Globally, food waste (FW) is found to be one of the major constituents creating several hurdles in waste management. On the other hand, the energy crisis is increasing and the limited fossil fuel resources available are not sufficient for energy needed for emerging population. In this context, biohydrogen production approach through valorization of FW is emerging as one of the sustainable and eco-friendly options. The present review explores FW sources, characteristics, and dark fermentative production of hydrogen along with its efficiency. FW are highly biodegradable and rich in carbohydrates which can be efficiently utilized by anaerobic bacteria. Based on the composition of FW, several pretreatment methods can be adapted to improve the bioavailability of the organics. By-products of dark fermentation are organic acids that can be integrated with several secondary bioprocesses. The versatility of secondary products is ranging from energy generation to biochemicals production. Integrated approaches facilitate in enhanced energy harvesting along with extended wastewater treatment. The review also discusses various parameters like pH, temperature, hydraulic retention time and nutrient supplementation to enhance the process efficiency of biohydrogen production. The application of solid-state fermentation (SSF) in dark fermentation improves the process efficiency. Dark fermentation as the key process for valorization and additional energy generating process can make FW the most suitable substrate for circular economy and waste based biorefinery.