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Effect of rotating magnetic field on the diffusivity of ethylammonium nitrate ionic liquid confined between micrometer-spaced glass plates
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering. Kazan State Medical University, 420012 Kazan, Russia.ORCID iD: 0000-0002-6810-1882
Kazan State Medical University, 420012 Kazan, Russia.
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Chemical Engineering. Department of Physics, Warwick University, Coventry CV4 7AL, UK.ORCID iD: 0000-0003-1067-7990
Kazan National Research Technological University, 420015 Kazan, Russia.
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2021 (English)In: Journal of Molecular Liquids, ISSN 0167-7322, E-ISSN 1873-3166, Vol. 323, article id 115008Article in journal (Refereed) Published
Abstract [en]

We studied changes in the diffusion coefficients in layers of EAN confined between glass plates, placed in a strong magnetic field with a magnetic flux density B0, and rotated around the axis directed along and normal to B0. Under the rotational conditions along B0, the diffusion coefficient decreases with time after placement in the magnetic field at the same rate as for a static sample, observed previously (Filippov and Antzutkin, Phys. Chem. Chem. Phys. 2018. 20. 6316). However, when the EAN layers are rotating around the axis perpendicular to B0, the duration of exposure to the magnetic field does not affect the diffusion coefficient until the rotation stops. On the other hand, the diffusivity after extended exposure to a static magnetic field increases as the sample starts to rotate around the axis perpendicular to B0. The observed effects are due to either the periodic change in the orientation of the thin surface layers of EAN or inhomogeneity of B0 in the sample due to the B0 fluctuation.

Place, publisher, year, edition, pages
Elsevier, 2021. Vol. 323, article id 115008
Keywords [en]
Diffusion, Ion dynamics, Phase transformations, Rotating magnetic field, Magnetic field inhomogeneity
National Category
Physical Chemistry
Research subject
Chemistry of Interfaces
Identifiers
URN: urn:nbn:se:ltu:diva-82313DOI: 10.1016/j.molliq.2020.115008ISI: 000610844800087Scopus ID: 2-s2.0-85098714927OAI: oai:DiVA.org:ltu-82313DiVA, id: diva2:1516561
Funder
The Kempe FoundationsLuleå University of TechnologySwedish Foundation for Strategic Research , EM16-003, 2019-2023
Note

Validerad;2021;Nivå 2;2021-01-12 (alebob);

Finansiär: Kazan Federal University (0671-2020-0051)

Available from: 2021-01-12 Created: 2021-01-12 Last updated: 2023-09-05Bibliographically approved

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Filippov, AndreiAntzutkin, Oleg N.

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