (2s*) for the same oxidised material. For un‐oxidised JCt‐1, respective compositions are 16.39 ± 0.60‰ (2s*; un‐oxidised) and 16.24 ± 0.38‰ (2s*; oxidised). The consistency between laboratories is generally better if carbonate powders were oxidatively cleaned prior to purification and measurement.

Place, publisher, year, edition, pages
John Wiley & Sons, 2021. Vol. 45, no 1, p. 59-75
Keywords [en]
mass spectrometry, Geological Survey of Japan, boron isotopes, carbonate reference materials, interlaboratory experiment
National Category
Geochemistry
Research subject
Applied Geochemistry
Identifiers
URN: urn:nbn:se:ltu:diva-81093DOI: 10.1111/ggr.12364ISI: 000588330800001Scopus ID: 2-s2.0-85096712169OAI: oai:DiVA.org:ltu-81093DiVA, id: diva2:1475004
Funder
EU, Horizon 2020, 805246NERC - the Natural Environment Research Council, NE/N011716/1
Note

Validerad;2021;Nivå 2;2021-03-15 (alebob)

Available from: 2020-10-12 Created: 2020-10-12 Last updated: 2023-10-28Bibliographically approved

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Rodushkin, Ilia

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