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Experimental Investigation of the Atmosphere-Regolith Water Cycle on Present-Day Mars
Luleå University of Technology, Department of Computer Science, Electrical and Space Engineering, Space Technology.ORCID iD: 0000-0003-0499-6370
Luleå University of Technology, Department of Computer Science, Electrical and Space Engineering, Space Technology. Centro de Astrobiología (CSIC-INTA), Torrejón de Ardoz, 28850 Madrid, Spain; School of Geosciences, University of Aberdeen, Aberdeen AB24 3FX, UK .ORCID iD: 0000-0002-4492-9650
Luleå University of Technology, Department of Computer Science, Electrical and Space Engineering, Space Technology. Centro de Astrobiología (CSIC-INTA), Torrejón de Ardoz, 28850 Madrid, Spain; School of Geosciences, University of Aberdeen, Aberdeen AB24 3FX, UK .ORCID iD: 0000-0001-6479-2236
2021 (English)In: Sensors, E-ISSN 1424-8220, Vol. 21, no 21, article id 7421Article in journal (Refereed) Published
Abstract [en]

The water content of the upper layers of the surface of Mars is not yet quantified. Laboratory simulations are the only feasible way to investigate this in a controlled way on Earth, and then compare it with remote and in situ observations of spacecrafts on Mars. Describing the processes that may induce changes in the water content of the surface is critical to determine the present-day habitability of the Martian surface, to understand the atmospheric water cycle, and to estimate the efficiency of future water extraction procedures from the regolith for In Situ Resource Utilization (ISRU). This paper illustrates the application of the SpaceQ facility to simulate the near-surface water cycle under Martian conditions. Rover Environmental Monitoring Station (REMS) observations at Gale crater show a non-equilibrium situation in the atmospheric H2O volume mixing ratio (VMR) at night-time, and there is a decrease in the atmospheric water content by up to 15 g/m2 within a few hours. This reduction suggests that the ground may act at night as a cold sink scavenging atmospheric water. Here, we use an experimental approach to investigate the thermodynamic and kinetics of water exchange between the atmosphere, a non-porous surface (LN2-chilled metal), various salts, Martian regolith simulant, and mixtures of salts and simulant within an environment which is close to saturation. We have conducted three experiments: the stability of pure liquid water around the vicinity of the triple point is studied in experiment 1, as well as observing the interchange of water between the atmosphere and the salts when the surface is saturated; in experiment 2, the salts were mixed with Mojave Martian Simulant (MMS) to observe changes in the texture of the regolith caused by the interaction with hydrates and liquid brines, and to quantify the potential of the Martian regolith to absorb and retain water; and experiment 3 investigates the evaporation of pure liquid water away from the triple point temperature when both the air and ground are at the same temperature and the relative humidity is near saturation. We show experimentally that frost can form spontaneously on a surface when saturation is reached and that, when the temperature is above 273.15 K (0 °C), this frost can transform into liquid water, which can persist for up to 3.5 to 4.5 h at Martian surface conditions. For comparison, we study the behavior of certain deliquescent salts that exist on the Martian surface, which can increase their mass between 32% and 85% by absorption of atmospheric water within a few hours. A mixture of these salts in a 10% concentration with simulant produces an aggregated granular structure with a water gain of approximately 18- to 50-wt%. Up to 53% of the atmospheric water was captured by the simulated ground, as pure liquid water, hydrate, or brine.

Place, publisher, year, edition, pages
MDPI, 2021. Vol. 21, no 21, article id 7421
Keywords [en]
Mars, pure liquid water, water cycle simulation, habitability, planetary protection, ISRU
National Category
Aerospace Engineering
Research subject
Atmospheric science
Identifiers
URN: urn:nbn:se:ltu:diva-87851DOI: 10.3390/s21217421ISI: 000718981700001PubMedID: 34770727Scopus ID: 2-s2.0-85118511551OAI: oai:DiVA.org:ltu-87851DiVA, id: diva2:1610079
Funder
The Kempe Foundations, SMK-1934Knut and Alice Wallenberg Foundation, 2016.0346
Note

Validerad;2021;Nivå 2;2021-11-10 (johcin);

Funder: Spanish State Research Agency (AEI) (MDM-2017-0737), Unidad de Excelencia “María de Maeztu”- Centro de Astrobiología (INTA-CSIC), Spanish Ministry of Science and Innovation (PID2019-104205GB-C21)

Available from: 2021-11-10 Created: 2021-11-10 Last updated: 2022-02-10Bibliographically approved
In thesis
1. A planetary chamber to investigate the thermal and water cycle on Mars
Open this publication in new window or tab >>A planetary chamber to investigate the thermal and water cycle on Mars
2022 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

The water processes that affect the upper layers of the surface of Mars are not yet fully understood. Describing the processes that may induce changes in the water content ofthe surface is critical to determine the present-day habitability of the Martian surface,understand the atmospheric water cycle, and estimate the efficiency of future water extraction procedures from the regolith for In-Situ-Resource-Utilization (ISRU). This PhD thesis describes the design, development, and plausible uses of a Martian environmental facility ‘SpaceQ chamber’ which allows to simulate the near surface water cycle.

This facility has been specifically designed to investigate the effect of water on the Martian surface. SpaceQ has been used to investigate the material curation and has demonstrated that the regolith, when mixed with super absorbent polymer (SAP), water, and binders exposed to Martian conditions, can form a solid block, and retain more than 80% of the added water, which may be of interest to screen radiation while maintaining a low weight. The thesis also includes the testing of HABIT operation, of theESA/IKI ExoMars 2022 robotic mission to Mars, within the SpaceQ chamber, underMartian conditions similar to those expected at Oxia Planum. The tests monitor the performance of the brine compartment, when deliquescent salts are exposed to atmospheric water.

In this thesis, a computational model of the SpaceQ using COMSOL Multiphysics has been implemented to study the thermal gradients and the near surface water cycle under Martian temperature and pressure experimental conditions. The model shows good agreement with experiments on the thermal equilibration time scales and gradients. The model is used to extrapolate the one-point relative humidity measurement of the experimental to each grid points in the simulation. This gives an understanding ofthe gradient in atmospheric water relative humidity to which the experimental samples such as deliquescent salts and Martian regolith simulants are exposed at different time intervals. The comparison of the thermal simulation and the experimental behavior of HABIT instrument tests, shows an extra internal heating source of about 1 W which can be attributed to the hydration and deliquescence of the salts exposed to Martian conditions when in contact with atmospheric moisture.

Finally, this thesis experimentally demonstrates that pure liquid water can persist for 3.5 to 4.5 hours at Mars surface conditions. The simulated ground captured 53% of the atmospheric water either as pure liquid water, hydrate, or brine. The result concludes  that the relative humidity values at night-time on Mars may allow for significant water absorption by the ground, which is released at sunrise. The water cycle dynamics near the surface is therefore always out of equilibrium. After frost formation, thin films of water may survive for a few hours. The results of this thesis about the water cycle on Mars, and about the interaction of atmospheric water with regolith and salts, have implications for the present-day habitability of the Martian surface and planetary protection policies.

Place, publisher, year, edition, pages
Luleå: Luleå University of Technology, 2022
Series
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
Keywords
Mars, space chamber, ISRU, water cycle simulation, pure liquid water, habitability, heat transfer
National Category
Earth and Related Environmental Sciences
Research subject
Atmospheric science
Identifiers
urn:nbn:se:ltu:diva-89007 (URN)978-91-8048-018-5 (ISBN)978-91-8048-019-2 (ISBN)
Public defence
2022-04-06, A1545, Luleå, 09:30 (English)
Opponent
Supervisors
Available from: 2022-01-31 Created: 2022-01-30 Last updated: 2025-02-07Bibliographically approved

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Vakkada Ramachandran, AbhilashZorzano Mier, María-PazMartín-Torres, Javier

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