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Advanced opportunities and insights on the influence of nitrogen incorporation on the physico-/electro-chemical properties of robust electrocatalysts for electrocatalytic energy conversion
Guangxi Key Laboratory of Electrochemical and Magneto-chemical, Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, PR China; College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, PR China.
College of Julong, Shenzhen Technology University, Shenzhen Guangdong 518118, PR China.
Key Laboratory of Optoelectronic Devices, Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China.
Key Laboratory of Optoelectronic Devices, Systems of Ministry of Education and Guangdong Province, College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, China.
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2021 (English)In: Coordination chemistry reviews, ISSN 0010-8545, E-ISSN 1873-3840, Vol. 449, article id 214209Article, review/survey (Refereed) Published
Abstract [en]

The use of a wide range of methods for incorporating nitrogen atoms on robust catalysts has given rise to fundamental advances in the field of energy conversion and storage. Recently, nitrogen incorporation has proven to be able to fine-tune the electron densities of exposed active sites to create high-performance electrocatalysts. The preservation of a strong interface between the local atomic coordination of nitrogen atoms on bare carbon, single metal atoms, transition metal oxides, metal chalcogenides, and MXenes during synthesis plays an important role in producing an efficient electrocatalysts. In addition, the ability of nitrogen atoms to bind with carbon or metal atoms can be influenced by processing conditions. In this regard, this review is the first comprehensive overview of the range of synthetic strategies to form nitrogen incorporated catalysts and assess their chemical, structural, physical electronic property modification and their influence on electrocatalytic ORR, OER, and HER performance. This review will describe how specific strategies have been utilized to realise effective electrocatalytic systems, including the energy conversion of nitrogen incorporated catalysts, structural coordination, and material optimization. Finally, the main challenges to be considered in future investigations in order to initiate new research efforts in this promising research area are discussed.

Place, publisher, year, edition, pages
Elsevier, 2021. Vol. 449, article id 214209
Keywords [en]
Nitrogen, N-doped carbon, Single-atom sites, N-doped metal oxides, N-doped metal chalcogenides, N-doped MXenes, ORR, OER, and HER
National Category
Materials Chemistry
Research subject
Machine Elements
Identifiers
URN: urn:nbn:se:ltu:diva-87102DOI: 10.1016/j.ccr.2021.214209ISI: 000698604800014Scopus ID: 2-s2.0-85115000176OAI: oai:DiVA.org:ltu-87102DiVA, id: diva2:1594916
Note

Validerad;2021;Nivå 2;2021-09-16 (alebob);

Forskningsfinansiär: Scientific Research Start-Up Project Program of Guilin University of Technology (RD2000002183)

Available from: 2021-09-16 Created: 2021-09-16 Last updated: 2023-09-05Bibliographically approved

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Namachivayam, Karthik

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