Sub‐Permil Interlaboratory Consistency for Solution‐Based Boron Isotope Analyses on Marine CarbonatesSchool of Ocean and Earth Science, University of Southampton, National Oceanography Centre, Southampton, European Way, Southampton, SO14 3ZH, UK.
GEOMAR Helmholtz Centre for Ocean Research Kiel, Wischhofstrasse 1‐3, 24148 Kiel, Germany.
Department of Earth and Environmental Sciences and Lamont‐Doherty Earth Observatory, Columbia University, 61 Route 9W Palisades, NY, 10964, USA.
Laboratoire d'Hydrologie et de Géochimie de Strasbourg, EOST, Université de Strasbourg et CNRS, 1 rue Blessig, 67084 Strasbourg, France.
Institut de Physique du Globe de Paris, Sorbonne Paris Cité, Université Paris‐Diderot, UMR CNRS 7154, 1 rue Jussieu, 75238 Paris, Cedex, France.
ARC Centre of Excellence for Coral Reef Studies, School of Earth and Environment, The University of Western Australia, Crawley, 6009 Australia.
Institut de Physique du Globe de Paris, Sorbonne Paris Cité, Université Paris‐Diderot, UMR CNRS 7154, 1 rue Jussieu, 75238 Paris, Cedex, France.
ALS Scandinavia AB, Aurorum 10, SE‐97775 Luleå, Sweden.
Geological and Planetary Sciences, Caltech, 1200 E California Blvd, Pasadena, California, 91125, USA; School of Earth and Environmental Sciences, University of St Andrews, North Street, St Andrews, UK.
Laboratoire d'Hydrologie et de Géochimie de Strasbourg, EOST, Université de Strasbourg et CNRS, 1 rue Blessig, 67084 Strasbourg, France; Biogéochimie des Ecosystèmes Forestiers, INRA, 54280 Champenoux, France.
School of Ocean and Earth Science, University of Southampton, National Oceanography Centre, Southampton, European Way, Southampton, SO14 3ZH UK; School of Earth Sciences, University of Bristol, Queens Road, Bristol, BS8 1RJ, UK.
Laboratoire des Sciences du Climat et de l’Environnement, LSCE/IPSL, CEA‐CNRS‐UVSQ, Université Paris‐Saclay, F‐91191 Gif‐sur‐Yvette, France.
Isotope Geochemistry Laboratory, Department of Earth Sciences, National Cheng Kung University, No 1 University Road, 701 Tainan, Taiwan.
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2021 (English)In: Geostandards and Geoanalytical Research, ISSN 1639-4488, E-ISSN 1751-908X, Vol. 45, no 1, p. 59-75Article in journal (Refereed) Published
Abstract [en]
Boron isotopes in marine carbonates are increasingly used to reconstruct seawater pH and atmospheric pCO2 through Earth’s history. While isotope ratio measurements from individual laboratories are often of high quality, it is important that records generated in different laboratories can equally be compared. Within this Boron Isotope Intercomparison Project (BIIP), we characterised the boron isotopic composition (commonly expressed in δ11B) of two marine carbonates: Geological Survey of Japan carbonate reference materials JCp‐1 (coral Porites) and JCt‐1 (giant clam Tridacna gigas). Our study has three foci: (i) to assess the extent to which oxidative pre‐treatment, aimed at removing organic material from carbonate, can influence the resulting δ11B; (ii) to determine to what degree the chosen analytical approach may affect the resultant δ11B, and (iii) to provide well‐constrained consensus δ11B values for JCp‐1 and JCt‐1. The resultant robust mean and associated robust standard deviation (s*) for un‐oxidised JCp‐1 is 24.36 ± 0.45‰ (2s*), compared with 24.25 ± 0.22‰ (2s*) for the same oxidised material. For un‐oxidised JCt‐1, respective compositions are 16.39 ± 0.60‰ (2s*; un‐oxidised) and 16.24 ± 0.38‰ (2s*; oxidised). The consistency between laboratories is generally better if carbonate powders were oxidatively cleaned prior to purification and measurement.
Place, publisher, year, edition, pages
John Wiley & Sons, 2021. Vol. 45, no 1, p. 59-75
Keywords [en]
mass spectrometry, Geological Survey of Japan, boron isotopes, carbonate reference materials, interlaboratory experiment
National Category
Geochemistry
Research subject
Applied Geochemistry
Identifiers
URN: urn:nbn:se:ltu:diva-81093DOI: 10.1111/ggr.12364ISI: 000588330800001Scopus ID: 2-s2.0-85096712169OAI: oai:DiVA.org:ltu-81093DiVA, id: diva2:1475004
Funder
EU, Horizon 2020, 805246NERC - the Natural Environment Research Council, NE/N011716/1
Note
Validerad;2021;Nivå 2;2021-03-15 (alebob)
2020-10-122020-10-122023-10-28Bibliographically approved