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A window–space-directed assembly strategy for the construction of supertetrahedron-based zeolitic mesoporous metal–organic frameworks with ultramicroporous apertures for selective gas adsorption
College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China; Department of Chemistry, University of North Texas, Denton 76201, United States; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China.
College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China.
College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China.
College of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350118, China; Collaborative Innovation Center for Intelligent and Green Mold and Die of Fujian Province, Fuzhou 350118, China.
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2021 (English)In: Chemical Science, ISSN 2041-6520, E-ISSN 2041-6539, Vol. 12, no 16, p. 5767-5773Article in journal (Refereed) Published
Abstract [en]

Despite their scarcity due to synthetic challenges, supertetrahedron-based metal–organic frameworks (MOFs) possess intriguing architectures, diverse functionalities, and superb properties that make them in‑demand materials. Employing a new window–space-directed assembly strategy, a family of mesoporous zeolitic MOFs have been constructed herein from corner-shared supertetrahedra based on homometallic or heterometallic trimers [M3(OH/O)(COO)6] (M3 = Co3, Ni3 or Co2Ti). These MOFs consisted of close-packed truncated octahedral cages possessing a sodalite topology and large β-cavity mesoporous cages (~22 Å diameter) connected by ultramicroporous apertures (~5.6 Å diameter). Notably, the supertetrahedron-based sodalite topology MOF composed with the Co2Ti trimer exhibited high thermal and chemical stability as well as the ability to efficiently separate acetylene (C2H2) from carbon dioxide (CO2).
Place, publisher, year, edition, pages
Royal Society of Chemistry, 2021. Vol. 12, no 16, p. 5767-5773
National Category
Energy Engineering
Research subject
Energy Engineering
Identifiers
URN: urn:nbn:se:ltu:diva-83186DOI: 10.1039/D0SC06841AISI: 000644990400022PubMedID: 33936581Scopus ID: 2-s2.0-85105122430OAI: oai:DiVA.org:ltu-83186DiVA, id: diva2:1534951
Funder
Carl Tryggers foundation
Note

Validerad;2021;Nivå 2;2021-05-11 (alebob);

Finansiär: Key Research Program of Frontier Science, CAS (QYZDJ-SSW-SLH033); National Natural Science Foundation of China (21521061, 21701024, 21875252,51401053); Central Government Research Program to Guide the Local Scientific and Technological Development (2018L3001); Natural Science Foundation of Fujian Province (2018J05075, 2018J01629, 2018I0001); Foundation for Distinguished Young Talents in Higher Education of Fujian Province (GY-Z17067); Projects from CAS Key Laboratory of Design and Assembly of Functional Nanostructures (2013DP173231); Scientific Research Foundation of Fujian University of Technology(GY-Z18175, GY-Z17001, GY-Z17152); China Scholarship Council (CSC, 201909360002); Researchers Supporting Program at King Saud University, Riyadh, Saudi Arabia (RSP-2021/79); Robert A.Welch Foundation (B-0027)

Available from: 2021-03-06 Created: 2021-03-06 Last updated: 2021-05-28Bibliographically approved

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Liu, Yanrong

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