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Ionic Liquids/Deep Eutectic Solvents-Based Hybrid Solvents for CO2 Capture
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Energy Science. Swerim AB, Box 812, SE-97125 Luleå, Sweden.ORCID iD: 0000-0003-1394-7925
State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.
CAS Key Laboratory of Green Process and Engineering, Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China. School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China .
Luleå University of Technology, Department of Engineering Sciences and Mathematics, Energy Science.ORCID iD: 0000-0002-0200-9960
2020 (English)In: Crystals, ISSN 2073-4352, Vol. 10, no 11, article id 978Article, review/survey (Refereed) Published
Abstract [en]

The CO2 solubilities (including CO2 Henry’s constants) and viscosities in ionic liquids (ILs)/deep eutectic solvents (DESs)-based hybrid solvents were comprehensively collected and summarized. The literature survey results of CO2 solubility illustrated that the addition of hybrid solvents to ILs/DESs can significantly enhance the CO2 solubility, and some of the ILs-based hybrid solvents are super to DESs-based hybrid solvents. The best hybrid solvents of IL–H2O, IL–organic, IL–amine, DES–H2O, and DES–organic are [DMAPAH][Formate] (2.5:1) + H2O (20 wt %) (4.61 mol/kg, 298 K, 0.1 MPa), [P4444][Pro] + PEG400 (70 wt %) (1.61 mol/kg, 333.15 K, 1.68 MPa), [DMAPAH][Formate] (2.0:1) + MEA (30 wt %) (6.24 mol/kg, 298 K, 0.1 MPa), [TEMA][Cl]-GLY-H2O 1:2:0.11 (0.66 mol/kg, 298 K, 1.74 MPa), and [Ch][Cl]-MEA 1:2 + DBN 1:1 (5.11 mol/kg, 298 K, 0.1 MPa), respectively. All of these best candidates show higher CO2 solubility than their used pure ILs or DESs, evidencing that IL/DES-based hybrid solvents are remarkable for CO2 capture. For the summarized viscosity results, the presence of hybrid solvents in ILs and DESs can decrease their viscosities. The lowest viscosities acquired in this work for IL–H2O, IL–amine, DES–H2O, and DES–organic hybrid solvents are [DEA][Bu] + H2O (98.78 mol%) (0.59 mPa·s, 343.15 K), [BMIM][BF4] + DETA (94.9 mol%) (2.68 mPa·s, 333.15 K), [L-Arg]-GLY 1:6 + H2O (60 wt %) (2.7 mPa·s, 353.15 K), and [MTPP][Br]-LEV-Ac 1:3:0.03 (16.16 mPa·s, 333.15 K) at 0.1 MPa, respectively.

Place, publisher, year, edition, pages
MDPI, 2020. Vol. 10, no 11, article id 978
Keywords [en]
ionic liquid, deep eutectic solvents, hybrid solvent, CO2 solubility, Henry’s constant, viscosity
National Category
Energy Engineering
Research subject
Energy Engineering
Identifiers
URN: urn:nbn:se:ltu:diva-81282DOI: 10.3390/cryst10110978ISI: 000593670800001Scopus ID: 2-s2.0-85094625791OAI: oai:DiVA.org:ltu-81282DiVA, id: diva2:1485245
Note

Validerad;2021;Nivå 2;2021-01-01 (johcin)

Available from: 2020-11-01 Created: 2020-11-01 Last updated: 2021-03-23Bibliographically approved

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Liu, YanrongJi, Xiaoyan

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