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Ore mineral characteristics as rate-limiting factors in sphalerite flotation: Comparison of the mineral chemistry (iron and manganese content), grain size, and liberation
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.ORCID iD: 0000-0001-9823-1664
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Minerals and Metallurgical Engineering.ORCID iD: 0000-0002-5228-3888
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.ORCID iD: 0000-0002-2634-6953
Luleå University of Technology, Department of Civil, Environmental and Natural Resources Engineering, Geosciences and Environmental Engineering.ORCID iD: 0000-0003-4711-7671
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2022 (English)In: Minerals Engineering, ISSN 0892-6875, E-ISSN 1872-9444, Vol. 185, article id 107705Article in journal (Refereed) Published
Abstract [en]

A sphalerite deportment study using QEMSCAN® was conducted to understand the distribution of the sphalerite grains with varying iron and manganese content during a multi-stage Zn-Pb-Cu flotation of a complex ore. In addition, the study aims to understand the effect of sphalerite chemistry in relation to grain size and liberation. Mineral chemistry, grain size, and degree of liberation were extracted for 497,704 sphalerite grains, composed of approximately 31 million energy-dispersive spectrometer (EDS) analysis points. Bulk chemical assay and electron probe microanalysis (EPMA) were used to validate the extracted sphalerite chemistry data from QEMSCAN®. Sphalerite recovery in the final zinc concentrate improved with increasing iron and manganese content for sphalerite grains containing up to 9% Fe and 2% Mn. At higher iron and manganese content, sphalerite recovery decreased or plateaued. Conversely, an opposite trend was observed for losses to the copper-lead concentrate. The obtained results indicated that considering the ore mineral characteristics, physical factors such as grain size and liberation have a more significant effect on sphalerite flotation than the presence of iron and manganese.

Place, publisher, year, edition, pages
Elsevier, 2022. Vol. 185, article id 107705
Keywords [en]
Sphalerite, Froth flotation, Lappberget, Garpenberg mine, Automated mineralogy, QEMSCAN
National Category
Geochemistry
Research subject
Ore Geology; Mineral Processing
Identifiers
URN: urn:nbn:se:ltu:diva-92027DOI: 10.1016/j.mineng.2022.107705ISI: 000823233000004Scopus ID: 2-s2.0-85133264775OAI: oai:DiVA.org:ltu-92027DiVA, id: diva2:1679190
Funder
EU, Horizon 2020, 72267
Note

Validerad;2022;Nivå 2;2022-06-30 (sofila);

Funder: Boliden Mineral AB

Available from: 2022-06-30 Created: 2022-06-30 Last updated: 2022-12-16Bibliographically approved
In thesis
1. Geometallurgy of a complex ore: Lappberget Zn-Pb-Ag-(Cu-Au) deposit, Garpenberg mine, Sweden
Open this publication in new window or tab >>Geometallurgy of a complex ore: Lappberget Zn-Pb-Ag-(Cu-Au) deposit, Garpenberg mine, Sweden
2023 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

Complex ores, in this instance, a polymetallic base metal ore with additional precious and penalty elements, pose particularly tough challenges for successful production forecasts. Plant performance and recoveries for complex ores are more difficult to predict due to the larger number of variables that must be considered, tracked, and characterized during the multi-stage separation process.

The focus of this study is to evaluate the mineralogical and textural controls that affect the variability in the flotation performance of a complex and variable ore. The research is based on a case study of the polymetallic Lappberget Zn-Pb-Ag-(Cu-Au) massive sulfide deposit at the Garpenberg Mine in Sweden. The mine is currently operated by Boliden Mineral AB and produces four different concentrates: zinc, lead, copper, and agravimetric concentrate targeted for gold and silver.

Geometallurgical characterization was conducted to understand the variability within the Lappberget deposit and to quantify the impact of geology (e.g., host rocks, mineralogy, and texture) on the metallurgical response and metal recovery processes. The approach undertaken is divided into five stages: (1) geological characterization, (2) ore classification, (3) geometallurgical testing, (4) development of prediction models, and (5) geometallurgical domaining. The first two stages aim at characterizing the geological characteristics of the ore and understanding its variability, whereas the latter three stages aim to describe and quantify the variability in the flotation performance of the ore and determine how it relates to its geological characteristics.

For the geological characterization, qualitative and quantitative mineralogical and textural investigations were undertaken for the different sulfides present in the deposit, mainly sphalerite, pyrite, galena, and chalcopyrite. Results from this study revealed the mineralogical, textural, and chemical variations of these sulfides within the deposit. This heterogeneity reflects the complex ore-forming conditions and the polyphase history of tectono-metamorphic processes that have affected the deposit. Three sphalerite types and four pyrite types were identified based on their distinct mineral chemistry, trace element signatures, texture, and host rock associations.

Based on the geological characteristics of the Lappberget deposit, ten geological domains were established to provide a framework for understanding the variability in flotation performance within the deposit. Batch flotation tests were conducted for samples from each geological domain. Quantified mineralogical characterization of the flotation products from the batch flotation tests was undertaken using automated mineralogy complemented by electron microprobe analysis. Results from the deportment study of the silver-rich ore type revealed a variety of complexly intergrown silver-bearing minerals: mainly native silver, allargentum, and freibergite. A strong association between silver and antimony was also observed. The results of the sphalerite deportment study indicate that in terms of ore mineral characteristics, physical factors, such as grain size and liberation, have a more significant effect on sphalerite flotation than the presence of elevated iron and manganese in the sphalerite crystal structure. The high variability in the feed grade of the different ore types identified in the Lappberget deposit reflects the heterogeneity of the ore and, consequently, the variable flotation performance.

Place, publisher, year, edition, pages
Luleå: Luleå University of Technology, 2023
Series
Doctoral thesis / Luleå University of Technology 1 jan 1997 → …, ISSN 1402-1544
National Category
Geology Metallurgy and Metallic Materials
Research subject
Ore Geology
Identifiers
urn:nbn:se:ltu:diva-94880 (URN)978-91-8048-238-7 (ISBN)978-91-8048-239-4 (ISBN)
Public defence
2023-02-24, E-632, Luleå University of Technology, Luleå, 10:00 (English)
Opponent
Supervisors
Funder
EU, Horizon 2020, 72267
Note

Funder: Boliden Mineral AB

Available from: 2022-12-19 Created: 2022-12-16 Last updated: 2023-09-14Bibliographically approved

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Tiu, GlacialleGhorbani, YousefJansson, NilsWanhainen, Christina

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