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Antiplasticization and transition to marked nonlinear viscoelasticity in poly(vinyl chloride)/acrylonitrile–butadiene copolymer blends
Department of Polymer Technology, Royal Institute of Technology, Sweden.
Department of Polymer Technology, Royal Institute of Technology, Sweden.
Department of Polymer Technology, Royal Institute of Technology, Sweden.
1977 (English)In: Journal of Applied Polymer Science, ISSN 0021-8995, E-ISSN 1097-4628, Vol. 21, no 11, p. 2953-2961Article in journal (Refereed) Published
Abstract [en]

A series of PVC/NBR blends with varying acrylonitrile (AN) content in the NBR has been studied in uniaxial tension creep tests. The tests have been carried out at 21.5 ± 0.5°C covering creep times from 10 to 1000 sec. NBR with low AN content, having poor compatibility with PVC, gives the blends with higher compliance and increased time dependence of the compliance. A higher AN content in the NBR gives the blends with the opposite properties when the NBR is added in small amounts. NBR with 40 wt‐% AN is found to act as an antiplasticizer giving minimal creep compliance when 7 wt‐% NBR is added. The antiplasticization reveals a considerably increased stress level at which the transition from approximatively linear to marked nonlinear viscoelasticity occurs and a decreased stress dependence of the creep compliance in the nonlinear viscoelastic range. Since the antiplasticization is also associated with a suppression of the β‐transition mechanism, the results provide a demonstration of the importance of β‐mechanism in the stress activated processes responsible for the appearance of nonlinear viscoelasticity in solid polymers.

Place, publisher, year, edition, pages
1977. Vol. 21, no 11, p. 2953-2961
National Category
Applied Mechanics
Identifiers
URN: urn:nbn:se:ltu:diva-93871DOI: 10.1002/app.1977.070211111ISI: A1977EA23300011Scopus ID: 2-s2.0-0017558185OAI: oai:DiVA.org:ltu-93871DiVA, id: diva2:1709266
Available from: 2022-11-08 Created: 2022-11-08 Last updated: 2022-11-08Bibliographically approved

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